• Title/Summary/Keyword: 광조사

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Dyeing and Photochromic Properties of Golden Yellow Reactive Dyes (Golden yellow 반응성 염료의 염색성 및 광변색 특성)

  • Lee, Jung-Jin;Kim, Hyun-Sung;Shin, Eun-Suk
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.32-32
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    • 2011
  • 염료의 포토크로미즘은 빛을 받았을 때, 염료의 분자구조가 변환되어 흡수파장이 달라지고 결과적으로 원래 색과 다른 색상을 나타내는 현상을 말한다. 대부분의 Golden yellow 색상을 나타내는 아조계 반응성염료는 Trans-Cis 간의 이성질체 전환을 통해 포토크로미즘 현상을 나타내며, 가역적으로 복색되기는 하지만 상업적으로 많은 문제와 불편을 초래한다. 한편 pyrazolone계 아조염료는 azo form 보다는 hydrazone form으로 더 많이 존재하는 것으로 알려져 있으며, 이로인해 상대적으로 Trans-Cis 이성질화가 잘 일어나지 않아 포토크로미즘 현상이 잘 일어나지 않을 것으로 기대된다. 이 연구에서는 3종의 pyrazolone계 golden yellow 반응성 염료를 합성하고, 합성한 염료를 면직물에 염색하여 염색성 및 견뢰도를 평가하였다. 또한 시판되고 있는 아조계 golden yellow 반응성 염료 4종을 선정하여 역시 염색성과 견뢰도 특성을 알아보았다. 그리고 7가지 염료의 광변색 특성을 조사하기 위해 포토크로미즘 평가방법인 ISO 105-B05법 및 이전 연구에서 제안된 광변색 평가방법을 사용하였다. ISO 105-B05법은 표준청색염포가 grey scale 4등급이 되는 시간을 구한 다음 이 시간의 1/4시간동안 조사한 후 포토크로미즘을 평가하는 것이며, 후자의 경우는 4시간동안 광조사된 시험편을 측색하고 시간에 따른 복색되는 정도를 평가한다. 합성한 pyrazolone계 염료들은 394-408nm의 최대흡수파장은 나타내었다. 7종의 yellow 반응성 염료들은 모두 면직물에 우수한 염색성 및 build-up성을 나타내었으며, 대체적으로 양호한 견뢰도를 얻었다. 또한 광변색 특성 평가결과 모든 염료들은 ISO 평가방법에 대하여 non-photochromic 특성으로 나타났으나, 다른 광변색 평가 결과 일부 염료들에 있어서 photochromic 특성이 있는 것으로 나타나 평가방법에 따라 차이를 보였다.

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Polymerization Shrinkage Distribution of a Dental Composite during Dental Restoration Observed by Digital Image Correlation Method (디지털 이미지 상관법을 이용한 치과용 복합레진의 수복 시 중합수축분포 관찰)

  • Park, Jung-Hoon;Choi, Nak-Sam
    • Composites Research
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    • v.30 no.6
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    • pp.393-398
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    • 2017
  • The shrinkage distribution of a dental composite (Clearfil AP-X, Kuraray, Japan) used for dental restoration was observed using a digital image correlation method. In order to analyze the shrinkage distribution formed during and after light irradiation, digital images were taken with different photographing conditions for each period. Optimal photographing conditions during LED irradiation were obtained through a preliminary experiment in which the exposure time was applied from 0.15 ms to 0.55 ms in 0.05 ms intervals. The DIC analysis results showed that the strain was non-uniform. For the initial 20 s of light irradiation the composite resin shrank to the level of 50~60% of the final curing shrinkage. Such large shrinkage amount of the composite resin lump affected the tensile stress concentration near the adhesive region between the composite resin and the substrate.

Utilization of Evergreen Ground Covers in Central Region of Korea as Landscape Materials -Focusing on the Changes in Leaf Color Related with Light during Winter- (중부지방 상록지피식물의 조경적 이용 -광이 월동중의 엽색에 미치는 영향을 중심으로-)

  • Nam, Yu-Kyeong;Kim, Myung-Hyoe
    • Journal of agriculture & life science
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    • v.45 no.2
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    • pp.1-7
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    • 2011
  • Three evergreen ground-cover species were tested and evaluated for cold acclimation with different lights in central Korea to enrich the varieties of ground cover plants for over-wintering. Nandina domestica which recently started to be planted in central Korea had high chlorophyll unit with shade condition in both locations, Banpo and Gwacheon during winter. Light condition had no influence on chlorophyll unit in Banpo after April, meanwhile full sun condition decreased chlorophyll unit significantly in Gwacheon, which is exposed to cold wind from north. Ophiopogon japonicas had more than double chlorophyll unit in shade condition compared to that in full light condition in both investigation areas in February. In addition, higher value of L and b in shade condition had been maintained than in full sun condition throughout investigation period. However, leaves in Gwacheon were de-colorized in full sun condition after over-wintering. Pachysandra terminalis had more higher chlorophyll unit in shade condition compared to in full sun condition in both investigation areas in February. But light conditions had not effect the difference of chlorophyll unit of Gwacheon in April. Therefore, The present results suggest that evergreen ground covers with shade condition would be used as landscape materials in the capital area.

Effect of Light Condition before and after Chilling Treatment on the Survival and Physiological Responses of Cucumber (Cucumis sativus L.) Seedlings (냉온처리 전후의 광환경 조건이 오이 묘의 생존율에 미치는 영향)

  • Yooun Il Nam;Young Hoe Woo;Hyung Jun Kim
    • Journal of Bio-Environment Control
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    • v.10 no.3
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    • pp.165-171
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    • 2001
  • This study was conducted to investigate the influence of light condition before and after chilling treatment started at different times of a day on the survival and physiological responses of cucumber seedlings grown in a greenhouse. Percent survival of cucumber seedling exposed to a chilling temperature of 2$^{\circ}C$ for 48 hours varied considerably depending upon the initiation time of chilling treatment. Seedlings exposed to chilling treatment from 7:00 o clock, the end of a dark period, showed considerably lower % survival of 30.6% as compared to 90.2% in those exposed to the same treatment starting from 18:00 o clock, the end of a photoperiod. This difference in % survival was found to be closely associated with content of photosynthetic assimilates in seedlings. Relative amount of electrolyte leakage was 57.1% in seedlings chilled from 7:00 o clock and 25.9% in seedlings chilled from 18:00 o clock. Among the ions found in the electrolyte leakage, content of $K^{+}$ was the greatest, followed by that of N $a^{+}$, $Mg^{+}$ and $Ca^{+2}$. Light illumination for 2 hours or longer shortly before chilling treatment during the dark period was effective in increasing % survival of seedlings, probably because of increased photosynthetic assimilates in seedlings. Light illumination during a 48 hour chilling treatment at 3$^{\circ}C$ significantly reduced % survival to 43.3% as compared to 92.0% in seedlings kept continuously in darkness.ess.s.

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A Study on the Impact of Media Façade Performances on the 10-story Gyeongcheonsa Pagoda (미디어파사드 상영 시 경천사지 십층석탑에 미치는 영향 조사 연구)

  • Lee, Hong Shik;Ryu, Jae Hyoung;Lee, Kwon Joon;Yang, Seok Jin
    • Conservation Science in Museum
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    • v.28
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    • pp.51-64
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    • 2022
  • This study aims to identify the impact of optical energy on cultural properties when the light energy irradiates cultural assets during augmented reality (AR) or media façade performances as activities designed to garner public interest. The 10-story Gyeongcheonsa Pagoda was used for this study, and the impact was evaluated by comparing the optical energy irradiated during a media façade performance with the energy irradiated under normal conditions. For comparison, this study measured the illuminance in lux for each light source that irradiated the ten-story stone pagoda and used the data to calculate illuminance in lux-hours. The results showed that the pagoda receives 786.4 lux per hour when both sunlight and artificial light are present, while 13.2 lux of energy is irradicated by the media façade for each performance. The result indicates that the pagoda receives about 29.8 times more optical energy from sunlight and artificial light sources than during media façade performances on an hourly basis, when the performance is carried out twice a week. This study therefore concludes that the optical energy of media façade performances inflicted trivial damage to the ten-story stone pagoda.

Characterization of the Effects of Different Wavelengths of Night-break Lighting on the Fruit Quality and Yield of 'Kyoho' Grapes (파장별 야간 조사에 따른 '거봉' 포도의 품질 및 생산량)

  • Kim, JunHyeok;Park, YoSup;Kwon, YongHee;Jung, MyungHee;Park, Hee-Seung
    • Horticultural Science & Technology
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    • v.35 no.2
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    • pp.170-177
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    • 2017
  • This study was conducted to estimate the light pollution damage caused by night-break lighting in 'Kyoho' grapes. Night irradiation was performed every night for four hours (10 p.m. to 2 a.m.) from the full bloom to the harvest stage using red, blue, and white lamps as artificial light. Fruit yield, soluble solid content, anthocyanin content, and chlorophyll a content were affected by night irradiation. The soluble solid content of the control was $17.5^{\circ}Brix$, approximately $1^{\circ}Brix$ higher than the red ($16.4^{\circ}Brix$), blue ($16.2^{\circ}Brix$), and white light treated grapes ($16.3^{\circ}Brix$). The anthocyanin content of the skin was also higher in the control at $4.08{\mu}g{\cdot}cm^{-2}$ compared to the red ($3.14{\mu}g{\cdot}cm^{-2}$), blue ($2.47{\mu}g{\cdot}cm^{-2}$), and white ($2.82{\mu}g{\cdot}cm^{-2}$) light treated samples. On the other hand, the chlorophyll a content of the control was the lowest at $0.268{\mu}g{\cdot}cm^{-2}$ as compared with the red ($0.339{\mu}g{\cdot}cm^{-2}$), blue ($0.345{\mu}g{\cdot}cm^{-2}$), and white ($0.372{\mu}g{\cdot}cm^{-2}$) light treated samples. Considering that higher soluble solid contents, higher accumulation of anthocyanin, and lower chlorophyll a contents are factors involved in fruit maturation, night irradiation may delay fruit maturation and red light treatment may result in decreased yield. Our results confirmed that night-break lighting regardless of the wavelength provoked light pollution in 'Kyoho' grapes. Therefore, fruit maturation may be poor in the presence of artificial light, including streetlamps, in neighboring vineyards.

LQG controller design for tracking servo control of holographic data storage system (홀로그래픽 정보저장 장치의 트래킹 서보 제어를 위한 LQG 제어기 설계)

  • Lee, Yong-Hui;Lee, Sang-Hun;KIm, Jang-Hyeon;Yang, Hyeon-Seok;Park, Yeong-Pil
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.1280-1283
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    • 2007
  • 본 연구는 홀로그래픽 정보저장기기에서 트래킹 서보 제어를 통해 원하는 데이터를 정확하게 기록 및 재생하기 위한 LQG 제어기를 제안하고 검증하는 것을 목적으로 한다. 서보광이라는 추가적인 광을 사용할 것을 제안하여, 서보광과 참조광 간의 간섭에 의해 기록매체에 서보 신호를 얻을 수 있게 하는 홀로그램을 형성한다. 기록 및 재생과정에서 신호광이 기록, 재생됨과 동시에 서보광에 의한 서보 신호가 재생되고, 그 신호의 경로에 설치된 포토 다이오드로부터 디스크 형태에서 발생 할 수 있는 외란을 감지하게 된다. 감지된 외란 신호인 트래킹 에러 신호를 통해 참조광이 디스크의 정확한 위치에 조사되게 하기 위해 평판유리 액츄에이터를 사용한다. 이와 같은 서보 제어를 수행했을 경우 데이터 페이지가 정확하게 재생되며 SNR 과 BER 이 개선되는 것을 확인할 수 있다.

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Dentin bond strength of bonding agents cured with Light Emitting Diode (LIGHT EMITTING DIODE로 광조사한 상아질 접착제의 상아질 전단접착강도와 중합률에 관한 연구)

  • Kim Sun-Young;Lee In-Bog;Cho Byeong-Hoon;Son Ho-Hyun;Kim Mi-Ja;Seok Chang-In;Um Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.29 no.6
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    • pp.504-514
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    • 2004
  • This study compared the dentin shear bond strengths of currently used dentin bonding agents that were irradiated with an LED (Elipar FreeLight, 3M-ESPE) and a halogen light (VIP, BISCO). The optical characteristics of two light curing units were evaluated. Extracted human third molars were prepared to expose the occlusal dentin and the bonding procedures were performed under the irradiation with each light curing unit. The dentin bonding agents used in this study were Scotchbond Multipurpose (3M ESPE), Single Bond (3M ESPE), One-Step (Bisco), Clearfil SE bond (Kuraray), and Adper Prompt (3M ESPE), The shear test was performed by employing the design of a chisel-on-iris supported with a Teflon wall. The fractured dentin surface was observed with SEM to determine the failure mode. The spectral appearance of the LED light curing unit was different from that of the halogen light curing unit in terms of maximum peak and distribution. The LED LCU (maximum peak in 465 nm) shows a narrower spectral distribution than the halogen LCU (maximum peak in 487 nm). With the exception of the Clearfil SE bond (P < 0.05), each 4 dentin bonding agents showed no significant difference between the halogen light-cured group and the LED light-cured group in the mean shear bond strength (P > 0.05). The results can be explained by the strong correlation between the absorption spectrum of camphoroquinone and the narrow emission spectrum of LED.

Evaluation of Plant Resources Cultivated under Tracking Solar Photovoltaic Power Station: Growth and Development of Oryza sativa L. cv. Saeillmi (추적식 태양광시설 하부 재배 식물자원 평가(1): 벼 작물의 생육)

  • Jong-Young Choi;Ye-Jin Lee;In-jin Kang;Seong-Ho Jeon;R&D Center, PARU CO. LTD;Chang-Hyu Bae
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2020.08a
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    • pp.38-38
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    • 2020
  • 본 연구는 영농형 태양광 발전시스템 적용을 위한 하부작물의 재배효율을 검토하기 위하여 중산간지역 재배지(전라남도 순천시 승주읍 월계리 소재)에 설치한 추적식 영농형 태양광 발전시설 하부에 주식량자원식물인 벼품종 새일미를 2018년 6월 16일 이앙하여 생육을 조사하였다. 2018년 7월 24일 기준, 초장(plant height)은 태양광 시설 하에서 대조구보다 길게 나타났고, 태양광발전시설 중심축에 가까울수록 웃자람(도장)을 보였다. 엽수는 음영지역에서 대조구에 비해 잎의 전개가 늦게 나타났으며, 수확기에 조사한 간장(culm length)은 음영이 강한 지역에서는 대조구에 비해 작게 나타났으나 음영이 약한 지역으로 갈수록 간장이 증가하여 대조구와 비슷하거나 약간 크게 나타났다. 수장(panicle length)은 대조구 대비 처리구와 큰 차이가 없었으며, 태양광발전시설 중심축의 남쪽인 경우 강한 음영지역에서 약한 음영지역으로 갈수록 길게 나타났다. 동년 8월24일 기준 처리구 동쪽의 출수(heading)율은 강한 음영지역(중심축으로부터 1~3m 떨어진 구간)에서 가장 낮았고, 중심축으로부터 멀어질수록 높게 나타났다. 이와 같이 태양광발전시설 설치구역에서는 음영이 강할수록 생장이 미흡하여 유효분얼수가 감소하고, 출수가 지연되었다. 이에 따라서 음영이 강한 구역일수록 수량구성 4요소 중에 등숙율을 제외한 단당이삭수, 수당평균영화수, 천립중이 감소하였다. 태양광발전시설 중심축으로부터 멀어질수록 음영강도가 약해져서 수량감소가 낮아졌으며, 또한 동서남북 방향에 따라 그 감소율이 다르게 나타났다.

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HARDNESS OF COMPOSITE RESIN CURED BY HIGH INTENSITY HALOGEN LIGHT (고강도 할로겐광으로 중합한 복합레진 수복재의 경도)

  • Park, Jong-Seok;Lee, Kwang-Hee;Kim, Dae-Eup;Kim, Seong-Hyeong;Ahn, Ho-Young
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.3
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    • pp.471-479
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    • 2001
  • The purpose of this study was to compare the effect of the high intensity halogen light $(850\sim1000mW/cm^2)$ with that of the conventional halogen light $(400mW/cm^2)$ on the hardness of composite resin. Three resin composites (Z-100, 3M, U.S.A. : Tetric Ceram, Vivadent, Liechtenstein; SureFil, Dentsply, U.S.A.) were filed in the stainless steel moulds which were 4mm in diameter and 2, 3, 4, and 5mm in depth, respectively. They were cured under the four different modes : (1) conventional mode, 40 seconds at $400mW/cm^2$; (2) 'ramp' mode, 10 seconds at 100 to $1000mW/cm^2$ plus 10 seconds at $1000mW/cm^2$; (3) 'boost' mode, 10 seconds at $1000mW/cm^2$; and (4) 'standard' mode, 20 seconds at $850mW/cm^2$. The surface hardnesses of the top and the bottom of the resin samples were measured with a microhardness tester (MXT70, Matsuzawa, Japan). The top surface hardness was not significantly different among the curing modes. The bottom surface hardness was generally the highest in the conventional mode and the lowest in the high intensity boost mode. There was no significant difference in the bottom surface hardness between the conventional mode and the high intensity standard mode in 2mm depth. The results suggest that the curing time of the high intensity halogen light $(850mW/cm^2)$ should be at least 20 seconds to produce the equal level of the bottom surface hardness of 2mm resin composite as compared to the hardness produced by the conventional halogen light $(400mW/cm^2)$.

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