• Title/Summary/Keyword: 균질기

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Sintering Behavior and Mechanical Strength of Hydroxyapatite/Polyacrylic Acid Homogeneous Composite (Hydroxyapatite/Polyacrylic Acid 균질복합체의 소결 특성 및 기계적 강도)

  • 이병교;이석기;구광모;이미혜;이형동
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.566-571
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    • 2003
  • Hydroxyapatite (HAp)/Polyacrylic Acid(PAA) homogeneous composites of four different composition ratio were preparation by co-precipitation process with synthetic HAp and PAA as a binder. HAP/PAA composites were molding by cold isostatic pressing and were sintering by various condition in air. Crystallinity and structure of sintered HAp/PAA composites were investigated by XRD and FT-IR. Also, the compressive strength and the fracture surface of sintered specimens were measured by UTM and SEM. HAp/PAA composites were showed phase transformation of partially ${\alpha}$, ${\beta}$-tricalcium phosphate at sintering condition of 1200$^{\circ}C$ and 3 h. The pore size and porosity of sintered body were showed the range of 0.2∼3.0 $\mu\textrm{m}$ and 0.49∼13.43%, respectively. The compressive strength of sintered specimens were appeared the range of 36.6∼58.2 MPa. From these results, the sintered HAp/PAA comosites can be accounted for the microporous HAp having a good compressive strength due to homogeneous pore morphology.

Preparation and Characteristics of Heterogeneous Cation Exchange Membrane : 2. Characteristics Change on Post-treatment (PE계 불균질 양이온 교환막의 제조와 특성 : 2. 후처리에 따른 특성 변화)

  • Yang, Hyun S.;Cho, Byoung H.;Kim, Woong K.;Lee, Chang S.
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.67-75
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    • 1997
  • Heterogeneous cation exchange membrane consisting of cation exchange resin particles (diameter of less than $149{\mu}$) which are finely dispersed in a polyethylene matrix, were produced as forms of sheet. The characteristics were measured after treating hot water or saturated sodium chloride. When membranes were treated with hot water or saturated sodium chloride, cation exchange resin particles swell and expand pushing away the polyethylene matrix of membranes. The above treatment results the formation of narrow cavities between a cation exchange resin particles and polyethylene matrix, and the formation of fine micro-cracks on the polyethylene matrix. Thus, we were obtained good physical and electrochemical properties. On the treatment with hot water or saturated sodium chloride, the optimum conditions for good heterogeneous cation exchange membrane were treatment time of 30min and treatment temperature of $90^{\circ}C$.

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Formation and Interface Mophologies of the Epitaxial $\textrm{CoSi}_2$ Using the Chemical Oxide on Si(100) Substrate (화학적 산화막을 이용한 epitaxial $\textrm{CoSi}_2$형성과 계면구조)

  • Sin, Yeong-Cheol;Bae, Cheol-Hwi;Jeon, Hyeong-Tak
    • Korean Journal of Materials Research
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    • v.8 no.10
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    • pp.912-917
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    • 1998
  • 화학적 산화막(SiOx)이 형성된 Si(100)기판 위에 Co-silicide의 형성과 계면 형상에 관한 연구를 하였다. 화학적 산화막은 과산화수소수(H2O2)의 인위적 처리에 의해 약 2nm을 형성시켰다. 그 위에 5nm 두께의 Co 박막을 전자빔 증착기에 의해 증착시킨 후 열처리하여 Co-silicide를 형성하였다. 화학적 산화막 위에서 Co-silicide 반응기구를 알아 보기 위해 $500^{\circ}C$-$900^{\circ}C$의 온도 범위에서 ex-situ와 in-situ 열처리를 하였다. 이와같이 형성된 Co-silicide 시편의 상형성, 표면 및 계면 형상, 그리고 화학적 조성을 XRD, SEM, TEM, 그리고 AES를 이용하여 분석하였다. 분석 결과 es-situ 열처리시 $700^{\circ}C$까지 CoSi2 상은 형성되지 않았고 Co의 응집화현상이 일어났다. $800^{\circ}C$ 열처리한 경우에는 CoSI2가 형성되었고 facet 현상이 크게 나타났으며 불연속적인 grain 들이 형성되었다. In-situ 열처리한 경우에는 저온에서 ($550 ^{\circ}C$)반응하여 Co-silicide가 형성되기 시작하였으며 $600^{\circ}C$부터는 facet에 의해 박막의 특성이 나빠지기 시작했다. $550^{\circ}C$에서 Co가 화학적 산화막 층을 통해 확산하여 균질한 Co-silicide를 형성하였다. 이와같이 형성된 균질한 실리사이드 층을 이용하여 다단계(55$0^{\circ}C$-$650^{\circ}C$-$800^{\circ}C$)열처리에 의해 균질한 다결정 CoSI2의 형성이 관찰되었다.

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A Study on Homogeneous Mixture Supply in a Multi-Cylinder Spark Ignition Engine - Effect on Combustion Characteristics - (다기통 전기점화기관의 균질혼합기 공급에 관한 연구 - 연소특성에 미치는 영향 -)

  • 김물시;이용길;박경석
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.8
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    • pp.2194-2200
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    • 1994
  • In an automotive spark ignition engine, it is important to form the proper mixture (air/fuel) on each driving condition for developing the stabilizing combustion and exhaust characteristics. Since most of supply fuel si attached on the inside wall of the intake manifold for unadequate nonuniformity of fuel distribution to each cylinder and mixture variation. Also it affects engine performance variation and causes noises and vibration. In this study, we verified the effect of the mixture variation which is caused by fuel liquid film in the intake manifold on combustion characteristics and engine performance.

Fracture Resistance and Integrity of Structural Materials for Major Nuclear Reactor Components (원자력발전소 주요부품 구조재료의 파괴 저항성 및 건전성)

  • 홍준화
    • Journal of the KSME
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    • v.35 no.6
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    • pp.481-494
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    • 1995
  • 원자로 압력용기 및 주 배관등 원자력발전소 주요부품 구조재료에서의 파괴저항성 및 건전성 문제를 일부 시험결과 및 평가결과와 함께 살펴보았다. 원자력환경하에서는 중성자 조사에 의한 조사취화 및 고온에서의 장기간 유지에 따른 열취ㅘ로 재료 고유의 파괴저항치가 가동에 따라 매우 감소하고, 이에 따라 부품의 건전성 및 수명이 매우 위협받고 있음을 확인하였다. 현재 가동중인 원자로 10기, 건설중인 8기, 합계 18기로 세계 9위의 원자력발전국이 되며, 대북 경수로 지원과 세계시장 진출을 계획하고 있는 우리나라에서는, 보다 안전한 원자력발전소가 건설되기 위해서, 재료의 균질성 및 파괴인성 개선연구, 조사특성 연구 등을 통해 파괴저항성이 우수한 국산소재를 제작\ulcorner공급하도록 하여야 한다. 또한, 수명기간 동안 고도의 건전성을 유지하면서 운전하고, 나아가 수명연장 운전을 위해서는, 용기 등 주요 부품의 상태(파괴인성치, 결함, 작용 응력)를 정확히 진단, 예측, 평가하여야 하고, 이들이 건전성에 미치는 영향평가와 건전성평가기술 확립을 통한 수명예측기술을 확보하여야 한다(이들은 대부분 파괴역학 시험 침 해석기술에 바 탕을 두고 있다). 국내 산\ulcorner학\ulcorner연 관련자들의 특별한 관심을 촉구하는 바이다.

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Design of the Symmetrical and Non-symmetrical Interdigitated Three-Line Four-port Microstrip Line Couplers in an Inhomogeneous Medium (비균질 매질내에서 대칭 및 비대칭구조를 갖는 3선 4포트 스트맆선 결합회로의 설계)

  • 진연강
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.10 no.6
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    • pp.287-295
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    • 1985
  • Analysis and design procedures for the symmetrical and non-symmetrical interdigitated four-port microstrip couplers conssiting of symmetrical three lines is presented. The configuration is simple and a lesser number of bond wires are requires as compared to the four-line couplers which are used. Physical dimensions of 3. 6 and 10dB couplers with substrates having typical dielectric constant values of 2.55 and 10 can be found by using the tables and charts.

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Formation and Microstructural Properties of C49 $\textrm{ZrSi}_{2}$ Thin Films on Si(100)Substrates (Si(100)기판위에서의 C49 $\textrm{ZrSi}_{2}$의 형성과 특성 연구)

  • Kim, Sang-Beom;Jeon, Hyeong-Tak
    • Korean Journal of Materials Research
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    • v.7 no.11
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    • pp.964-968
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    • 1997
  • Si(001)기판 위에 형성시킨 Zr-silicide의 전기적, 물리적 특성에 관한 연구를 하였다. Zr 박막은 전자빔 증착기를 사용하여 증착하였으며, 50$0^{\circ}C$ 열처리하여 Zr-silicide를 형성시켰다. 각 온도에서 열처리된 Zr-silicide시편의 상형성, 전기적 특성, 화학적 조성, 표면 및 계면 형상을 XRD, four-point probe, AES, TEM과 HRTEM으로 분석하였다. 분석 결과 $600^{\circ}C$부터 Zr과 Si기판의 계면에서 C49 ZrSi$_{2}$의 생성이 관찰되었다. Zr-Silicide박막의 비저항은 C49 ZrSi$_{2}$의 형성에 영향을 받는 것으로 관찰되었으며, 50$0^{\circ}C$ 열처리 후에는 184.3 $\mu$Ω-cm로 낮아졌으며, C49 ZrSi$_{2}$가 박막에 완전히 형성된 80$0^{\circ}C$ 열처리 후에는 32$\mu$Ω-cm의 낮은 저항을 나타내었다. 형성된 C49 ZrSi$_{2}$박막은 균질한 화학적 조성을 하고 있음을 AES 분석으로 확인하였다. Zr-silicide의 표면 및 계면의 형상을 TEM과 HRTEM으로 관찰하였으며, $600^{\circ}C$ 열처리 후에 계면에서 ZrSi$_{2}$의 상형성이 시작되는 것을 관찰하였다. 80$0^{\circ}C$ 열처리 후에도 계면과 표면형상은 비교적 균질한 형상이 유지되었음이 관찰되었으며, 이는 C49 ZrSi$_{2}$가 높은 온도에서도 잘 응집되지 않으며 고온 안정성을 가지는 재료임이 관찰되었다.

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Capacitively Coupled Radio Frequency Discharge System for Excitation of Gas Laser (기체레이저의 여기를 위한 용량결합고주파(ccrf) 방전시스템)

  • Choi, Sang-Tae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.1
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    • pp.19-26
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    • 2006
  • The ccrf-discharge has in comparison with the hollow-cathode discharge and DC-discharge some advantages: Simple design of the tube and homogeneous plasma. The ccrf-discharge was researched with the goal, to use on the excitation of the gas laser. In this work a rf-exciting system was planned and developed. With it a homogeneous discharge was produced in the cw operation. To supply the rf-power with the frequency 13.56[MHz] effectively in the discharge, laser tube were used with inner diameter of 5[mm] and the specially developed rf-electrodes. A matching circuit was composed also. Thereby the impedance of the discharge tube was adjusted to the 50[$\Omega$] output resistance of the rf-source.

Dispersion Properties of Epoxy-layered Silicate Nanocomposites Using Homogenizer (균질기를 이용한 에폭시-층상 실리케이트 나노콤포지트 분산 특성)

  • Lee, Sang-Keuk;Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.2
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    • pp.126-133
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    • 2013
  • This paper presents a study on the dispersion effect of the X-Ray diffraction, glass transition and DMA properties of organic modifier clay/epoxy nanocomposites produced in a homogenizer. Several experiments were conducted including different types of dispersion condition with varying processing conditions such as homogenizer rotor speed and applied time of homogenizer. The effects of these variables on the dispersion properties of nanocomposites were then studied. In order to fully understand the experimental results, a X-ray diffraction, DSC and DMA were used to investigate the effect of above mentioned variables on microstructure and intercalation/exfoliation of organic modifier clay/epoxy nanocomposites. The results from this work could be used to determine the best processing condition to obtain appropriate levels of d-spacing, glasss transition temperature and storage modulus in organic modifier clay/epoxy nanocomposites.

A Study on Topology Optimization of Table Liner for Vertical Roller Mill using Homogenization Method (균질화법을 이용한 수직형 롤러 분쇄기용 테이블 라이너의 위상최적설계에 관한 연구)

  • 이동우;홍순혁;조석수;이선봉;주원식
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.6
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    • pp.113-122
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    • 2003
  • Topology optimization is begun with layout optimization that is attributed to Rozvany and Prager of the 1960's. They claimed that structure was transformed into truss connecting all the nodes of finite element and optimized by control of its sectional modulus. But, this method is partial topology optimization. General layout optimal design appliable to continum structure was proposed by Bendsoe and Kikuchi in 1988. Topology optimization expresses material stiffness of structure into function of arbitrary variable. If this variable is 1, material exists but if this variable is 0, material doesn't exist. Therefore, topology optimization searches the distribution function of material stiffness for structure. There are a few researchs for simple engineering problem such as topology optimization of square plane structure or truss structure. So, This study applied to topology optimization of table liner for vertical roller mill that is the largest scale in the world. After table liner decreased by 20% of original weight, the structure analysis for first optimized model was performed.