• Title/Summary/Keyword: 광표백

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Photochemical bleaching properties of photopolymer (포토폴리머의 광화학 표백 특성)

  • 성기영;경천수;이영락;곽종훈;최옥식;이윤우;이인원;서호형
    • Korean Journal of Optics and Photonics
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    • v.10 no.4
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    • pp.335-341
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    • 1999
  • We fabricate acrylamide photopolymer as a holographic recording material and investigrate photobleaching characteristics. To explain the photobleaching kinetics of photopolymer we adopt two models of the Beer-Lambert law and optical transmittance based on rate equations obtained from a simplified energy-band model. The Beer-Lambert law is in good agreement with the experimental results in a first short-time region but not in long-time region. But the optical transmittance model based on rate equations explains the experimental results very well in both short-and long-time regions.

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Polymeric digital optical switch based on photobleached waveguides (광표백 폴리머 광도파로를 이용한 디지탈 광스위치)

  • 이상신;신상영
    • Korean Journal of Optics and Photonics
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    • v.7 no.4
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    • pp.414-418
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    • 1996
  • An electro-optic polymer digital optical switch was fabricated by using a photobleached waveguide and a self-aligned electrode. It features wavelength insensitive operation, fabrication tolerance and flexible design. And its possible advantages include low coupling losses to the fibers and wide bandwidths. For improving its switching performance, the guided mode profiles of the photobleached waveguides were controlled by photobleaching times to achieve optimized coupling in the branch. And the self-aligned electrode was employed to achieve both efficient overlap of the optical and electric fields and easy introduction of the adiabatically tapered electrodes. The measured crosstalks were better than -21dB at 1.32 ${\mu}{\textrm}{m}$ and 1.55 ${\mu}{\textrm}{m}$, and the extinction ratios of each output port were also more than 20 dB.

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Development of Image-based Fluorescence Photobleaching Technique for Measuring Macromolecule Diffusion in Biological Porous Medium (생체 다공성 매질에서 분자 확산 측정을 위한 영상 기반 형광 광표백 기법 개발)

  • Lee, Dong-Hee;Lee, Jeong-Hoon;Park, Choon-Ho;Kim, Jung-Kyung
    • Journal of the Korean Society of Visualization
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    • v.7 no.1
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    • pp.9-13
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    • 2009
  • Fluorescence recovery after photobleaching (FRAP) has been widely used for the measurement of molecular diffusion in living cells and tissues. We developed an image-based FRAP (iFRAP) technique using a modified real-time microscope and a 488 nm Ar-ion laser. A fractional intensity curve was obtained from the time-lapse images of fluorescence recovery in the bleached spot to determine the diffusion coefficient of fluorescently labeled macromolecules in porous medium. We validated iFRAP through experiments with agar gels (0.5% and 1.5% w/v) containing FITC-Dextrans (10, 70 and 500 kDa MW). Further validation was performed by a Monte Carlo approach, where we simulated the three-dimensional random walk of macromolecules in agar gel model. Diffusion coefficients were deduced from the mean square displacement curves and showed good agreements with those measured by iFRAP.

Holographic recordings in acrylamide photopolymer (Acrylamide Photopolymer의 제작 및 홀로그램 기록 특성)

  • 경천수;성기영;곽종훈;최옥식;이윤우;이인원;서호형;이일항
    • Korean Journal of Optics and Photonics
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    • v.9 no.1
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    • pp.31-37
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    • 1998
  • We fabricated acrylamie photopolymer holographic recording materials by photopolymerization of acrylamide, and described hologram formation process. Light absorption and phtobleaching process by MB(methylene blue) dye and radical polymerization process due to TEA(triethanolamind) are explained in detail. We adopted the Beer-lambert law in order to explain the photobleaching kinetics. Dependencies of diffraction efficiency of the hologram on monomer amout and the exposure are investigated. The scattering effect caused by grain of polymer crystal, and fixing method are also illustrated.

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Photocatalytic Reaction of Sensitizer, Rose Bengal and Supersensitizer, Allylthiourea (감응제 Rose Bengal과 초감응제 AIIylthiourea의 광촉매 반응)

  • Yoon, Kil-Joong;Lee, Beom-Gyu
    • Analytical Science and Technology
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    • v.11 no.1
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    • pp.13-19
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    • 1998
  • In the dye sensitization for the solar energy conversion with a photoelectrochemical cell containing allylthiourea, the time profile of the sensitized photocurrent showed a rise and fall with the irradiation time. The dye solution before and after irradiation was analyzed by means of spectroscopic methods. A new precipitation reaction between sensitizer and supersensitizer and photobleaching of the dye appeared to be involved in the decreased photocurrent.

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Photocatalytic Reaction of Sensitizer, Rose Bengal and Supersensitizer, Thiourea (감응제 Rose Bengal과 초감응제 Thiourea의 광촉매 반응)

  • Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.9 no.1
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    • pp.62-71
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    • 1996
  • The enhancement of the solar energy conversion efficiency into the electrical energy by the dye sensitization with a photoelectrochemical cell was studied. The magnitude of the rose bengal sensitized photocurrent containing the supersensitizer, thiourea was five times greater than that in the absence of thiourea. It was observed, however, that the long time span of irradiation causes the decrease in the photocurrent. Spectroscopic analysis of the dye solution showed that the dye molecule was photobleached and the insoluble aggregate which settles down in the solution, was formed as a result of the possible photocatalytic reaction and the disappearance of dye from the solution was the cause of the decreased photocurrent in the sensitization run.

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Control of the Photo-induced Discoloration of the Handmade Korean Paper with Polyethylene Glycol (Polyethylene Glycol에 의한 수록한지(手漉韓紙)의 광(光) 변색(變色) 억제(抑制))

  • Cheon, Cheol;Park, Soo-Ahn
    • Journal of Korean Society of Forest Science
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    • v.89 no.2
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    • pp.161-166
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    • 2000
  • Classified handmade Korean paper which has been commonly used as the material for the paper cultural assets divide into four classes. We irradiated xenon arc lamp, which has almost the same spectrum distribution as natural sunlight, to test photo-induced of discoloration according to PEG molecular weight and concentration. So, we reach the followings. 1) Unbleached handmade Korean paper with PEG showed rapid decrease of brightness for 10 hours after photo-irradiation, regardless of molecular weight of PEG, but, after 10 hours, it showed gradual increase of brightness. From this, it proved that there was an effect of preventing discoloration of photo-irradiation. 2) Chemical bleached handmade Korean paper showed increase of brightness after 20 hours. Though time was delayed in increase of brightness, there was also an effect of preventing discoloration of photo-irradiation in chemical bleached paper. 3) Handmade Korean paper made with abet-mosk showed the lowest of brightness when it was tested on 400-20% PEG. Before photo-irradiation, the brightness of paper, applied it, was the lowest, but it showed the least difference of brightness after photo-irradiation. From this, it proved that there was the greatest effect of preventing discoloration in this paper. 4) Preventing yellowish, the first phenomena by photo-irradiation ageing with applying PEG was proved that there was the decrease of value of $b^*$ +, and increase value of $L^*$, which could fairly prevent decrease of brightness.

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