• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.8 no.1
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• pp.67-75
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• 1998

The objectives of this study were both to evaluate the level and correlations of hazardous agents and to suggest measures to control industrial hygiene problems caused by using water-soluble metalworking f1uids(MWF). Geometric mean of formaldehyde(0.039 ppm) was higher than criteria of NIOSH(0.016ppm). Formaldehyde, originally existed in the biocide, is released and used to kill microbes in soluble MWF. Microbe concentrations were above $10^4No./mL$ in 14 MWF tanks among 20 tanks surveyed. Nitrosamines that is formed by reaction of nitrosating group and amines was detected to $18.4-47.1{\mu}g/m^3$. Formaldehyde concentration was low when microbes were abundant(r=-0.67, p=0.011), and high when open tank area was wide(r=0.75. p=0.012). The significant relationship between pH and microbes(r=-0.76. p=0.003) was also observed. The predominant bacteria species in MWF were Pseudomonas spp., Bacillus spp., Comamonas testosteroni, Acinetobacter haemolyticus, Bordertella bronchiseptica in order. Therefore, hazardous agents emitted by using water-soluble MWF seems to be correlated microbial growth. In order to minimize worker's exposure to several hazardous agents by an water-soluble MWF and to increase productivity, microbial growth must be controlled to the lowest level as possible. Administrative control as well as engineering control must comprehensively be applied to control microbe's growth in water-soluble MWF.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.23 no.3
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• pp.169-176
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• 2013

Objectives: The aim of this study is to critically review the health effects of not only direct exposure to biocide, but also indirect exposure to by-product hazardous agents generated through the use of biocide in metalworking operations. Methods: An extensive literature review was conducted of studies reporting on respiratory disease cases, particularly hypersensitivity pneumonitis (HP), in environments using water-soluble metalworking fluids (MWFs). Keyword search terms included 'metalworking fluids', 'machining fluids', 'metalworking operation' 'machining operation' and 'biocide', which were also used in combination. Additional articles were identified in references cited in the articles reviewed. Results: Several of the field, epidemiological and experimental studies reviewed assumed that the symptoms and signs typical of HP developed in machinists who handled water-soluble MWF could be caused by inhalation exposure to nontuberculous mycobacteria (NTM). Most NTM are known to be not only resistant to both biocide and disinfectant, but also to have acid-fast cell walls that are highly antigenic. The presence or persistence of the Mycobacterium species, referred to as NTM, in metalworking fluid-using operations may be caused by NTM contamination in either the natural water or tap water that is used to dilute the base oil and additives for water-soluble MWFs. This hypothesis that NTM contamination in water-soluble MWFs is a causative agent of HP has high biologic plausibility, such as antigenic property, hydrophobicity and small diameter (< 5 um). Conclusions: Aerosolized mycobacteria colonized from MWF are likely to be causing the HP. Inhalation exposure to mycobacteria should be considered as a possible cause for the development of HP.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.17 no.1
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• pp.71-80
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• 2007

The purpose of this study was to assess the ambient level of Polynuclear aromatic hydrocarbons(PAHs), oil mist of the metalworking fluids(MWFs), especially in heat treat industry and non heat treat industry. And we assessed the relationship of the pattern of exposed PAHs with oil mist during survey day. The study population of heat treat industries contained 98 workers, non-heat treat industry contained 40 workers. Personal samples were taken for ambient monitoring of PAHs and oil mist. PAHs was to analyze the relationship of airborne oil mist. The geometric mean of airborne total PAHs was $3.44{\mu}g/m^3$ in heat treat industry and $0.13{\mu}g/m^3$ in non heat treat industry, Pyrene and Benzo(a)pyrene was detected from heat treat industry and Naphthalene in heat treat industry was significantly detected higher than in non heat treat industry. The geometric mean of airborne oil mist was $0.19{\mu}g/m^3$ in heat treat industry and $0.70{\mu}g/m^3$ in non-heat treat industry. The correlation between oil mist and total PAHs was shown below, total PAHs in workers of non heat treat industry and heat treat industry were not significantly correlated with oil mist

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.22 no.4
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• pp.284-292
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• 2012

Objectives: The objective of this study was to investigate the relations between the bacterial concentration and the environmental factors in the water soluble metal working fluids at factories. Methods: The bacterial concentrations for airborne and fluid samples of 7 factories were quantified during the summer season. And we statistically analysed the relations between the bacterial concentrations and the factors such as temperature, relative humidity, usage quantity, mixing ratio and exchange interval. Results: The geometric mean levels of the airborne bacterial concentrations were 79.1(range : N.D.~686) $CFU/m^{3}$ and 68.1(range: N.D.~919) $CFU/m^{3}$ in the process and outdoor. The airborne bacterial concentrations showed no statistical difference by process, usage quantity, mixing ratio and exchange interval. The airborne bacterial concentrations had negatively weak correlations with air temperature and relative air humidity(p<0.05). The bacterial concentrations and pH showed significantly negative correlations in the fluids(p<0.05). And the airborne bacterial concentrations in factories and those in metal working fluids showed no statistical relationship. Conclusions: In the water soluble metal working fluids using factories, the airborne bacterial concentrations of the process were related to those of the outdoor and environmental factors, rather than the onsite contaminated metal working fluids.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.3
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• pp.300-309
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• 2014

Objectives: The objective of this study is to evaluate microbial exposure hazards in the metal-working fluids(MWF) handling industry. Methods: Air quality parameters(airborne bacteria, fungi, endotoxin and oil mist) and bulk MWF in storage tanks were evaluated at 54 points at nine sites in South Korea. Results: The geometric means(GM) of culturable airborne bacteria, fungi, endotoxin and oil mist concentration were $133CFU/m^3$(n=376, range $7{\sim}6,510CFU/m^3$), $159CFU/m^3$(n=381, range $7{\sim}8,469CFU/m^3$), $8.06EU/m^3$(n=103, range $0.34{\sim}280.4EU/m^3$) and $0.20mg/m^3$(n=104, range $0.01{\sim}2.87mg/m^3$), respectively. The ratio of indoor to outdoor concentration was 2.7 for bacteria, 6.1 for endotoxin, and 4.8 for oil mist. Even though average airborne bacteria concentration did not exceed recommended exposure limits($1,000CFU/m^3$), MWF in the storage tanks was highly contaminated with bacteria(arithmetic mean $2.1{\times}10^6CFU/ml$) and exceeded recommended bacteria limits($10^5CFU/ml$). Conclusions: It is necessary for MWF handling workplaces to conduct periodical biohazard inspection of MWF storage tanks. Additionally, further research may be necessary to establish biological occupational exposure limits.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.428-428
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• 2010

유기 발광 소자내의 전공과 전자의 균형과 효율적인 재결합을 통한 발광소자의 효율 향상을 위한 다양한 연구가 소자의 응용에 매우 큰 영향을 주고 있다. 그러나 대부분의 전도성 유기물내에서 정공의 이동도 가 전자의 이동도 보다 100 배 정도 빠르기 때문에 발광 효율을 향상시키기 위한 효율적인 전자 주입이 요구된다. 본 연구에서는 전자주입효율을 향상하기 위하여 강한 전자 받게 역할을 하는 플러렌($C_{60}$)의 장점을 이용한 이중 전자 주입층을 제작하고 녹색 유기 발광 소자에 사용하여 발광효율의 변화를 관찰하였다. 유기 발광 소자에서 전자의 이동도를 향상하여 발광 층내로 주입되는 전자의 주입량을 증가하여 엑시톤 형성 확률을 높이기 위하여 전자 주입 층 내에 $C_{60}$을 첨가하였다. $C_{60}$만으로 이루어진 단층 전자 주입 층으로 구성된 유기발광 소자는 Al과 $C_{60}$ 계면사이에 거칠기가 큰 계면으로 인해 발생된 누설전류로 인해 Cesium flouride (CsF) 단층 전자 주입 층에 비해 낮은 발광효율을 나타냈다. 플러렌의 높은 전자전도성을 유지하며 누설전류의 흐름을 방지하기 위하여 매우 얇은 CsF층을 알루미늄 금속과 플러렌사이에 형성함으로써 플러렌과 Al 사이의 공유결합을 없애 누설전류를 줄였으며 Cs의 무거운 원자량으로 인해 전자 수송층으로의 확산되는 량이 적어 발광층에서 엑시톤의 재결합효율이 개선되어 유기발광 소자의 발광효율 향상이 나타남을 관찰하였다.

• Journal of Life Science
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• v.13 no.6
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• pp.917-923
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• 2003

The present investigation was conducted to determine the chemical oxygen demand (COD) removal efficiency by Pseudomonas aeruginosa EMS1. The COD removal efficiency in the medium containing 1% metal working fluid (MWF) was 12% after cultivation of 4 days. The composition of optimum medium for the COD removal efficiency of 1% MWF by P. aeruginosa EMS1 were NH$_4$Cl 0.3%,$ K_2HPO_4\; 0.05%,\; KH_2PO_4\; 0.04%,\; MgSO_4.7H_2O\; 0.05%,\; CaCl_2.2H_2O 0.03%$ and $FeSO_4.7H_2O$ 0.04% at initial pH 7.0 and $30^{\circ}C$. Under this condition, the highest the COD removal efficiency was observed after 4 days.

• Korean Chemical Engineering Research
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• v.43 no.4
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• pp.487-494
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• 2005

Nowadays a large amount of wastewater containing metal working fluids and cleaning agents is generated during the cleaning process of parts working in various industries of automobile, machine and metal, and electronics etc. In this study, aqueous or semi-aqueous cleaning wastewater contaminated with soluble or nonsoluble oils was treated using ultrafiltration system. And the membrane permeability flux and performance of oil-water separation (or COD removal efficiency) of the ultrafiltration system employing PAN as its membrane material were measured at various operating conditions with change of membrane pore sizes and soil concentrations of wastewater and examined their suitability for wastewater treatment contaminated with soluble or insoluble oil. As a result, in case of wastewater contaminated with soluble oil and aqueous or semi-aqueous cleaning agent, the membrane permeability increased rapidly even though COD removal efficiency was almost constant as 90 or 95％ as the membrane pore size increased from 10 kDa to 100 kDa. However, in case of the wastewater contaminated with nonsoluble oil and aqueous or semi-aqueous cleaning agent, as the membrane pore size increased from 10 kDa to 100 kDa and the soil concentration of wastewater increased, the membrane permeability was reduced rapidly while COD removal efficiency was almost constant. These phenomena explain that since the membrane material is hydrophilic PAN material, it blocks nonsoluble oil and reduces membrane permeability. Thus, it can be concluded that the aqueous or semi-aqueous cleaning solution contaminated with soluble oil can be treated by ultrafiltration system with the membrane of PAN material and its pore size of 100 kDa. Based on these basic experimental results, a pilot plant facility of ultrafiltration system with PAN material and 100 kDa pore size was designed, installed and operated in order to treat and recycle alkaline cleaning solution contaminated with deep drawing oil. As a result of its field application, the ultrafiltration system was able to separate aqueous cleaning solution and soluble oil effectively, and recycle them. Further more, it can increase life span of aqueous cleaning solution 12 times compared with the previous process.

• Clean Technology
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• v.17 no.4
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• pp.314-324
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• 2011

Several amide derivatives have been used as additives for base oil of metal working fluids and pressure working oils. In this paper, a series of succinic acid alkyl half-amide derivatives were synthesized as over 97% yields by ring-opening reaction of succinic anhydride and several amines and were soluble in 100 N base oil within 1 wt% concentration. The structures of the synthesized amides were confirmed by $^1H$-NMR, FT-IR spectrum and GC analysis. Anti-corrosion properties of the amides in sea water were evaluated through ASTM D665 method and weight loss method. As the results of anti-corrosion properties, the properties of the amides with shorter alkyl chain and high concentration showed better performance than those with longer alkyl chain and low concentration. Also, the dialkyl amides showed better anti-corrosion properties than those of the monoalkyl amides. Inhibition efficiency% (IE%) was over 93% in the concentration of 40 ppm and corrosion rate (CR) was below 0.5 mm/year in the same concentration.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.367-375
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• 2011

Succinic acid ester derivatives have been used as additives for the base oil of metal working fluids and pressure working oils. In this paper, a series of succinic acid alkyl half-esters were synthesized with over 97% yields by ring-opening reaction of succinic anhydride and fatty alcohol and were soluble in 100 N base oil within 1 wt% concentration. The structures and purities of ester derivatives were confirmed by $^1H-NMR$ and FT-IR spectrum and GC analysis. Anti-corrosion properties of the esters in sea water were evaluated through ASTM D665 method and weight loss method and compared to that of succinic alkyl esters without carboxylic acid group in the molecule. As the results, anti-corrosion properties of succinic acid alkyl half-esters with carboxylic acid group were better than those of succinic acid alkyl esters without carboxylic acid group. And, Anti-corrosion properties of the esters with a shorter alkyl chain of high concentration showed better performance than those with longer alkyl chain of low concentration. Inhibition efficiency % (IE%) of the esters was over 95% in the concentration of 80 ppm and corrosion rate (CR) was below 0.3 mm/year at the same concentration. Thus, the corrosion properties of succinic acid alkyl half-esters result from the carboxylic acid groups in molecules.