• Journal of the Korean Chemical Society
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• v.30 no.2
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• pp.166-171
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• 1986

Hydrogen atom transfer reactions, $RNH_2+CH_3{\to}RNH+CH_4\;where\;R=H\;and\;CH_3$, were studied by MINDO/3 MO method. It is expected that stable complex may exist between $CH_3\;and\;NH_3$. Transition state characteristics and activation parameters including activation entropies have been determined. In cases of absolute and activation entropies, results are found to agree in general with ab initio and experimental values, wherever comparisions are possible.

• Journal of the Korean Chemical Society
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• v.23 no.3
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• pp.119-124
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• 1979

The cyclization of o-terphenyl type compounds were interpreted by means of orbital symmetry theory and energy correlation diagram. Results show that the cyclization of o-terphenyl type compounds are photocyclization. This agrees with the experimental result and other theoretical ones.

• Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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• 2003.04a
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• pp.300-304
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• 2003

기상위성은 그 특성상 다양한 Imager, Sounder, 그리고 여러 환경 테스트용 장비를 지니게 되며 일정한 시간동안 지구에 그 정보를 전송한다. 본 논문에서 제안된 수신 시스템은 현재 운영중인 아리랑위성 1호의 임무계획에 필요한 기상정보를 직접 획득하여 운영의 효율성을 높일 필요성에 의해서 GMS-5의 S-VISSR data 뿐만 아니라 2003년 4월 이후에 서비스를 할 것으로 예정된 GOES-9위성의 GVAR data도 역시 수신 및 처리를 할 수 있도록 설계되었다. Link budget 설계를 수행하여 최악의 경우에도 영상을 복원할 수 있는 통신링크가 제공되도록 설계하였고, 시스템 구성 모듈을 가능한 한 상용제품으로 사용하였다. 설치된 후에는 태양을 이용한 G/T의 값을 측정하여 설계치 보다 약1.608 향상된 시스템임을 검증하였고, 수신된 GMS-5의 S-VISSR 데이터를 성공적으로 처리함으로써 자체적으로 개발한 처리 소프트웨어를 검증하였다.

• Proceedings of the KIPE Conference
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• 2006.06a
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• pp.166-168
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• 2006

새로운 도시교통 시스템을 개발하기 위하여 시스템의 적용지역 검토 후 운영자, 이용자, 공급자 측면에서의 요구사항 도출과 아울러 이를 토대로 하여 시스템 요구사항을 도출하였다. 이는 기능 및 성능으로 구분할 수 있고 하부시스템별로 기능과 성능을 할당하여 각 하부시스템의 기능과 주요 장치가 갖추어야 할 조건, 용량 등을 정의하였다. 또한 환경요구사항 및 하부 시스템별 기기의 동작 조건등을 정의하여 시스템 개념을 확립하였다.

• Journal of the Korean Chemical Society
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• v.24 no.5
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• pp.337-341
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• 1980

Radical formation reaction of phenolic antioxidants were examined MO theoretically. Results show that substitution of electron-donating alkyl groups in phenol increases the rate of phenoxy radical formation when attacked by an electrophilic radical by stabilization of cationic transition state.

• Journal of the Korean Chemical Society
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• v.13 no.4
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• pp.281-287
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• 1969

Rate constans for the chloride exchange of some arylmethylchloride in dry acetone have been determined, and activation parameters have been evaluated. The reactivities of substates are explained with perturbational molecular orbital (PMO) method and HSAB principle. It was found that carbon-chlorine resonance integral at the transition state is a out 67% of ${\beta}$, the carbon-carbon resonance integral.

• Journal of the Korean Chemical Society
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• v.29 no.1
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• pp.3-8
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• 1985

Molecular electronegativity (EN) values are calculated employing the density functional definition of EN: the negative of the chemical potential in the density functional theory. Calculations are limited to the use of valence electrons (valence electron approximation). Our formula for the EN is given in terms of Hartree-Fock(HF) orbital energies. Resulting EN values for molecules as well as atoms exhibit a remarkable correlation with other existing scales. For molecules, we have achieved electronegativity equalization principle (Sanderson's principle).

• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.85-91
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• 1981

In order to discuss the existence of the biindenyl dianion, we chose the 2, 3-dimethyl butadiene as a model compound and attempted the CNDO/2 calculations for its monoanino and dianion. We investigated the changes in the electronic structures by means of the partial geometry optimization. We found the stability effects on dianion were markedly different from those on monodianion.

• Journal of the Korean Chemical Society
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• v.16 no.6
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• pp.329-333
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• 1972

Chloramphenicol molecule has an asymmetric carbon, so it has conformational isomer, namely, threo and erythro form. These two forms have great difference in biological activity, that is, only threo (-) form has biological activity. Semiempirical quantum mechanical treatments are applied to these molecules to explain the difference, using the extended Huckel theory. The theoretical predictions for the preferred conformation are in good agreement with the experimental results.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1999.05a
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• pp.210-215
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• 1999

In this paper, a new approach to the dynamic control technique for track vehicle system using fuzzy-neural network control technique is proposed. The proposed control scheme uses a Gaussian function as a unit function in the neural network-fuzzy, and back propagation algorithm to train the fuzzy-neural network controller in the framework of the specialized learning architecture. It is proposed a learning controller consisting of two neural network-fuzzy based on independent reasoning and a connection net with fixed weights to simply the neural networks-fuzzy. The performance of the proposed controller is shown by simulation for trajectory tracking of the speed and azimuth of a track vehicle.