• Journal of the Society of Cosmetic Scientists of Korea
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• v.41 no.2
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• pp.121-126
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• 2015

In general, the pearlescent pigment is a pigment which was used for optical characteristics like pearl, rainbow and metallic luster. Titanium dioxide coated mica plate developed by DuPont in 1965 is currently being used as a main part of pearlescent pigment for cosmetics. Although the smooth and clear surface substrate laminated with 2 ~ 3 ingredients is thicker than a previous monolayer coated substrate, it has been applied for cosmetics as the optical interference powder to realize stronger shine and brighter interference color than monolayer one. In this study, we developed a new optical interference powder with thinner and higher chroma than a current pearlescent pigment for the strong luster and bright interference color. It was prepared from the manufacturing process, in which the coated titanium dioxide precursor was changed and crystallized by coating and heat treatment process with a half of dividing the coated amount of titanium dioxide. We confirmed the dense coating of titanium dioxide grain with Scanning Electron Microscope and measured superior crystallization degree compared with a monolayer coated pearlescent pigment by X-ray Diffraction. It is concluded that our new pearlescent pigment had higher reflectivity of light and stronger interference color than previous products.

• Journal of Radiation Protection and Research
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• v.37 no.1
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• pp.50-55
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• 2012

To evaluate the ability of Dongchongxiacao ($Paecilomyces$ $japonica$) extract (PJE) to protect the skin from photodamage, the gross and microscopic changes in the skin of hairless mice and PJE-treated mice exposed chronically to ultraviolet (UV) were examined. The skin of the UV-irradiated mice showed characteristic signs of photoaging, such as deep wrinkles across the back. PJE-treated mice showed a significantly decreased wrinkling score. By the 22nd week, 88.9% (i.p. with saline) or 44.4% (topical administration with cream base) of the UV-irradiated mice developed at least one tumor. PJE delayed tumor onset significantly. PJE (i.p.) was also effective in reducing the occurrence of UV radiation-induced skin tumors and reduced the number of tumors per mouse. After 22 weeks of treatment, 80.0% (i.p.) and 75.0% (topical) of the mice treated with PJE were tumor-free. Tumor multiplicity was reduced by 96.2% (i.p.) in the PJE treated groups. It is noted that skin that is chronically exposed to UV is subject to photoaging and photocarcinogenesis and regular use of PJE would prevent these photodamaging effects of UV.

• Proceedings of the Optical Society of Korea Conference
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• 2000.08a
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• pp.104-105
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• 2000

다이오드 레이저로 펌핑되는 Nd:YAG 매질에 형성된 열 복굴절은 레이저 출력과 빔질의 저하를 초래한다. 선편광된 레이저 출력을 얻기 위해서는 주로 공진기 내에 선형 편광자를 삽입하게 되는데, 레이저 매질에 형성된 열 복굴절에 의한 왜곡 편광된 레이저 빔이 편광자에 의해 반사되어 공진기 손실을 초래한다. 편광 왜곡에 의한 레이저 빔의 손실을 줄이거나 이중 초점을 제거하기 위해 주로 사용되어지는 광 소자는 Faraday 회전자, λ/4 판, 석영 회전자 등이 사용되어진다.$^{(1-5)}$ 90$^{\circ}$ 석영 회전자와 Faraday 회전자는 공진기 내에 두 개의 동일한 구조를 갖는 레이저를 이용할 경우 사용되고 λ/4 판 과 45$^{\circ}$ Faraday 회전자는 주로 단일 레이저 헤드의 복굴절 보상을 위해 사용되어진다. 45$^{\circ}$ Faraday 회전자는 이론적으로 완벽히 열복굴절에 의한 편광 왜곡을 보상한다. 그러나, 열복굴절을 완벽히 보상하기 위해서는 레이저 빔이 항상 레이저 매질의 같은 지점을 통과해야 한다. 실제적으로 레이저 매질에서는 열에 의한 열 렌즈 효과가 있기 때문에 레이저 빔이 항상 같은 지점을 통과하지 않게 된다. 이런 문제를 해결하기 위해 공진기 내에 열 렌즈 효과를 보상하기 위한 렌즈를 삽입하거나 레이저 헤드를 공진기 거울 가까이 설치하여야 한다. Faraday 회전자는 길이가 길기 때문에 레이저 헤드를 공진기 거울 가까이 설치하기는 어렵고 항상 열 렌즈 효과를 보상해주는 광학 소자가 있어야 하는 단점이 있다. 반면 λ/4 판은 완벽한 편광 왜곡을 보상해주지 않아 레이저 손실을 초래하지만 두께가 얇아 레이저 헤드와 공진기 거울을 근접해서 설치할 수 있어서 몇몇 연구자에 의해 연구되어 졌다.$^{(3)}$ 본 연구에서는 λ/4 판을 이용하고 편광기에서 반사된 빔을 공진기에 되반사 시키는 구조를 사용하여 선 편광된 레이저의 출력과 빔의 질을 개선 시켰다. (중략)

• Journal of Life Science
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• v.27 no.4
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• pp.383-389
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• 2017

This study intends to analyze the contents of rutin, procyanidin B3, quercetin, kaempferol, known to have antioxidant, anti-inflammatory and anti-carcinogenic effects, among the polyphenol type contained in the grape pruning stem extracts (GPSE), utilizing grape stems being discarded after harvest, measure the effects on the skin moisture, inhibition of skin cell proliferation, anti-inflammatory on the damaged skin of a HR-1 mice induced with UVB, and verify the applicability as a material for functional food and functional cosmetics. The results of verifying the photoprotection effects through the skin proliferation control through of GPSE showed similar result to suncream was achieved at the GPSE concentration of 2,000 mg/kg on the epidermis (p<0.05). The results showed anti-inflammatory effects on all groups applied with GPSE as compared to the control group irradiated with UVB, but at the GPSE concentration of 1,000 mg/kg, a lower COX-2 protein expression at 8%, lower than the 22% of suncream, was observed to achieve an excellent anti-inflammatory effect (p<0.05). The results of this study confirmed the existence of active polyphenol type, such as rutin, kaempferol, querocetin and procyanidin B3, within the GPSE, and GPSE has improvement effects on moisturizing effects, skin proliferation control effect, inflammatory control effect and improvement effects on the skin barrier function through UV ray damage. GPSE is a functional ingredient with a potential for skin protection effects, and has high utilization as an ingredient for functional food and functional cosmetics.

• Journal of the Korea Convergence Society
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• v.11 no.7
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• pp.157-162
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• 2020

In recent years, laser induced graphene process have been intensively studied for eco-friendly electronic device such as flexible electronics or thin film based energy storage devices because of its simple and effective process. In order to increase the performance and efficiency of an electronic device using such a graphene patterned structure, it is essential to study an optimized laser patterning condition as small as possible linewidth while maintaining the graphene-specific 2-dimensional characteristics. In this study, we analyzed to find the optimal line pattern by using a Ti:sapphire femtosecond laser based photo-thermal reduction process. we tuned intensity and scanning speed of laser spot for generating effective graphene characteristic and minimum thermal effect. As a result, we demonstrated the reduced graphene pattern of 30㎛ in linewidth by using a focused laser beam of 18㎛ in diameter.

• Korean Journal of Environmental Agriculture
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• v.21 no.2
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• pp.83-89
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• 2002

The effect of low dose $\gamma$ radiation on photosynthesis and the reduction of photoinhibition in red pepper plant was investigated. The seedling height leaf width and leaf length of pepper were stimulated in plants grown from seeds irradiated with the low dose of 4 Gy. The $O_2$ evolution in the 4 Gy irradiation group was 1.5 times greater than in the control. To investigate the effect of low dose $\gamma$ radiation on response to high light stress, photoinhibition was induced in leaves of pepper by illumination of high light (900 $\mu mol/m^2/s$). Pmax was decreased with increasing illumination time by 20% in the control, while hardly decreased in the 4 Gy irradiation group. The photochemical yield of PSII, estimated as Fv/Fm, was decreased with increasing illumination time by 50% after 4 hours while Fo did not change. However, Fv/Fm in the 4 Gy irradiation group was decreased by 37% of inhibition, indicating that the photoinhibition was decreased by the low dose $\gamma$ radiation. Changes in the effective quantum yield of PSII, $\Phi_{PSII}$, and 1/Fo-1/Fm, a measure of the rate constant of excitation trapping by the PSII reaction center, showed similar pattern to Fv/Fm. And NPQ was decreased after photoinhibitory treatment showing no difference between the control and the 4 Gy irradiation group. These results showed the positive effect of low dose $\gamma$ radiation on the seedling growth and the reduction of photoinhibition.

• Applied Chemistry for Engineering
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• v.24 no.6
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• pp.605-610
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• 2013

Gamma-aminobutyric acid (GABA) is a non-protein amino acid widely present in organisms, which has shown several important physiological functions such as neurotransmission, hypotension induction, as well as diuretic and tranquilizer effects. They have also been extensively used in food industry. GABA contents in the grain and brown rice are about 1~4 mg/100 g and 4~8 mg/100 g, respectively but it is difficult to expect physiological activity from such low amounts of natural food intake. We investigate the effects of GABA-coated rice on the secretion of melatonin and serotonin which both have been used as sleep inductive compounds. As a result, the secretion of melatonin and serotonin from mice were found to be $3.578{\pm}0.158pg/mL$, $5.918{\pm}0.169ng/mL$ respectively. The melatonin and serotonin in mice increased significantly up to the 8.7 and 22.8 times respectively, when compared to that of the rice, but there was no cumulative effects. Due to the continuous intake of GABA-coated rice, which was developed as a functional food nutrient, inductive effects of melatonin and serotonin from general rice could be achieved and also the similar effect as taking up directly 25 mg/mL of GABA could be obtained.

• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.569-574
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• 1991

Six free base porphyrins were synthesized by reacting pyrrole with benzaldehyde or its derivatives and then reacted with metal chlorides to prepare corresponding metal complexes. In addition, polymer-bonded porphyrins were synthesized by treating chloromethylated styrene-divinyl benzene (1%) copolymer beads with meso-tetra (p-aminophenyl)porphyrin (TNPP) solution and then treated with cupric chloride to obtain Cu(Res-NH-TPP-$NH_2$). The porphyrin compounds were characterized by visible, inffrared and electron spin resonance spectral analyses. The metal contents of metalloporphyrins were determined by atomic adsorption spectrophotometry. The synthesized porphyrin compounds were subsequently examined for their catalytic strength and found the activity to increase in the following order: free base porphyrins; metalloporphyrins; polymer-bonded metalloporphyrin. Among metalloporphyrins, Cu-TNPP showed the greatest catalytic power.

• Journal of Energy Engineering
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• v.26 no.4
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• pp.107-117
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• 2017

Since South Korea started to apply Renewable Portfolio Standard (RPS) in 2012, there have been huge investment for deploying renewable technologies. Recently, the government determined to incentivize battery energy storage system(BESS) with renewable generations in order to induce the improvement of dispatching capability. In this paper, the annual pattern of PV generation based on actual generation data in South Korea is analyzed and the duration curve of capacity factor is proposed in order to provide the simplified analyzing methodology of present support policy for additional BESS installation for decision maker who is responsible for supply and demand planning. With suggested methodology, the range of appropriate BESS size with respect to the variation of system marginal price(SMP) and renewable energy certificate(REC) price can be derived briefly, and decision makers easily evaluate the effect of support scheme. Current policy for BESS installation support present additional BESS-related installation policy may give incentives to developers partially, however, the dependence between BESS size and benefit components (SMP and REC) can limit the deployment of the various portfolios of the BESS. Therefore, when improving the current policy in future, addressing the dependence between the technical aspects of battery size and the benefit components separately by the technical and economical parts is needed to set the suitable compensation rules for the renewable generation and BESS.

• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.650-656
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• 1995

Rate Constants of hydrolysis of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl chlorides were determined by UV spectrophotometry in 50% (v/v) aqueous methanol at 25$^{\circ}C.$ On the basis of rate equation, substituent effect, solvent effect, salt effect, thermodynamic parameters and hydrolysis product analysis, it may be concluded that the hydrolysis of N-(benzenesulfonyl)-C-(N-methylanilino)imidoyl chlorides proceed through $S_N1$ mechanism via azocarbonium ion intermediate below pH 9.0, while aebove pH 10.0 the hydrolysis proceeds through nucleophilic addition-elimination ($Ad_{N-E}$) mechanism.