• Title/Summary/Keyword: 광화유체

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Geochemical Exploration for a Potential Estimation on the Carlin-type Gold Mineralization in Northern Mt. Taebaek Mining District, Korea (태백산 광화대 북부에서 칼린형 금광화작용 부존 잠재력 평가를 위한 지구화학 탐사)

  • Sung, Kyu-Youl;Park, Maeng-Eon;Yun, Seong-Taek;Moon, Young-Hwan;Yoo, In-Kol;Kim, Ryang-Hee;Shin, Jong-Ki;Kim, Eui-Jun
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.537-549
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    • 2007
  • The characteristics of the mineralization and geology in the northern Mt. Taebaek mining district are found to be similar with those reported from Nevada district where the Carlin-type gold deposit occurs characteristically as repeated metallic ore deposits in space and time. Though two spots of hs and several spots of Sb anomalies were recognized in the Yeongweol area, they have no relationship with any metalliferous mineralization. On the other hand, two spots of As anomaly in the Jeongseon area have shown to be related with metalliferous ore deposits (mainly Ag-Au), and they are closely associated with Sb anomaly. Some elements of altered limestones in the study such as Au, Ag, As, Sb, Cu, Pb, Zn, and Mo area are closely associated together, and are more enriched in the Jeongseon area than in the Yeongweol area. In particular, Sb and As which may reflect the occurrence of the Carlin-type gold deposit are highly enriched. However, the base metals such af Zn and Pb are highly variable according to samples. The patterns of the enrichment factor for Sb and As, as well as those for Ag and Au, are very similar with those reported from the Carlin-type gold deposits in Nevada. These similarities in elemental distribution may imply that hydrothermal ore mineralization in the study areas was possibly originated from a fluid with the characteristics of the Carlin-type gold mineralization found in Nevada, China, and Indonesia. However, the pattern of base metals and Mo are different. This may result from different chemistry and/or mineralogy of host rock in the study areas.

Hydrothermal Evolution for the Inseong Au-Ag Deposit in the Hwanggangri Metallogenic Region, Korea (황강리 광화대 인성 금-은 광상의 광화 유체 진화)

  • Cho, Hye Jeong;Seo, Jung Hun;Lee, Tong Ha;Yoo, Bong Chul;Lee, Hyeonwoo;Lee, Kangeun;Lim, Subin;Hwang, Jangwon
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.4
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    • pp.307-323
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    • 2018
  • The Inseong Au-Ag and base metal deposit, located in Chungchengbuk-do, Korea, consists of series of quartz veins filling fissures. The deposit occurs in Hwanggangri meta-sediment formation, a lime pebble-bearing phyllite, in the Okcheon Supergroup. Abundant ore minerals in the deposit are pyrite, arsenopyrite, sphalerite, chalcopyrite and galena. The gangue minerals are quartz, calcite and chlorite. Hydrothermal alteration such as chlorization, silicitication, sericitization and carbonitization can be observed around the quartz veins. 4 vein stages can be distinguished based on its paragenetic sequence, vein structure, alteration features and ore minerals. Microthermometry of the fluid inclusion assemblages occur in the veins are conducted to reconstruct a hydrothermal P-T evolution. Fluid inclusions in clean and barren quartz vein in stage 1 have Th of $270{\sim}342^{\circ}C$ and salinity of 1.7~6.4 (NaCl eqiv.) wt%. Euhedral quartz crystal in stage 2 have Th of $108{\sim}350^{\circ}C$ and salinity of 0.5~7.5 wt%. Barren milky quartz vein in stage 3 have Th of $174{\sim}380^{\circ}C$ and salinity of 0.8~7.5 wt%. Calcite vein in stage 4 have Th of $103{\sim}265^{\circ}C$ and salinity of 0.7~6.4 wt%. Calculated paleodepth about 0.5~1.5 km (hydrostatic pressure) indicate epithermal ore-forming condition. Shallow depth but relatively high-T hydrothermal fluids possibly create a steep geothermal gradient, sufficient for base metal precipitation in the Inseong deposit.

Mesothermal Gold Vein Mineralization of the Seolhwa Mine: Fluid Inclusion and Sulfur Isotope Studies (설화 광산의 중열수 금광화작용: 유체포유물 및 황동위원소 연구)

  • Yun, Seong-Taek;So, Chil-Sup;Choi, Seon-Gyu;Choi, Sang-Hoon;Heo, Chul-Heo
    • Journal of the Korean earth science society
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    • v.22 no.4
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    • pp.278-291
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    • 2001
  • Mesothermal gold vein minerals of the Seolhwa mine were deposited in a single stage of massive quartz veins which filled the mainly NE-trending fault shear zones exclusively in the granitoid of the Gyeonggi Massif. The Seolhwa mesothermal gold mineralization is spatially associated with the Jurassic granitoid of 161 Ma. The vein quartz contains three main types of fluid inclusions at 25$^{\circ}$C: 1) low-salinity (< 5 wt.% NaCl), liquid CO$_{2}$-bearing, type IV inclusion; 2) gas-rich (> 70 vol.%), aqueous type II inclusions; 3) aqueous type I inclusions (0${\sim}$15 wt.% NaCl) containing small amounts of CO$_{2}$. The H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl inclusions represent immiscible fluids trapped earlier along the solvurs curve at temperatures from 430$^{\circ}$ to 250$^{\circ}$C and pressures of 1 kbars. Detailed fluid inclusion chronologies may suggest a progressive decrease in pressure during the auriferous mineralization. The aqueous inclusion fluids represent either later fluids evelved through extensive fluid unmixing (CO$_{2}-CH$_{4}$ effervescence) from a homogeneous H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl fluid due to decreases in temperature and pressure, or the influence of deep circulated meteoric waters possibly related to uplift and unloading of the mineralizing suites. The initial fluids were homogeneous containing H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl components and the following properties: the initital temperature of >250$^{\circ}$ to 430$^{\circ}$C, X$_{CO}\;_{2}$ of 0.16 to 0.62, 5 to 14 mole% CH$_{4}$, 0.06 to 0.3 mole% N$_{2}$ and salinities of 0.4 to 4.9 wt.% NaCl. The T-X data for the Seolhwa gold mine may suggest that the Seolhwa auriferous hydrothermal system has been probably originated from adjacent granitic melt which facilitated the CH$_{4}$ formation and resulted in a reduced fluid state evidenced by the predominance of pyrrhotite. The dominance of negative ${\delta}\;^{34}$S values of sulfides (-0.6 to 1.4$%_o$o) are consistent with their deep igneous source.

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Nickel and cobalt partition coefficients in pyrite-pyrrhotite as geothermometer. (지질온도계로써 황철석과 자류철석내의 Ni와 Co의 분배 계수)

  • Yoo, Jae-Shin
    • Journal of the Speleological Society of Korea
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    • v.24 no.25
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    • pp.69-80
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    • 1991
  • 광화시기가 같은 유화광물중에서 상접하는 황철석과 자류철석 내에 함유되어 있는 코발트와 니켈의 함량을 정량분석하여 이들 원소들의 Partition Coefficients로부터 Bezmen method를 이용하여 광물의 생성온도를 구하였다(217~395$^{\circ}$). 지질 연대가 같은 유화광물의 생성온도는 동시기에 생성된 인접한 석영내의 유체포유물의 filling temperature와 거의 일치한다(255~395$^{\circ}$). 따라서 이들 광산내의 광물의 생성온도는 지질온도계로 사용이 가능하며 광물의 생성환경을 규명하는데도 유용할 것이다.

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Mineralogy and Geochmistry of the Sanjeon Au-Ag Deposit, Wonju Area, Korea (산전 금-은 광상에 관한 광물 및 지화학적 연구)

  • Se-Hyun Kim
    • Economic and Environmental Geology
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    • v.32 no.5
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    • pp.445-454
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    • 1999
  • The Sanjeon Au-Ag deposit consists of three subparallel hydrothermal quartz-calcite veins which filled fault-related fractures (generally $N20^{\circ}$ to 35"W-trending and $70^{\circ}$ to $80^{\circ}$ SW-dipping) within quartz porphyry. The vein mineralization shows an apparent variation of mineral assemblages with paragenetic time: (1) early, white quartz + pyrite + arsenopyrite + brown sphalerite, (2) middle, white (vein) to clear quartz (vug) + base-metal sulfides + electrum + argentite, (3) late, calcite + pyrite + native silver. Mineralogic and fluid inclusion data indicate that gold-silver minerals were deposited at temperatures from 2l $0^{\circ}$ to $250^{\circ}$ with salinities of 4 to 5 wt. % equiv. NaCl and log fS2 values from -14.0 to -12.2 atm. The linear relationship between homogenization temperature and salinity data indicates that gold-silver deposition was a result of meteoric water mixing. Ore mineralization occurred at pressure conditions of about 70 bars, which corresponds to the mineralization depths of about 260 m to 700 m. There is a remarkable decrease of the calculated 1)180 values of water from 1.3 to -9.7%0 in hydrothermal fluid with increasing paragenetic time. This indicates a progressive increase of meteoric water influx in the hydrothermal system at the Sanjeon deposit. Oxygen-hydrogen, sulfur, and carbon isotope values of hydrothermal fluids indicate that the ore mineralization was formed largely from meteoric waters with the contribution of sulfur and carbon from a deep igneous source.

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Contrasting Styles of Gold and Silver Mineralization in the Central and Southeastern Korea (한국 중부와 동남부지역 금·은광화작용의 성인적 특성)

  • Choi, Seon-Gyu;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.28 no.6
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    • pp.587-597
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    • 1995
  • Two distinct precious-metal mineralizations actively occur at central and southeastern Korea which display consistent relationships among geologic, geochemical and genetic environments. A large number of preciousmetal vein deposits in the central Korea occur in or near Mesozoic granite batholiths elongated in a NE-SW direction. Whereas, gold and/or silver deposits in the southeastern Korea occur within Cretaceous volcanic and sedimentary rocks. However, most of the precious-metal deposits in the southeastern Korea show characteristics of the silver-rich deposits than the gold-rich deposits in the central Korea. Two epochs of main igneous activities are recognized: a) Jurassic Daebo igneous activity between 121 and 183 Ma, and b) Cretaceous Bulgugsa igneous activity between 60 and 110 Ma. Precious-metal mineralization took place between 158 and 71 Ma, coinciding with portions of the two magmatic activities. Contrasts in the style of mineralization, together with radiometric age data and differences in geologic settings reflect the genetically variable natures of hydrothermal activities from middle Jurassic to late Cretaceous time. The compilation and re-evaluation of these data suggest that the genetic types of hydrothermal precious-metal vein deposits in the central and southeastern Korea varied with time. The Jurassic and early Cretaceous mineralizations are characterized by the Au-dominant type, but tend to change to the Au-Ag and/or Ag-dominant types at late Cretaceous. The Jurassic Au-dominant deposits commonly show several characteristics; prominent associations with pegmatites, simple massive vein morphologies, high fmeness values in ore-concentrating parts, and a distinctively simple ore mineralogy such as Fe-rich sphalerite, galena, chalcopyrite, Au-rich electrum, pyrrhotite and/or pyrite. The Cretaceous precious-metal deposits are generally characterized by some- features such as complex vein morphologies, low to medium fmeness values in the ore concentrates, and abundance of ore minerals including Ag sulfosalts, Ag sulfides, Ag tellurides and native silver. Mineralogical and fluid inclusion studies indicate that the Jurassic Au-dominant deposits in the central area were formed at the high temperature (about $300^{\circ}$ to $500^{\circ}C$) and pressure (about 4 to 5 kbars), whereas mineralizations of the Cretaceous Au-Ag and Ag-dominant deposits were occurred at the low temperature (about $200^{\circ}$ to $350^{\circ}C$) and pressure (<0.5 kbars) from the ore fluids containing more amounts of less-evolved meteoric waters.

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Pb Isotopic Composition of the Ore Deposits Distributed in Jeonbuk Province (전북 광상의 납 동위원소 조성에 대한 고찰)

  • Chung Jae-Il;Park Kye-Hun
    • The Journal of the Petrological Society of Korea
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    • v.15 no.2 s.44
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    • pp.81-89
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    • 2006
  • Pb isotopic compositions were determined from the ore deposits of Beonam, Dongjin, Jeoksang and Bukchang mines distributed within Jeolabuk-do. As a result, individual mine shows significantly different values of Pb isotopic compositions from each other. Pb isotopic values of the Beonam, Bukchang and Dongjin mines altogether from linear variation, but it is too steep to represent their formation age. Instead, such trend suggests that these ore leads were originated from binary mixing. Precambrian basement rocks and Mesozoic granitoids are suggested for such two end-members. The relative contribution of lead from each source seems to be quite different for each ore deposit, implying that the circulation of the ore-forming fluid was very localized when they were formed. In the case of Dongjin mine it seems significant portion of the ore leads were originated from the basement rocks, which suggests that related igneous rock seems to have acted as heat source to generate circulation of the fluid rather than the source of the ore-forming elements.

Condition of the Sangdong Tungsten Skarn Formation (상동 중석 스카른의 생성조건에 관한 연구)

  • Moon, Kun Joo
    • Economic and Environmental Geology
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    • v.17 no.4
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    • pp.259-272
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    • 1984
  • Fluid inclusion and stable isotope studies on the Sangdong tungsten skarn have led to a conclusion that the mineralizing fluids might be derived from a magma, which was inferred within 1km below the present Sangdong ore deposit. Mineral assemblages of the skarns appear to have formed under the equilibrium conditions as the fluids flow outward from a central fluid column, in which the quatz-mica occurs dominantly. A characteristic skarn showing mineralogical zonation by repeated over-prints. The quartz-mica zone at the central part of the Sangdong skarns shows the final stage of protracted fluid evolution. Thermodynamic conclusion based on simplified chemical compositions of major components may express quantitatively the conditions of the skarn formation by using diagrams.

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Talc Mineralization in the Middle Ogcheon Metamorphic Belt (I): with Emphasis of the Stable Isotope Studies of the Dongyang Talc Deposit (중부 옥천변성대내의 활석광화작용 (I): 동양활석광상의 안정동위원소연구를 중심으로)

  • Park, Hee-In;Lee, Insung;Hur, Soondo
    • Economic and Environmental Geology
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    • v.28 no.6
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    • pp.635-646
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    • 1995
  • Mineralized zone in the Dongyang talc deposits occurs on the lowest dolomite member of the Hyangsanri Dolomite belonging to the Ogcheon Supergroup. Ore bodies are emplaced as pipe-like body along the axis of minor folds plunging $40^{\circ}$ to the west developed in these dolomite layers. Amphibolite and chlorite schist are found along the upper or lower contact of all ore bodies (Kim et al., 1963; Park and Kim, 1966). Following the recrystallization and silicification of dolomite, tremolite and tabular and leafy talc(I) of the earlier stage formed, and microcrystalline talc(II) formed in the later stage. Talc(l) and tremolite formed by the reaction between dolomite and the fluid. Whereas talc (II) formed by the reaction between dolomite and fluid, or by the reaction between early formed tremolite and fluid. During the early stage of mineralization, the fluid was the $H_2O-CO_2$ system dominant in $CO_2$, In the later stage, the composition of the fluid changed to $H_2O-NaCl-CO_2$system, and finally to the $H_2O-NaCl$ system. The pressure and temperature conditions of the formation of tremolite associated with talc(I) were 1,640~2,530 bar, and $440{\sim}480^{\circ}C$, respectively. The pressure and temperature condition of talc(II) ore formation was 1,400~2,200 bar, and $360{\sim}390^{\circ}C$, respectively. These conditions are much lower than the metamorphic pressure and temperature of the rocks from the Munjuri Formation located about 5 km to the noJ:th of Dongyang talc deposit ${\delta}^{13}C$ and ${\delta}^{18}O$ values of dolomite which is the host rock of the talc ore deposit are 2.9~5.7‰ (PDB), and -7.4~l6.8‰ (PDB), respectively. These values are little higher than those from the Cambro-Ordovician limestones of the Taebaeksan region, but belong to the range of the unaltered sedimentary dolomite. ${\delta}^{18}O$and ${\delta}D$ values of the talc from Dongyang deposit are 8.6~15.8‰ (vs SMOW), and -65~-90‰ (vs SMOW), respectively, belonging to the range of magmatic origin. These values are quite different from those measured in the metamorphic rocks of Munjuri and Kyemyungsan Formation. ${\delta}^{34}S$ value of anhydrite is 22.4‰ (CDT), which is much lower than ${\delta}^{34}S$ (30‰ vs COT) of sulfate of early Paleozoic period, and indicates the possibility of the addition of magmatic sulfur to the system. Talc ores show the textures of weak foliation and well developed crenulation cleavages. Talc ore deposit in the area is concluded as hydrothermal replacement deposit formed before the latest phase of the deformations that Ogcheon Belt has undergone.

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Gold Mineralization of the Youngbogari Mine, Youngdong Area (영동지역 영보가리 광산의 금광화 작용)

  • Heo, Chul-Ho;Chi, Se-Jung
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.115-124
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    • 2007
  • Electrum-sulfide mineralization of the Youngbogari mine area occurred in two stages of massive quartz veins that fill the fractures along the fault/shear zones in the Precambrian gneiss. Ore mineralogy is simple, consisting of arsenopyrite $(31.4{\sim}33.4atom.%As)$, pyrite, sphalerite $(4.1{\sim}17.6mole%FeS)$, galena, chalcopyrite, argentite, and electrum. Electrum $(60.3{\sim}87.6atom.%Ag)$ is associated with galena, chalcopyrite and late sphalerite infilling the fractures in quartz and sulfides. Fluid inclusion data show that ore mineralization was formed from $H_2O-CO_2-CH_4-NaCl$ fluids $(X_{CO2+CH4}=0.0\;to\;0.2)$ with low salinities (0 to 10wt.% eq. NaCl) at temperatures between $200^{\circ}\;and\;370^{\circ}C$. Gold-silver mineralization occurred later than the base-metal sulfide deposition, at temperatures near $250^{\circ}C$ and was probably a result of cooling and decreasing sulfur fugacity caused by sulfide precipitation and/or $H_2S$ loss through fluid unmixing.