• Title/Summary/Keyword: 극성효과

Search Result 298, Processing Time 0.027 seconds

A Study on the Factors that Influence the Sun Protection Factor(SPF) and Protection Factor of UV-A(PA) in Sunscreen (자외선 차단제품에서 자외선차단지수(SPF)와 자외선A차단등급(PA)에 영향을 주는 인자에 관한 연구)

  • Yeon, Jae-Young;Seo, Jeong-Min;Bae, Jun-Tae;Lee, Cheong-Hee;Lee, Sang-Gil;Pyo, Hyeong-Bae;Hong, Jin-Tae
    • Journal of the Korean Applied Science and Technology
    • /
    • v.31 no.3
    • /
    • pp.422-439
    • /
    • 2014
  • In this study, we measured the effects of UV protection efficiency of the polarity of oil, the type of emulsion, the viscosity of product, the type of thickener and light stabilizer in sunscreen. As a result, even higher polarity of the oil, UV protection efficiency is measured high (Butyloctyl salicylate: SPF 44.10, PA 7.93). In case of low, it was measured low conversely (Dimethicone: SPF 16.40, PA 5.57). In case of emulsion types, UV protection efficiency of W/O emulsion which organic sunscreen agent is based in the outer phase is measured higher than O/W emulsion. According to increasing of viscosity, UV protection efficiency tends to increase proportionally. However, the size of emulsion particles and the kinds of thickener has no effect to UV protection efficiency. Also light stabilizer was found to be an important factor affecting the UV protection efficiency. As a result, it is able to improve UV protection efficiency and it has potential which improve the economical effect of the sunscreen without increasing sunscreen agents.

Oil Extraction and Biodiesel Production from Micro-Algae Pre-treated with Microwave (Microwave를 이용한 미세조류로부터 오일 추출 및 바이오디젤 생산)

  • Kim, Deogkeun;Choi, Byoungyun;Kim, Sungmin;Oh, Youkwan
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2010.06a
    • /
    • pp.250.2-250.2
    • /
    • 2010
  • 빛과 공기 중의 이산화탄소를 고정화하여 생성되는 바이오매스(biomass)로부터 다양한 에너지 및 물질을 생산하는 연구는 석유고갈과 환경문제 해결의 한 방안으로서 활발히 진행되어 왔으며, 앞으로도 그 지속 가능성과 환경 친화성에 의해 바이오에너지 이용 및 보급은 꾸준한 증가세를 보일 것으로 전망된다. 바이오디젤, 바이오에탄올의 경우는 미국, 브라질, EU, 한국 등에서 상용화되어 사용되고 있으며 그 생산량이 계속적으로 증가하고 있다. 하지만, 바이오연료의 보급 증가는 식량 자원과의 충돌과 열대우림 파괴 등의 부작용을 일으키고 있다. 이러한 문제 해결의 일환으로 단위면적당 생산성이 대두, 유채보다 월등한 것으로 보고되는 미세조류에 대한 관심이 증가하고 있으며 우수 미세조류종 개발, 미세조류 고속배양 및 수확, 미세조류로부터 에너지 및 유용물질, 소재 생산에 대한 연구가 활발히 진행되고 있다. 본 연구에서는 미세조류로부터 바이오디젤 원료유를 생산하기 위해 Soxhlet을 이용한 추출 방법을 이용하였다. 추출되는 오일은 사용 용매의 극성에 따라 물성과 추출 효율에 차이가 큰 것으로 나타났다. 강한 극성의 용매일 경우, 엽록소와 단백질이 같이 추출되는 문제가 있으며 약한 극성 용매는 세포벽의 방해로 용매가 세포내부로 흡수되지 못하는 문제가 있다. 추출 효율이 높은 극성용매의 경우 불순물을 제거해야 고순도의 바이오디젤의 생산이 가능하고 비극성 용매는 추출 오일의 물성은 좋으나 수율이 매우 낮게 측정되었다. 이러한 동시추출을 방지함과 동시에 추출 효율을 높이기 위해 본 연구에서는 세포벽 파괴 후 용매추출하는 방법으로서 미세조류를 Microwave에 노출시켜 오일 추출율을 증가시키는 전처리 연구를 수행하였다. 전처리시, Microwave에 의한 열 발생은 미세조류를 탄화시키기 때문에 열매체로서 물을 혼합하여 탄화를 방지하고 세포벽 내외부의 가열효과로 세포벽을 파괴하고자 하였다. Microwave에 의한 에너지 손실을 줄이며 세포벽 파괴에 효과적인 수분혼합비를 조사하였으며 Microwave에 노출 후 잔류수분을 건조하고 효율적으로 용매를 접촉시키기 위해 분쇄를 수행하였다. 모든 전처리 반응을 거친 미세조류에서 약 2배 증가된 추출수율을 얻을 수 있었으며, SEM을 통해 전처리 미세조류와 미전처리 미세조류를 분석해본 결과 전처리 미세조류의 다공성이 증가함을 확인하였다. 또한, 90%의 메탄올에 미세조류를 녹여 엽록소 함유량을 측정한 결과, 전처리 미세조류의 엽록소가 미전처리 미세조류보다 약 7배가량 감소함을 확인할 수 있었다.

  • PDF

Microbe Adhesion and Organic Removal from Synthetic Wastewater Treatment using Polypropylene Media Modified by Ion-Assisted Reactions (이온 보조 반응에 의하여 활성화된 폴리프로필렌 담체를 이용만 합성폐수 처리시 미생물 부착 및 유기물의 제거)

  • Seon, Yong-Ho;Han, Sung;Koh, Seok-Keun
    • KSBB Journal
    • /
    • v.17 no.3
    • /
    • pp.235-240
    • /
    • 2002
  • The surface of polypropylene was modified by 1 keV $Ar^+$ ion beam in an $O_2$ environment in order to enhance wettability. Contact angle of deionized water on modified polypropylene was reduced from $78^{\circ}$to $22^{\circ}$. The enhanced wettability is originated from newly formed functional groups such as ether, carbonyl, and carbonyl groups. During immersion in deionized water, the enhanced wettability has remained nearly same. After washing in water, the hydrophilic functional groups on the polymer surface have been very stable. The modified polypropylene was adopted as bio-film media to remove organics in synthetic wastewater. Microbe adhesion on the polypropylene surface was improved due to the newly formed hydrophilic groups.

Control of Polarity by Magnetic Array Table in Magnetic Abrasive Polishing Process (자기연마가공에서 마그네틱 어레이 테이블에 의한 극성 제어)

  • Gang, Han-Sung;Kim, Tae-Hui;Kawk, Jae-Seob
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.34 no.11
    • /
    • pp.1643-1648
    • /
    • 2010
  • It is very difficult to polish non-magnetic materials by the magnetic abrasive polishing (MAP) process because magnetic force is required for MAP, but the magnetic force for non.magnetic materials is low. In this study, we aimed to develop a magnetic array table and control the magnetic polarity such that the magnetic force can be increased for the MAP of non-magnetic materials. The newly designed magnetic array table has 32 electro magnets, and the magnetic polarity of each electro-magnet can be easily controlled by changing the electric polarity. It was analytically verified that the magnetic flux density of non-magnetic materials can be varied by varying the applied magnetic polarity.

Solvent Effects on the Nucleophilc Addition (I) Effect of Solvent Polarity on the Nucleophilic Addition of Amine to Phenylvinylketone (친핵성 첨가반응에 대한 용매효과 (I) Phenylvinylketone에 대한 아민의 첨가반응속도에 미치는 용매의 극성효과)

  • Gap-Cheol Shin;Tae-Rin Kim
    • Journal of the Korean Chemical Society
    • /
    • v.36 no.2
    • /
    • pp.287-292
    • /
    • 1992
  • The rate constants of the nucleophilic addition reaction of amines (piperidine and diethylamine) to phenylvinylketone in various solvents have been determined by UV spectrophotometry at $25^{\circ}C$. On the basis of the high sensitivity of the rate to the polarity of the medium, it may be concluded that the reaction intermediate has zwitterionic character. The effect of the solvents on the rate of the bimolecular nucleophilic addition reaction is described well by the Kirkwood equation: The transition state of the reaction has a cyclic structure formed through an intramolecular hydrogen bond. The addition reaction of primary and secondary amines to phenylvinylketone in all solvents take place considerably faster than that of tertiary amine and this results also can be explained by the intermediate products in the reaction have a cyclic structure formed through an intramolecular hydrogen bond for the primary and secondary amines but not for the tertiary amine.

  • PDF

Evaluation of the Biological Activity Affected by Extracting Solvents of Rosemary (Rosmarinus officinalis L.) (로즈마리(Rosmarinus officinalis L.) 극성별 용매 추출물의 생리활성 검증)

  • Li, Ke;Yang, Kyeong Hee;Guo, Lu;Cui, Zhengwei;Son, Beung Gu;Kang, Jum Soon;Lee, Yong Jae;Park, Young Hoon;Je, Beong Il;Choi, Young Whan
    • Journal of Life Science
    • /
    • v.29 no.1
    • /
    • pp.69-75
    • /
    • 2019
  • Rosemary (Rosmarinus officinalis L.) is widely used as a food material. Although various physiological activities of rosemary have been reported, there have been no studies on the physiological activity of solvent extracts with different polarities. Rosemary extracts were obtained by extraction of dried powder using 0%, 25%, 50%, 70%, and 95% ethanol (EtOH) in distilled water, methanol, ethyl acetate, and hexane. As these ratios of EtOH are generally chosen by default and scarcely optimized, we investigated the impact of the composition of EtOH in distilled water on extract-related characteristics, such as DPPH free radical scavenging and ${\alpha}$-glucosidase inhibition, on the differentiation of 3T3-L1 adipocytes and inhibition of tyrosinase. Adipogenesis inhibition was highest at 70% EtOH. DPPH scavenging activity and inhibition of tyrosinase activity were reduced with 50% EtOH in water. However, inhibition of ${\alpha}$-glucosidase activity was higher in 50% EtOH in water. The best solvents in terms of DPPH scavenging activity, inhibition of tyrosinase and ${\alpha}$-glucosidase, and differentiation of adipocytes obtained with different concentrations of EtOH, although a lower similar activities were found with 50% ethanol. Considering the extraction solvents, a ratio of EtOH in water gives different content and constituents of compounds. These differences will give activities inhibition of adipogenesis, tyrosinase, ${\alpha}$-glucosidase activity, and DPPH scavenging activity.

Study on of polarity effect on alignment film in transcription-aligned TN-LCD (전사배향 TN-LCD 에서의 배향막의 극성효과에 관한 연구)

  • Kim, Jin-Ho;Seo, Dae-Shik
    • Proceedings of the KIEE Conference
    • /
    • 1999.07d
    • /
    • pp.1812-1814
    • /
    • 1999
  • The effects of polarity of the polymer on transcription-aligned twisted nematic (TN)-liquid crystal display (LCD) on various the polyimide (PI) surfaces were investigated. The monodomain alignment of nematic (N)LC is obtained in cells fabricated by transcription alignment method on PI surface with medium polarity. The LC alignment using transcription alignment method is attributed to polarity of the polymer. The threshold voltage of transcription-aligned TN-LCD decreases with increasing the polarity of the polymer on three kinds of the PI surfaces. The threshold voltage of transcription-aligned TN-LCD on PI surface with high polarity is almost the same compared to rubbing-aligned TN-LCD. The response time of transcription-aligned TN-LCD decreases with the increasing the polarity of the polymer on all PI surfaces. The decay time of transcription-aligned TN-LCD is slow compared with the rubbing-aligned TN-LCD.

  • PDF

Characteristics of Silicone Rubber for EHV Cable Accessories (초고압 케이블 중간 접속함용 실리콘 고무의 특성 고찰)

  • Ko, Eui-Gon;Shin, Doo-Sung;Ji, Eung-Seo;Yoon, Seung-Hoon
    • Proceedings of the KIEE Conference
    • /
    • 2004.07c
    • /
    • pp.1652-1654
    • /
    • 2004
  • 초고압 지중 케이블을 전기적, 기계적으로 연결하는 역할을 하는 중간 접속함은 미가교 폴리에틸렌을 사용하여 현장에서 가교시키는 TMJ(tape molded Joint), 에폭시와 EPDM고무의 복합 절연구조를 가지고 있는 PJ(Prefabricated Joint), 그리고 EPDM또는 실리콘 고무를 단독으로 사용하는 PMJ(Premolded Joint)로 대표된다. 그러나 TMJ는 현장에서 가교하는 방식으로 조립 후 품질을 파악하기가 쉽지 않으며 PJ는 공장에서 미리 성형한 제품을 현장에서 조립만 하면 되는 구조이나 그 부품의 수가 많고, 이종 계면을 가지고 있는 복합절연구조를 가지고 있어 최근에는 부품의 수도 적고 조립이 간편하며 이종 계변의 수를 최소화하여 전기적 안정성을 높인 조립형 접속함인 PMJ를 선호하는 경향을 보이고 있다. 본 논문에서는 PMJ용으로 사용되는 실리콘 고무의 절연과 반도전 계면에서의 접착력과 전기적 파괴 특성간의 상관 관계를 규명하였고 또한 실리콘 고무의 상온 및 고온에서의 AC 및 Impulse 전압의 특성 변화와 Impulse 전압의 극성효과에 대해 규명하였다.

  • PDF

Dynamic Characteristic of Magnetic Fluids in a Circular Pipe (원관내 자성유체의 동적특성)

  • 유신오;박정우;최병호;서이수
    • Journal of the Korean Magnetics Society
    • /
    • v.10 no.1
    • /
    • pp.42-47
    • /
    • 2000
  • In the present work, we analyze theoretically the flow of magnetic fluids in a circular pipe with longitudinal magnetic field. We used governing equations induced Shliomis and Polar theory of Eringen. Using theoretical equations and distributions for the velocity, vorticity and angular velocity as the magnetic response, it is shown that magnetic fluid flow is non-Newtonian fluid. We investigate dynamic characteristic of magnetic fluid by comparing longitudinal magnetic field with transverse magnetic field. And, the limits, influence magnetic fluid, of the intensity of the magnetic field with polar, size and magnetic effect parameters are shown.

  • PDF

Exposure Measurements of Co-60 Gamma rays (Co-60 감마선의 조사선량 측정)

  • Hah, Suck-Ho;Kim, Hyun-Moon
    • Journal of Radiation Protection and Research
    • /
    • v.16 no.2
    • /
    • pp.7-16
    • /
    • 1991
  • Measurement of Co-60 gamma rays has been made for establishment of exposure standard and analyze it's overall uncertainties. Exposure rate determined by the charge mode method using vibrating reed amplifier with cylinderical type cavity chamber. The values of a variety of physical constants and the correction factors are evaluated. The resulting exposure rate is 690.81 R/h at the distance of 1m from the source and the related uncertainties is ${\pm}0.8%$

  • PDF