• Title/Summary/Keyword: 광화학적

Search Result 297, Processing Time 0.027 seconds

A Study on the Characteristics of Natural VOC Emissions from Pine Trees in Season (계절별 소나무로부터 배출되는 자연 VOC(NVOC) 배출특성에 관한 연구)

  • 김조천;임준호;홍지형;전의찬;주명칠;조규탁
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2003.05b
    • /
    • pp.93-94
    • /
    • 2003
  • 대기 중 휘발성유기화합물(Volatile Organic Compounds)은 인간에게 직접적으로 위해한 영향을 준다는 보건학적인 측면과 광화학스모그 생성에 관여한다는 이유 등으로 많은 주목을 받고있다. 식생은 자연 VOC(NVOC)의 가장 주요한 배출원이며, 대기중으로 유입되는 반응성이 강한 탄소의 주요한 배출원이며, 전 세계적으로는 NVOC의 배출량이 인위적인 것의 약 7배정도에 이를 것으로 추정되고 있다. 우리나라의 경우 전 국토의 2/3이상이 산림으로 이루어져 있어 NVOC가 인위적인 VOC의 양을 훨씬 초과할 것이라고 사료된다. (중략)

  • PDF

Stochastic Properties of Air Quality Variation in Seoul (서울시 광화물 지역의 대기질 변동 특성의 추계학적 분석)

  • Han, Hong;Kim, Young-Sik
    • Journal of Environmental Health Sciences
    • /
    • v.17 no.2
    • /
    • pp.1-8
    • /
    • 1991
  • The stochastic variance and structures of time series data on air quality were examined by employing the techniques of autocorrelation function, variance spectrum, fourier series, ARIMA model. Among the air quality properties of atmosphere, SO$_{2}$ is one of the most siginificant and widely measured parameters. In the study, the air quality data were included hourly observations on SO$_{2}$ TSP and O$_{3}$. The data were measured by automatic recording instrument installed in Kwanghwamoon during February and March in 1991. The results of study were as follows 1. Hourly air quality series varied with the domiant 24 hour periodicity and the 12 hour periodic variation was also observed. 2. The correlation coefficients between SO$_{2}$ and O$_{3}$ is -0.4735. 3. In simulating or forecasting variation in SO$_{2}$ ARIMA models are on a useful tools. The multiplicative seasonal ARIMA (1, 1, 0) (0, 2, 1)$_{24}$ model provided satisfactory results for hourly SO$_{2}$ time series.

  • PDF

Multiple Angiomyolipoma of the Liver - Report of a Case with Diagnosis by Fine Needle Aspiration Cytology - (간의 다발성 맥관근지방종 - 세침흡인 세포학적 검사로 진단한 1예 보고 -)

  • Yim, Hyun-Ee;Park, Kwang-Wha;Lee, Kyi-Beom
    • The Korean Journal of Cytopathology
    • /
    • v.9 no.1
    • /
    • pp.79-84
    • /
    • 1998
  • Angiomyolipoma(AML) of the liver is a rare benign tumor; about 50 cases, almost solitary, have been reported. We present here a extremely rare case of multiple AML in the liver diagnosed by fine needle aspiration cytology(FNAC). Two large masses were found in a 51 year-old woman complaining of abdominal discomfort by computed tomography and several smaller masses are scattered in the liver. FNAC was performed, showing bundles of spindle shaped smooth muscle cells intermingled with mature fat cells. FNAC may be a valuable method for definitive diagnosis of hepatic AML. The diagnosis was further confirmed by histologic examination with immunohistochemical studies.

  • PDF

Pulmonary Nocardiosis Diagnosed by Fine Needle Aspiration - A Case Report - (세침흡인 세포학적 검사로 진단한 폐의 Nocardiosis - 1예 보고 -)

  • Yim, Hyun-Ee;Park, Kwang-Hwa
    • The Korean Journal of Cytopathology
    • /
    • v.6 no.2
    • /
    • pp.169-173
    • /
    • 1995
  • Nocardia, aerobic members of the order of Actinomycetaceae, produces infections in human lung. Nocardial infection is associated with underlying diseases of immuno-suppression or treatment with corticosteroid. It is difficult to detect Nocardia by sputum examination or histologic sections and it has rarely been diagnosed by fine needle aspiration of the lung. We describe a case of pulmonary nocardiosis in a 72 year-old man, diagnosed by fine needle aspiration, which was confirmed by culture of aspirates. The aspirates showed neutrophil-predominant inflammatory cells with microorganisms demonstrated by Gomori methenamine silver and Gram stain. The organisms had characteristic long blanching filamentous structures. The lesions on chest X-ray were in resolution with antimicrobial therapy.

  • PDF

The Role of Planetariums in Astronomy Education (천문학 교육에서 천체투영관의 역할)

  • Kim, Wansoo;Shim, Hyunjin
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.42 no.1
    • /
    • pp.48.2-48.2
    • /
    • 2017
  • 올해는 1967년 광화문 우체국에 설치된 천체투영관을 시작으로 국내에 천체투영관이 도입된 지 50주년이 되는 해이다. 지방자치제의 시행과 더불어 디지털 투영기가 보급되면서 국내 천문시설은 급격히 증가하게 되었고, 현재 국내에는 약 80곳의 천체투영관이 있으며 연간 약 250만명이 방문하는 인기 있는 천문시설 중 하나로 자리 잡게 되었다. 하지만 현재의 천체투영관은 영상물 상영 위주의 운영이 주를 이루고 있고 교육 시설로의 활용은 부족한 편이다. 반면 해외에서는 1960년대부터 학교와 지역사회에서 천체투영관을 활용한 교육이 활발하게 이루어지고 있다. 또한 천체투영관의 교육적 효과에 대한 연구도 지속적으로 이루어지고 있으며 천문학적 개념 형성에 긍정적인 효과가 있는 것으로 나타나고 있다. 따라서 본 발표에서는 해외에서 이루어지고 있는 천체투영관을 활용한 다양한 방식의 연구방법과 사례를 살펴보고 현재 국립대구과학관에서 개발하여 운영 중인 프로그램과 활용방법에 대해 소개하고자 한다.

  • PDF

Effect of Urea on the Rose Bengal Sensitized Photocurrent (Rose Bengal 감응 광전류에 미치는 Urea의 영향)

  • Yun, Gil Jung;Gang, Seong Cheol;Kim, Gang Jin
    • Journal of the Korean Chemical Society
    • /
    • v.34 no.6
    • /
    • pp.600-605
    • /
    • 1990
  • Electron injection from excited rose bengal into the conduction band of a thin film of SnO$2$, semiconductor was investigated in an electrochemical cell, ITO/SnO$2$/rose bengal, NaClO$4$/Pt. It was observed that urea enhanced the supersensitized photocurrent, followed by the reduction in the photocurrent after a shallow maximum. Spectroscopic analyses of the dye solution containing urea revealed that dye aggregation appeared to be involved in the increased photocurrent, although the concentration of the dye was continuously decreased dye to photochemical reactions.

  • PDF

충남 삼성광산의 견운모화작용에 관한 광물학적 및 성인적 연구

  • 김원사;신현숙
    • Proceedings of the Mineralogical Society of Korea Conference
    • /
    • 2003.05a
    • /
    • pp.44-44
    • /
    • 2003
  • 충남 청양군에 위치한 삼성광산은 견운모 광석을 채광하는 광산이다. 이 광산의 주변 지질은 선캠브리아기의 화강편마암과 운모 편암 및 호상 편마암, 그리고 이를 관입한 흑운모 화강암으로 구성되어있다. 견운모광체는 화강편마암내에 발달하고 있으며, 견운모화되는 과정은 모암의 구성광물이 변질되어 형성된 것으로서, 이들 광물이 순서적으로 견운모로 변질되는 현상을 관찰할 수 있었다. 즉, 정장석이 제일 먼저 견운모로 변하며, 그 다음으로 사장석, 석영, 백운모 등의 순서로 각각 변질됨을 알 수가 있었다. 견운모화작용이 진행되어 감에 따라 모암으로부터 견운모광체로 근접할수록 SiO$_2$, CaO, $Na_2$O는 감소하는 반면, $Al_2$O$_3$, $K_2$O 등은 증가한다. 견운모 광화작용은 쥬라기의 흑운모 화강암의 관입과 성인적으로 연관된 것으로 믿어진다.

  • PDF

Studies on the Geology and Geochemistry in the Beonam Mine, Korea (전북 번암광산의 지질과 지화학적 연구)

  • Chung, Jae-Il;Na, Choon-Ki;Lee, Young-Up;Jeon, Seo-Ryeong;Kim, Seon-Young
    • Economic and Environmental Geology
    • /
    • v.28 no.6
    • /
    • pp.623-633
    • /
    • 1995
  • The Beonam deposits which is located in south-western part of Sobaeksan massif are emplaced along $N20{\sim}30^{\circ}E$ trending fissures in Precambrian Sobaeksan gneiss complex. Surrounding granites are inferred to be differentiated and formed from calc-alkaline magma which was generated from remelting or partial melting of the crustral material having igneous composition. The Sr isotope data of ore minerals showing significantly low initial Sr value relative to those of surrounding granite batholiths suggest that the ore-bearing fluid formed the Beonam Au-Ag mine are isotopically distinct from those of the wall rocks, and it indicates that there is no evidence of genetic relationship between ore-bearing fluids and surrounding granites, although further study should be needed. The results of paragenetic studies suggest three stages of hydrothermal mineralization; stage I: base-metal sulfides stage, stage II: late base-metal sulfides, electrum and silver-bearing sulfosalts stage, stage III: minor silverbearing minerals, barren quartz and carbonates stage. The temperature, salinity and pressure of the Beonam deposits estimated from mineral assemblage, chemical composition, fluid inclusion and sulfur isotope geothermometry are as follows; stage I: $200{\sim}315^{\circ}C$, 3.5~6.5 NaCl eq. wt%, 0.28~0.61 Kbar, stage II: $150{\sim}235^{\circ}C$, 4.5~7.4 NaCl eq. wt%, 0.11~0.15 Kbar. The estimated oxygen and sulfur fugacity during first stage mineralization, based on phase relation of associated minerals, range from $10^{35.1}{\sim}10^{-39.7}$ atm. and $10^{-11.0}{\sim}10^{-13.4}$ atm., respectively. All these evidences suggest that the Beonam deposits are polymetallic meso-epithermal ore deposits.

  • PDF

Effects of Low Dose $\gamma$-Radiation on the Growth, Activities of Enzymes and Photosynthetic Activities of Gourd (Lagenaria siceraria) (저선량 $\gamma$선 조사가 참박의 초기 생육과 효소 활성 및 광합성 능에 미치는 영향)

  • 이혜연;김재성;백명화;이영근;임돈순
    • Korean Journal of Environmental Biology
    • /
    • v.20 no.3
    • /
    • pp.197-204
    • /
    • 2002
  • Gourd seeds were irradiated with the doses of 0-20 Gy to investigate the effect of the low dose $\gamma$-radiation on the early growth and physiological activity. The stimulating effects of the low dose y- radiation on the early growth were not noticeably high, but were increased generally at 4-16 Gy irradiation group. The catalase and peroxidase activity of cotyledon from seeds irradiated with $\gamma$- radiation were increased at 8 Gy irradiation group. The photochemical activity of leaf was noticeably high at 4 Gy irradiation group. The photochemical yield of PSII, estimated as Fv/Fm, decreased with increasing illumination time by 50% after 4 hrs in the control and 8 Gy irradiation group, while Fo slightly increased. However, Fv/Em in the 4 Gy irradiation group decreased by 40% of inhibition, indicating that photoinhibition decreased by the low dose $\gamma$- radiation. Changes in the effective quantum yield of PSII, $\varphi_{PSII}$ and 1/Fo- l/Fm, a measure of the rate constant of excitation trapping by the PSII reaction center, showed similar pattern to Fv/Em. NPQ decreased by 70% after photoinhibitory treatment with showing similar pattern between the control and the irradiation group. These results showed the positive effect of low dose $\gamma$- radiation on the seedling growth and the reduction of photoinhibition in the 4 Gy irradiation group.

Organic Synthesis Based on Ruthenium Carbene Catalyzed Metathesis Reactions and Pyridinium Salt Photochemistry (루테늄 카벤 촉매 복분해 상호교환 반응과 피리듐 염 광화학반응을 이용한 유기 합성)

  • Cho, Dae-Won;Mariano, Patrick S.
    • Journal of the Korean Chemical Society
    • /
    • v.54 no.3
    • /
    • pp.261-268
    • /
    • 2010
  • In this account, three synthetic methodologies that serve as the basis for new strategies for the preparation of selected natural products are briefly introduced. One process, involving ruthenium carbene catalyzed ring rearrangement metathesis developed by Grubbs and his coworkers, transforms alkene-tethered cycloalkenes to thermodynamically more favored alkene-tethered cycloalkenes. Another ruthenium carbene promoted reaction, referred to as dienyne metathesis, was uncovered in early studies by Grubbs and his collaborators. This process converts dienynes to fused bicyclic conjugated dienes. Finally, a novel photo-electrocyclization reaction of pyridinium salts, which leads to the formation of 4-aminocyclopenten-3,5-diol derivatives, is discussed. Examples are provided to show the utility of these methodologies in natural product synthesis. Emphasis is given to studies in which pyridinium salt photochemistry is coupled with ring rearrangement and dienyne metathesis in routes for the synthesis of polyhydroxyalted indolizidine alkaloids and the construction of the tricyclic core of the lepadiformine and cylindricine alkaloids.