• Title/Summary/Keyword: 구리 영향

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Effect of Soil Properties on Leaching of Preservative Components from CCA-treated Wood (토양 특성이 CCA 처리재로부터 방부제 성분의 용탈에 미치는 영향)

  • Jeong, Yong Gi;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.87-94
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    • 2005
  • This study was carried out to investigate the effect of soil types and soil properties on wood preservative leaching. Radiata pine (Pinus radiata Don.) sapwood stakes, which had been treated with 2.0%(w/v) CCA, were leached for 12 weeks by a common laboratory method in four different soils and for 14 days by the AWPA standard leaching method in water. The physical and chemical properties of the four soils were determined, and the percent leaching of the individual component of CCA was correlated with the various soil properties. The data show that leaching of preservative chemicals from treated wood exposed to soil is influenced by the type of soil. The preservative leaching was greater when wood was exposed to water than when the wood was in contact with water-saturated soil. The greatest chromium, copper and arsenic leaching from CCA-treated stakes were observed in the sandy loam, loam, and sand, respectively, and the least amount of leaching of CCA components occurred in the silty loam. The leaching of preservative components from treated wood is extremely complex and appears to be influenced differently by the soil properties. The extent of copper leaching from CCA treated wood appears to be related to exchangeable Mg and sum of bases. There is a reasonably good relationship between chromium leaching and exchangeable Mg, and between arsenic leaching and exchangeable K, soil Ni, Mn, Fe, Cr, or Cu content. Since this study was conducted based on laboratory leaching method using small cross-sectional dimensions; thus, data obtained from this experiment should not be used to predict leaching characteristics from commercial-size wood used in real situation. Accordingly, further studies are necessary using outdoor ground-contact leaching.

Crab shell과 chemical sorbent의 중금속 제거능 비교에 관한 연구

  • 안희경;박병윤;김동석
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2000.05a
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    • pp.134-139
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    • 2000
  • Crab shell의 중금속 제거 가능성과 그 효율을 검토하기 위하여 chemical sorbent인 cation exchange resin(CER), zeolite, granular activated carbon(GAC), powdered activated carbon(PAC)의 중금속 제거능을 비교한 결과 다음과 같은 결론을 도출할 수 있었다. 1) 0.1 mM~l.0 mM의 초기 중금속 농도에서 중금속 제거량에 미치는 영향을 비교해 보았을 때 중금속 제거의 평형에 도달하는 시간은 농도가 높을수록 오래 걸렸으며 단위 흡착제 질량당 중금속 제거량은 초기 중금속 농도가 높을수록 증가하였다. 특히 구리 이온 제거 실험에서는 낮은 농도에서 crab shell의 구리 이온 제거량이 CER의 경우보다 조금 떨어지는 경향을 보였으나, 대부분의 중금속 제거에 있어서는 crab shell이 다른 chemical sorbent에 비해 뛰어난 중금속 제거능력을 보였다. 2) 흡착 등온 모델에 적용해 보았을 때, 단위 흡착제 질량당 중금속 최대 흡착량이 crab shell > CER > zeolite > PAC =GAC의 순으로, 모든 중금속 제거 실험에서 crab shell이 가장 뛰어난 것으로 나타났다. 실제 폐수처리 공정에서는 GAC나 PAC가 많이 이용되고 있는데, 수중의 중금속을 보다 효율적이고 경제적으로 처리할 수 있는 crab shell을 폐수처리 공정에 응용할 수 있는 방안을 검토할 필요성이 있을 것으로 판단된다.

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The Effect on Copper Dissolution from Copper Cookware by Acid Condiments (구리냄비의 구리용출에 미치는 산성조미료의 영향)

  • ;;;;南出隆久
    • Journal of the East Asian Society of Dietary Life
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    • v.10 no.3
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    • pp.239-244
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    • 2000
  • Effects of acetic acid, malic acid and citric acid on copper dissolution from new and used copper saucepans at different concentrations (0, 0.02. 0.04, 0.1 0.2, 0.4, 1.0, 2.0, 4.0%), different boiling times (0,10, 20. 30, 40, 50, 60mins.), and different temperatures (5, 20, 40, 60, 80, 10$0^{\circ}C$ ) were investigated. As acetic acid concentration increases, copper content increases. Copper dissolution concentration from copper saucepans at boiling in malic acid increases more than in acetic acid or citric acid. At above 6$0^{\circ}C$, as the temperature increases, the concentration of copper dissolved from copper saucepans also increases. As boiling time increases, the concentration of copper dissolved from copper saucepans also increases. In addition, through repeated use, the concentration of copper increases as well. And copper concentration dissolves in large amounts from used saucepans rather than new saucepans. The dissolution of copper with distilled water by repeated use does not dissolve at all. 1% acetic acid dissolves in large quantities.

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The Effect of Lubricant Containing Copper Alloy Fine Particles on a Marine Diesel Engine (극미세 구리합금입자(NICO)를 이용한 특수윤활유가 박용기관 성능에 미치는 영향)

  • 소병두;임희성;박권하
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2000.11a
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    • pp.61-67
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    • 2000
  • Many research works for improving a boundary lubrication performance have been executed by using solid lubricants, and been tried to apply an engine lubrication. However those general lubricants like MoS$_2$ or PTFE have not been applied on engines due to the extreme conditions such as very high temperature and pressure by combustion process in a cylinder. A copper nickel alloy fine particle has been introduced and studied. In this Paper the lubricant using the alloy Particles is applied on a marine diesel engine and assessed by the engine performance test The results showed the increase of cylinder pressure related strongly to the engine efficiency as well as the improving the engine lubrication performance.

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The effects of nanofluid containing metal nano-powder on heat transfer (나노금속분말을 혼합한 용액이 열전달에 미치는 영향)

  • Kim, Hye-Min;Choi, Soon-Ho;Jeong, Jae-Hyun;Jeong, Jae-Hyun
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.177-182
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    • 2005
  • Many studies have been conducted to increase heat transfer in fluid. One of the various heat transfer enhancement techniques is to suspend fine metallic or nonmetallic solid powder in traditional fluid. Nanofluid is defined at a new kind of heat transfer fluid containing a very small quantity of nanometer particles that are uniformly and stably suspended in a liquid. In this study CuNi or CuAg nano particles are used to investigate heat transfer enhancement. The result shows the thermal conductivity of nanofluid is much higher than that of traditional fluid.

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Effect of Additives on Shape and Properties of Electrodeposited Cu Dendrite (수지상 구리 전기도금 시 형상 및 물성에 첨가제가 미치는 영향)

  • Park, Da-Jeong;Park, Chae-Min;Kim, Yang-Do;Gang, Nam-Hyeon;Lee, Gyu-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.327-328
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    • 2015
  • 본 연구에서는 전기도금법을 이용하여 수지상(Dendrite) 구리 분말을 제조할 때 첨가제 유무를 비교하였다. 인가전위, 첨가제의 종류(JGB, PEG) 및 농도에 따른 수지상의 형상적인 특성이 비교되었으며, 겉보기 밀도와 비표면적(BET)이 측정되었다. 형상적 특성은 수지상의 2차 가지와 추축의 두께 비(ratio)로 비교한 결과 JGB 첨가(10ppm) 도금욕에서 30.67로 가장 큰값을 가지며, 겉보기 밀도는 JGB 첨가(80ppm)에서 $1.115g/cm^3fh$ 가장 낮은값을 보였다.

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Effect of Surface Pre-treatment and Composition of Noble Metal Oxide on the DSE for High-rate Electroplating (표면 전처리 및 귀금속 산화물층 조성이 고속 전기도금용 DSE에 미치는 영향)

  • Son, Seong-Ho;Kim, Jin-Hwa;Park, Seong-Cheol;Kim, Hyeong-Mi;Jeon, Sang-Hyeon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.157-157
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    • 2015
  • 전기화학 성능이 우수하고 고내구성 고속 구리 전해도금용 DSE를 개발하기 위해 전기화학적 특성이 좋은 백금족 산화물의 조성비, 전처리 등의 공정으로 전극을 제조한 후, 고 전류밀도 조건에서 구리 전해도금을 실시하여 유기첨가제 소모율을 측정하여 최적의 전극제조 공정 조건을 확보하였다. 최적조건의 전극과 시제품 전극들을 비교분석한 결과, 상용 DSE와 비슷하거나 상회하는 내구수명을 가지는 것을 확인하였다.

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The Effect of Arsenic on Copper Electrodeposition in Copper-Sulfate Solutions in Copper-Electrorefining (동 전해정련시 황산구리 수용액 중의 Arsenic이 구리의 전해전착에 미치는 영향)

  • Kim, Do-Hyung;Kim, Yong-Hwan;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.42 no.3
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    • pp.103-108
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    • 2009
  • The effect of Arsenic in copper-sulfate solutions during electrorefining of copper was investigated using scanning electron microscopy, X-ray diffraction and cyclic voltammetry analysis. Electrodeposition was carried out using Arsenic, Antimony and bismuth addition to sulfate electrolytes: 45 g/l $Cu^{2+}$ and 170 g/l $H_2SO_4$. Arsenic in sulfate electrolytes changed the morphology and structure of the copper deposits as compared with those obtained from impurity free solutions. When arsenic was present in the sulfate electrolytes, $Cu-3$As intermetallic phase was formed locally on the deposits.

The Effect of Lubricant Containing Copper Alloy Nano-powder on Shafting Stability and Torque of a Diesel Engine (구리합금 나노분말을 혼합한 윤활제가 디젤기관의 축계안정성 및 토크에 미치는 영향)

  • Park, Kweon-Ha;Kim, Young-Nam;Kim, Young-Il
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.4
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    • pp.514-521
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    • 2008
  • Many research works for improving a boundary lubrication performance have been executed by using solid lubricants, and been tried to apply an engine lubrication. However those general lubricants have not been applied on engines due to the extreme conditions such as very high temperature and pressure during combustion process in a cylinder. In this study a lubricant containing copper alloy nano-powder is applied on a diesel engine driven by an electric motor. Torques and shaft vibrations are measured, then an engine friction loss and rotating stability are assessed. The results show that the frequency of the vibration is about the same as that of a general lubricant, but the amplitudes in the both X and Y direction are reduced as well as the friction loss is reduced.