• Resources Recycling
• /
• v.25 no.5
• /
• pp.64-74
• /
• 2016

Titanium and iron are closely related in nature, although titanium is the ninth most abundant element in the Earth's crust. Iron in titanium ores must be removed for use as feedstocks in the manufacture of titanium dioxide pigments and pure $TiCl_4$ for metal titanium. In this study, various beneficiation processes of ilmenite for production of $TiO_2$ have been reviewed and compared. Most of these processes involve a combination of pyrometallurgy and hydrometallurgy. These beneficiation processes of ilmenite generate considerable quantities of wastes primarily in the form of iron salt, iron oxide and acidic effluents. Therefore, it is important that recovery of acid value from waste and conversion of iron bearing waste to useful materials for development of new beneficiation processes of ilmenite.

• Resources Recycling
• /
• v.18 no.2
• /
• pp.62-68
• /
• 2009

Number of vehicles in Korea is gradually increasing and it exceeded 16 million in 2007. Holding of vehicles is connected to disposal, owing to this reason the importance of ELVs recycling has been emphasized. The recycling of ELVs makes the disposal of ELVs easier as well as protects environment and it has the alternative effect economizing the insufficient resource. This study was carried out to evaluate the economic effect of recycling of ELVs compared with disposal of ELVs. The analysis showed that recycling process makes a profit in comparison to the disposal of ELVs. Therefore the government has to consider establishing the regulation related to recycling of ELVs or materials and car manufactures have to develop the efficient dismantling and recycling methods.

• Resources Recycling
• /
• v.18 no.1
• /
• pp.30-37
• /
• 2009

Distribution diagram of Pt(IV), Pd(II), and Rh(III) in HCl solution was obtained as a function of HCl concentration from 0.001 to 10 M by considering complex formation reaction together with mass balance. When HCl concentration was higher than 0.1 M, most of Pt and Pd in HCl solution exist as $PtCl_6^{2-}$ and $PtCl_4^{2-}$. The concentration of HCl had a feat effect on the speciation of Rh(III). As HCl concentration increases from 0.1 to 10 M, the pedominant species changes from $PhCl_5^{2-}$ to $PhCl_6^{3-}$. Interaction parameters of $PtCl_6^{2-}$ and $PdCl_4^{2-}$ with hydrogen ion were evaluated from the solvent extraction data of Pt and Pd reported in the literature.

• Resources Recycling
• /
• v.23 no.4
• /
• pp.58-68
• /
• 2014

The statistics showed that about 1 billion automobiles were registered and about 40million ELVs occurred on the world in 2010. So all advanced countries including EU had plan to increase the ELVs recycling rate up to 95% of total by 2015. The Korean government also established a target for raising up to 95% of ELVs recycling rate according to 'Act on the Resource Circulation of Electrical and Electronic Equipment and Vehicles'. Before being satisfied with the requirement of recycling of ELVs however, the problem is issued on the scraps of plastic and non-ferrous metals which are now being abandoned and reclaimed with no adequate reuse. Therefore, as a part of preceding investigation on the present state of ELVs recycling in the world, this preliminary investigation study was carried out focusing on the state of EU's disposal and management regulations of ELVs and SLF/ASR including the world trend of disposal and management regulations of ELVs and SLF/ASR.

• Resources Recycling
• /
• v.13 no.4
• /
• pp.32-38
• /
• 2004

Recently, Orimulsion (a bitumen-in emulsion) has received increasing attention as an alternative fuel. Orimulsion combusion produces an ash rich in V, Ni and Mg which are processed to recover metals. As a basic study to recover V from Orimulsion ash, physico-chemcial properties and leaching behaviours were investigated. Orimulsion ash was fine size grains ($d_{50}$ 5.9 $\mu\textrm{m}$) with 16% V, 4 % Ni and 9% S. Vanadium was easily leached in water because Orimulsion ash was mainly constituted of metal sulfates. However, the increase of leaching temperature decreased the extraction percentage of vanadium because of hydrolysis of V(V) to vanadium pentoxide. The addition of sulfuric acid could increase the leaching percentage vanadium. In case of alkaline leaching for selective recovery of vanadium, the oxidzing agent such as $H_2$$O_2$ is required to improve the leaching per-centage

• Resources Recycling
• /
• v.9 no.6
• /
• pp.45-52
• /
• 2000

Generally, the residues of EAF's dusts treated by reduction process at high temperature are disposed. If the residues can be recycled as iron sources of EAF by upgrading their iron contents, it can be expected to reduce the amounts of disposed wastes and the environmental impacts. Reduction of EAF's dusts mixed with millscale was carried out in rotary hearth furnace to upgrade iron contents of reduction residues. Dusts should be reduced rapidly to protect from reoxidation of reduced iron residue which can be reoxidized at high temperature. In our experimental conditions, optimum reduction time was about 40min. and iron contents of the residues were increased with increasing mixing ratio of millscale and upgrade to 85% at 50%wt mixing ratio. Zinc and lead contents in residues were about 3% and 0.5% respectively. The residues reduced rapidly must be recycled in EAF because heavy metal elements in the residues can be extracted easily and contaminate air and water.

• Resources Recycling
• /
• v.8 no.1
• /
• pp.18-22
• /
• 1999

In order to utilize incineration fly ash of industrial wastes as resources, we present the recovery and separation of metals included in the fly ash by leaching with aqueous solution A great quantity of Cu, Pb, and Zn as well as a small amount oftoxic heavy metals are contained in the leach liquor of the fly ash, and the concentration of the ingredients of the fly ash depends on the industrial wastes which are fed into incinerators. In this paper, sequential Ieachiog operations are conducted using $H_2O$, $H_2SO_4$, $(NH_4)_2CO_3$ and NaOH as Icachants. Water soluble copper salt was leached by $H_2O$, Zn and Pb were separated by the NaOH leach liquor, and water insoluble copper was selectively leached as chelate ion with the $(NH_4)_2CO_3$ leach liquor of the third Ieaehant. Results show that the reduction percent of the fly ash in the leaching steps using $H_2O$, $H_2SO_4$, and $(NH_4)_2CO_3$ is 77%, and the other leaching procedures lose the weight of fly ash by above 60%.

• Resources Recycling
• /
• v.21 no.1
• /
• pp.82-92
• /
• 2012

There are several kinds of tungsten carbide(WC) such as light bulbs, metal cutting tools, drill bits, mining tools, military ordinance, high speed tool steels, chemicals/catalysts, wear resistance parts, jet engine turbine blades, etc.. These days it has been widely studied for the recycling technologies of the used tungsten carbide(WC) from view points of economy and efficiency. In this paper, open/registered patents of US, JP, EP, and KR and SCI Journal related to recycling technologies of the used Tungsten Carbide(WC) between 1969-2011 were reviewed. Patents and papers were collected using key-words searching and filtered by filtering criteria. The trends of the patents and papers was analyzed by the years, countries, companies, and technologies.

• Resources Recycling
• /
• v.21 no.2
• /
• pp.59-65
• /
• 2012

The refining effect of tantalum by electron beam melting(EBM) process for recycling tantalum scraps was investigated in the study. The purity of the tantalum metals refined by EBM was evaluated using glow discharge mass spectrometry (GDMS). From the result of GDMS, most impurities in the tantalum metals were removed by EBM down to a few mass ppm levels. The purity of the refined tantalum scraps was improved up to 5N (99.9991%) from 4 N (99.996%) of the initial tantalum scraps. The amount of metallic impurities in the tantalum was decreased from 30 ppm to 8 ppm. In addition, the gaseous impurities in the tantalum were decreased from 470 ppm to 50 ppm. Therefore a possibility of refining method for recycling tantalum scraps by EBM process was confirmed in this study.

• Resources Recycling
• /
• v.20 no.4
• /
• pp.52-57
• /
• 2011

Present paper reports a new method to separate the electrolyte membranes and carbon paper without using ultrasonic waves and stirring. In this method, these were separated from fuel cell membrane-electrode assembly(MEA) using the distilled water, butanol and surfactant by dipping method without the dispersion of catalyst particles. Separated carbon paper catalysts and fuel cell Pt/C catalysts were heated in aqua regia at $80{\sim}85^{\circ}C$ and added to precipitant. After calcination, Pt metal was recovered which might be used in fabricating new fuel cells.