• Applied Chemistry for Engineering
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• v.34 no.2
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• pp.121-125
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• 2023

Casein is a milk protein and one of the most important nutrients in milk. The composition is over 80% in cow's milk and about 20~45% in human's milk. Casein is highly biocompatible and biodegradable, so it has been studied for various biomedical materials applications as well as drug delivery systems. It is widely known that casein can be prepared as nanoparticles in the presence of the Ca²⁺ metal ion. Because casein is amphiphilic, hydrophobic drugs could be loaded inside to form a protein-based drug delivery system. In this study, we studied the optimum conditions for casein nanoparticle formation using natural metal ions present in the body, such as calcium, magnesium, zinc, and iron. It was confirmed that nanoparticles have a uniform size of around 150 nm and negative zeta potential values. In addition, it was demonstrated that casein nanoparticles have a cell viability of more than 80% and efficient intracellular uptake properties using confocal microscopy. From the results, it was also shown that the casein nanoparticles prepared using various metal ions have the potential to be biocompatible drug delivery carriers.

• Economic and Environmental Geology
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• v.42 no.4
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• pp.301-314
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• 2009

The Taebaeksan mineralized province, which is the most important one in South Korea, is rich in zinc-lead-tungsten-iron-copper-molybdenum-silver-gold mineral resources and has a diversity of deposit styles. These deposits principally coexist in time and space with porphyry-related epigenetic deposit such as skarn, hydrothermal replacement, mesothermal vein, and Carlin-like deposits. The magmatic-hydrothermal systems in the Taebaek fold belt is genetically characterized by the Bulguksa subvolcanic rocks(ca. $110{\sim}50\;Ma$) related to northwestward subduction of the paleo-Pacific Plate. The most important zinc-lead deposits in the area are the Uljin, Yeonhwa II and Shinyemi skarn, the Janggun hydrothermal replacement, and the Yeonhwa I intermediate-mixed (skarn/hydrothermal replacement) ones. In the present study, we present a compilation of metal production and mineral assemblage of the zinc-lead deposits. The metal difference of deposit styles in the area indicates a cooling path from intermediate-sulfidation to low-sulfidation state in the polymetallic hydrothermal system, reflecting spatial proximity to a magmatic source.

• Economic and Environmental Geology
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• v.12 no.2
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• pp.51-73
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• 1979

The zinc-lead deposits at the Yeonhwa I mine were investigated in terms of ore-forming geologic setting, structural style of ore control, geometry of individual orebodies, zoning, paragenesis and chemical composition of skarn minerals, as well as metal grades and ratios of selected orebodies. The Yeonhwa I mine is characterized by a large swarm of chimney type massive orebodies with thin skarn envelopes, boldly developed through a thick sequence of Pungchon Limestone, the overlying Hwajeol Formation, and the underlying Myobong Slate of Cambrian age. Nearly 20 orebodies of similar shape, but of varying size are arranged in a V-shaped pattern with northwest and northeast trends, clearly indicating an outstanding ore control by a conjugate system of fractures with these trends. Important orebodies are the Wolam 1, 2, 3, and 5 orebodies in the west, and the Namsan 1, 2, 3. and 5 orebodies in the east, among others. The Wolam 1 orebody, which was observed from the -360 level through the -240, -120, and 0 levels to the surface outcrops (totaling a vertical height of about 500m), shows a vertical variation in skarn mineralogy, ranging from pyroxene-garnet zone on the lower levels. through pyroxene (without garnet) zone on the intermediate levels, and finally to rhodochrosite vein on the upper levels and surface. Microprobe analyses of pyroxene and garnet on a total of 14 mineral grains revealed that pyroxenes are manganoan salitic in most samples, with downward increase of Fe and Mn, whereas garnets are highly andraditic, containing fractions of subordinate grossular with downward decrease of Fe. This indicates a reverse relationship of Fe-contents between pyroxene and garnet with depth. Ore minerals are major sphalerite, subordinate galena, and minor chalcopyrite. Sulfide gangue minerals include major pyrrhotite, and minor pyrite and marcasite of later age. Two types of variational trends in metal grades and ratios with depth are present on the plots of assay data from the Wolam orebodies: one is a steady upward increase in Pb, Zn, and Pb:Zn ratios, with a terminal decline at the top of orebody: the other is an irregular or sinusoidal change. The former is characteristic of chimney-type orebodies, whereas the latter is of vein· shaped orebodies. The Pb grades show large variations among orebodies and from level to level, whereas the Zn grades are relatively constand or less variable.

• Economic and Environmental Geology
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• v.36 no.4
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• pp.285-293
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• 2003

Tailings of Dukum mine in the vadose and saturated zone were investigated to reveal the mobility of metal elements and the condition of mineralogical solubility according to redox environments throughout the geochemical analysis, thermodynamic modelling, and mineralogical study for solid-samples and water samples(vadose zone; distilled water: tailings=5 : 1 reacted, saturated zone; pore-water extracted). In the vadose zone, sulfide oxidation has generated low-pH(2.72∼6.91) condition and high concentration levels of S $O_4$$^{2-}$(561∼1430mg/L) and other metals(Zn : 0.12∼l57 mg/L, Pb : 0.06∼0.83 mg/L, Cd : 0.06∼l.35 mg/L). Jarosite$(KFe_3(SO_4)_2(OH)_6)$ and gypsum$(CaSO_4{\cdot}2H_2O$) were identified on XRD patterns and thermodynamics modelling. In the saturated zone, concentration of metal ions decreased because pH values were neutral(7.25∼8.10). But Fe and Mn susceptible to redox potential increased by low-pe values(7.40∼3.40) as the depth increased. Rhodochrosite$(MnCO_3)$ identified by XRD and thermodynamics modelling suggested that $Mn^{4+}$ or $Mn^{3+}$ was reduced to $Mn^{2+}$. Along pH conditions, concentrations of dissolved metal ions has been most abundant in vadose zone throughout borehole samples. It was observed that pH had more effect on metal solubilities than redox potential. How-ever, the release of co-precipitated heavy metals following the dissolution of Fe-Mn oxyhydroxides could be the mechanism by which reduced condition affected heavy metal solubility considering the decrease of pe as depth increased in tile saturated zone.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.283-298
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• 2022

In this study, we investigated the mineral geochemistry of the albite-spodumene pegmatite, associated exogreisen, and wall rock from the Boam Li deposit, Wangpiri, Uljin, Gyeongsangbuk-do, South Korea. The paragenesis of the Boam Li deposit consists of two stages; the magmatic and endogreisen stages. In the magmatic stage, pegmatite dikes mainly composed of spodumene, albite, quartz, and K-feldspar intruded into the Janggun limestone formation. In the following endogreisen stage, the secondary fine-grained albite along with muscovite, apatite, beryl, CGM(columbite group mineral), microlite, and cassiterite were precipitated and partly replaced the magmatic stage minerals. Exogreisen composed of tourmaline, quartz, and muscovite develops along the contact between the pegmatite dike and wall rock. The Cs contents of beryl and muscovite and Ta/(Nb+Ta) ratio of CGM are higher in the endogreisen stage than the magmatic stage, suggesting the involvement of the more evolved melts in the greisenization than in the magmatic stage. Florine-rich and Cl-poor apatite infer that the parental magma is likely derived from metasedimentary rock (S-type granite). P₂O₅ contents of albite in the endogreisen stage are below the detection limit of EDS while those of albite in the magmatic stage are 0.28 wt.% on average. The lower P₂O₅ contents of the former albite can be attributed to apatite and microlite precipitation during the endogreisen stage. Calcium introduced from the adjacent Janggun formation may have induced apatite crystallization. The interaction between the pegmatite and Janggun limestone is consistent with the gradual increase in Ca and other divalent cations and decrease in Al from the core to the rim of tourmaline in the exogreisen.

• The Science & Technology
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• v.9 no.8 s.87
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• pp.23-27
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• 1976

우리나라에서 본격적으로 물리탐사를 시도한것은 1958~1960년에 실시한 항공자력탐사로서 그후 현재까지 불과 20년이 지나지 않았다. 그간 물리탐사의 기술발전으로 자원탐사분야에 많은 공헌이 있었다. 현재까지 주로 적용된 분야는 철자원탐사를 위한 자력탐사, 지하수조사를 위한 전기비저항탐사동, 연등의 통화금속광물탐사를 위한 각종 전기탐사, 제3기층 지질구조와 땜공사, 공업단지조성등의 기반암조사, 그리고 광산의 갱내 출수조사등을 위한 탄성파탐사, 우라늄자원을 위한 방사능탐사, 그리고 해저지질 및 자원조사를 위한 해상물리탐사등이다. 이와 동시에 석탄층조사를 위한 전기탐사 및 Model연구자력탐사의 전산처리 적용, 그리고 광물 및 암석의 물리적 성질등 학술분야에 대한 기초연구도 계속하여 왔다. 우리나라에 있어 물리탐사의 적용조건은 비교적 험악한 지형, 복잡한 지질구조, 광상의 불규칙 또는 소규모의 발달과 산재등이다. 이와 같은 특징은 탐사해석의 정도를 높이기 위하여 보다 고도의 과학기술문제의 해결을 요구하고 있으며 이와 동시에 현대적 탐사방법과 연구개발로 대상자원의 탐사지역확대와 지하심부 탐사등이 당면과제이다. 기술과제로서는 석탄 및 기타자원에 대한 물리검층탐사, 경상계 지질구조구명을 위한 탄성파탐사 및 동력탐사의 적용, 항공자력, 전자 및 방사능탐사 및 해양의 각종물리탐사의 기술개발이 있으며 그외 탐사자료의 전산처리기술 및 지구과학의 기초연구등이 있다.

• Journal of Environmental Health Sciences
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• v.37 no.5
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• pp.335-341
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• 2011

The Goseong abandoned mine accident was a typical case of long-term sequela resulting from environmental disruption during the rapid economic development of Korea. While the final conclusion of epidemiologic investigation was that residents surrounding the abandoned mine were simply exposed to cadmium from the abandoned mine without any patient contracting 'itai-itai' disease, not only did residents around the abandoned mine suffer enormous psychological and economic damage, but people in neighbouring communities did as well when the entire area was stigmatized as an contaminated area. Environmental civic groups and the government worked together to solve the problem by forming a joint committee which held the right of decision in any matter to be determined. By inviting all the stakeholders to participate in the joint committee, a transparent investigation was guaranteed and the results of investigation and recommendations to solve the problem were accepted by all involved. Even though the environmental health division in Ministry of Environment has developed considerably and built up a capacity to deal with environmental accidents, the process which was adopted to solving the Goseong abandoned mine accident can be useful to settle environmental health issues with severe conflicts among stakeholders.

• The Korean Journal of Food And Nutrition
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• v.15 no.1
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• pp.64-69
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• 2002

To know a degree of pollution in agricultural products cultivated around 4 unworked mines located in Chollanam-Do, we investigated a concentration of heavy metal and trace metal to provide the basic data for its residual limits. 28 samples of seven kinds of agricultural products(lettuce, onion, potato, radish, pepper, pumpkin, bean) collected from 4 unworked mines located in Chollanam-Do in 2001 were analyzed by Mercury Analyzer for mercury and Atomic Absorption spectrophotometer for Pb, As, Cd, Cu, Mn, and Zn. Hg contents were detected N.D. ∼trace level(0.01 ppm and less) and As content were detected N.D. ∼ 0.029 lpm but most of same)leE were not detected. Cd contents were detected N.D∼0.124 ppm. The results of Hg, As, Pb and Cd content showed that for all the 7 species of agricultural products studied, none have accumulated levels dangerous enough to Pose health problems. The average contents of Cu were 3.070 ∼ 7.825 ppm in bean, the Mn were 3.688 ∼23.935 ppm in lettuce ailed the Zn were 5.690 ∼21.171 ppm in bean, respectively.

• Economic and Environmental Geology
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• v.26 no.4
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• pp.465-472
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• 1993

The heavy metal contents are more abundant in stream waters, paddy soils and rice plants in the vicinity of abandoned mines compared to the surrounding areas in the Kyungpook province. However, these contents tend to decrease with distance from mines, and show some variation under different geological and geochemical environments. The Sin-stream waters have high contents of Cu=4.9 ppm, Pb=0.1 ppm, Zn=3.5 ppm and other heavy metals (Ni, Co, Cd) at Dalsung abandoned mine and low contents of Cu=0.4 ppm, Pb=0.1 ppm, Zn=0.1 ppm and other metals= 0.002 ppm in the surrounding area. The high contents decrease in the downstream in the area of calcareous sedimentary rocks. The paddy soils have high contents of approximately Cu=51 ppm, Pb=83 ppm, Zn=211 ppm, and Cd=11.3 ppm in the vicinity of Gunwi abandoned mine but low contents of Cu=4.5 ppm, Pb=2.9 ppm, Zn=60 ppm and Cd=0.4 ppm in the surrounding area. The Dadeog abandoned mine also shows similar trends to Gunwi mine. The contents of heavy metals of rice plants are high in the roots but trends to decrease through stem+leaf and become low in brown rices.

• Resources Recycling
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• v.22 no.4
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• pp.12-21
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• 2013

Waste electrical and electronic equipment(WEEE or E-waste) is one of the fastest growing waste stream in Korea. The proper management of such equipment has become of major concern for solid waste professionals because of the large growth of the waste stream and the presence of a myriad of toxic materials in it. In this paper, in order to evaluate the economical value of the recycling metallic materials from the E-waste, big size electrical home appliances, small size electrical home appliances, end of life hand phone and PCB(printed circuit board) were reviewed.