• Title/Summary/Keyword: 광굴절 고분자

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Mechanism of Photorefractive Effect in Polymer Layered Nematic Liquid Crystal Systems (고분자 층이 도입된 네마틱 액정 시스템의 광굴절 효과 기작)

  • Mun Jun-Ho;Yun Chun-Seop;Kim Hyeon-Uk;Choe Su-An;Kim Jong-Deuk
    • Proceedings of the Optical Society of Korea Conference
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    • 2001.02a
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    • pp.206-207
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    • 2001
  • The photorefractive (PR) effect in liquid crystals sandwiched between photoconductive polymer layers was first studied by Ono et al. They reported that the PR effect vanished at steady state If there were not insulating layers because no charge trapping occurred in the photoconductive poly(N-vinylcarbazole) (PVK) layers. However we observed a significant PR effect in the polymer layered liquid crystal (PLLC) system where a liquid crystal layer doped with fullerene is sandwiched between two photoconductive PVK layers. (omitted)

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Comparison of Properties of Polymer Based Glass Lenses by Chemical Etching Reaction (고분자 안경 렌즈의 재질별 화학적 식각 반응성 비교)

  • Lee, Junghwa;Noh, Hyeran
    • Journal of Korean Ophthalmic Optics Society
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    • v.17 no.2
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    • pp.119-126
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    • 2012
  • Purpose: To study changes in coating and lens materials after chemically etched different polymer based glass lenses in short-term and ambient condition using hydrofluoric acid. Methods: Vinyl ester polymer (Lens A) and thiourethane polymer (Lens B), both dyed in gray 70%, were etched in hydrofluoric acid solution for 5, 10, or 15 min. The mechanical properties, degrees of damages in hard coating, anti-reflection coating, and other coatings, rates of refractive index and light transmission of both polymer types were evaluated. Results: Rates of refractive index of both lens types were not changed significantly after chemical etching. However, anti-reflection coatings and hard coatings were removed and lens surfaces were damaged. As a results, UV light transmission of lenses increased and mechanical properties decreased. Chemical etching notably changed various properties of thiourethane polymer materials. Conclusions: Depending on types of polymer materials, chemical reactions by hydrofluoric acid were dissimilar. Thus, various properties of les materials were altered differently.

UV Absorbent-added Polymerization and its Application as Ophthalmological Material (자외선 흡수제를 첨가한 고분자 중합 및 안 의료용 소재로의 적용)

  • Sung, A-Young;Kim, Tae-Hun;Ye, Ki-Hun
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.98-103
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    • 2011
  • This study was done for the preparation of macromolecular material with UV-blocking features by adding the benzophenone group that is commonly used as a UV-absorbent and $TiO_2$ which is known to be a very stable material in chemical and physical aspects. Also, we compared the level of UV absorbency of the polymer produced from polymerization with previous materials and measured basic properties such as water content, refractive index and optical transmittance of produced contact lenses. The results of the measurement showed that the refractive index and water content of the contact lens with added UV-absorbent was 1.430~1.440 and 35.0~45.0% respectively, which was similar to that of previous contact lenses. Also, for optical transmittances of each wave length, contact lenses without the UV-absorbent was 89%, 88% and 89% respectively for UV-A, UV-B and visible light, indicating that the UV transmittance is very high though contrary with cases of contact lenses with added 2-hydroxy-4-methoxy-benzophenone and 2,4-dihydroxy-benzophenone which showed transmittances of 0% and 6% respectively for UV-A and UV-B showing a UV-blocking effect. Meanwhile, contact lenses with added $TiO_2$ showed transmittance of 6% and 51% respectively for UV-A and UV-B also showing a UV-blocking effect. The visible transmittance was 77~89% showing that it satisfies the visible transmittance required for ophthalmological materials.

Fabrication of nano texturing on the polymer surface for transmittance property (폴리머 기판상 나노 구조 형성을 통한 광특성 제어 연구)

  • Byeon, Eun-Yeon;Lee, Seung-Hun;Kim, Do-Geun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.87.2-87.2
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    • 2017
  • 폴리머 필름에 표면처리 및 코팅, 필름의 다층화, 원료 소재의 하이브리드화 등을 통해서 기능성을 부여한 기능성 고분자 필름은 디스플레이, 반도체, 자동차, 에너지, 포장재 등 다양한 분야에 응용되고 있다. 기능성 고분자 필름의 산업화를 위해 대면적 연속 공정기술 개발이 필요하며, 본 연구에서는 roll to roll 시스템을 이용하여 폴리머 기판상 나노 구조 형성을 위한 공정연구를 수행하였다. 재료연구소 자체 개발 선형이온소스는 0.25 keV에서 1 keV까지 에너지 조절이 용이하며, 이온빔 조사를 통해서 PET, PMMA, PDMS 등 다양한 폴리머 기판의 표면에 나노 구조화 공정을 개발하였다. 표면 나노 구조 형성을 통해서 폴리머 필름의 투과도와 Haze 제어가 가능하며, 공정 기술을 통해 저반사 및 고굴절 특성의 기능성 필름을 제작하였다. 이러한 나노 구조화 필름은 플렉서블 디스플레이의 광추출효율 향상을 위한 광추출층, 저반사 디스플레이 패널 필름 등에 적용 가능한 기술이다.

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Optical Properties and Thermal stability of Fluorinated Polymers for WDM Photonic Devices (파장분할다중 광소자용 불소 치환된 고분자의 열적 안정성 및 광특성)

  • Lee, Myeong-Hyeon;Lee, Hyeong-Jong;Lee, Eun-Mi;O, Min-Cheol;An, Ju-Heon;Han, Seon-Gyu;Kim, Hae-Geun
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.856-859
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    • 1998
  • 파장분할다중 광소자용으로 새로운 치환된 고분자인 폴리아릴렌에테르를 합성하였다. 이 물질은 열적으로 $500^{\circ}C$까지 안정하며, $1.5\mu\textrm{m}$의 파장 근처에서 넓은 투과 영역을 가진다. 굴절률도 1.495-1.530의범위에서 불소 함유량으로 조절되었다. 단일 모드 광도파로를 제작하여 광도파손실을 측정하였다. 측정된 광도파손실은 1.55$\mu\textrm{m}$의 파장에서 0.2 dB/cm 이하였다.

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Polymerization of Norbornene with ${\eta}^3$-Allyl Pd(II) Complexes/MAO Catalysts (${\eta}^3$-알릴 Pd(II) 화합물/MAO 촉매를 이용한 노보넨 중합)

  • 윤근병;이동호
    • Polymer(Korea)
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    • v.28 no.3
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    • pp.281-284
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    • 2004
  • 비닐 형태의 부가중합에 의해 생성된 비결정 폴리노보넨은 주사슬이 고리화합물로 이루어져 있으며, 높은 고체밀도와 유리 전이 온도를 나타내며, 낮은 유전상수를 가지는 특징이 있다. 광학적으로 폴리노보넨은 낮은 투과손실을 가지고 있는데, 광통신 대역인 850 nm에서 삽입 손실이 0.1 dB/cm이고, 복굴절이 0.001을 나타내어 광결합 소자 및 광소자에 응용이 기대된다. 이는 주사슬의 고리화합물에 의해 결정화되지 않아, 유리 전이 온도가 28$0^{\circ}C$로 높으면서 비결정의 투명성을 가지기 때문이다.

Analysis of Polarization Characteristics of Reflection Type Photopolymer for Stabilization (반사형 광 폴리머의 효율 안정을 위한 편광특성 분석)

  • Kim, Eun-Seok;Kim, Nam
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.7
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    • pp.36-42
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    • 2000
  • Some polarization characteristics of reflection type photopolymer are investigated. Photopolymer on a Mylar substrate alters an incoming linearly polarized laser beam to an elliptical polarization. Due to the rotation of the polarization, the recording gratings show different diffraction efficiencies. The rotation angle is of order of 10-50% for the tested samples. It is found that the polymer layer does not changes the polarization direction but the Mylar substrate alone distorts the incoming polarization to a comparable degree. As align the polarization states of photopolymers to be parallel with a laser using a He-Ne laser(633nm), which is not sensitive to that material, it was possible to make high diffraction efficiency gratings.

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광도파로용 광경화성 폴리머의 UV 레이저를 이용한 직접모화

  • Kang, Hee-Sin;Seo, Jung;Lee, Jehoon;Kim, Jung-O
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.238-238
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    • 2004
  • 폴리머는 20세기 중반부터 그 사용량이 급격히 늘어나고 있고 또한 사용범위도 매우 광범위해진 중요한 재료이다. 석유화학공업의 발달과 더불어 초기의 고분자공업은 범용수지의 생산에 주로 의존하였으나 최근에는 용도가 다양해지고 기능화 되면서 소량, 고가의 기능성 고분자재료들이 많이 나타나고 있다.(중략)

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Zig-zag electrode pattern for improvement of electro-optic characteristic in polymer stabilized blue phase liquid crystal cell (고분자 안정화 블루상 액정셀의 전기광학특성 향상을 위한 지그재그 형태 전극 설계)

  • Kang, Wan-Seok;Mun, Byung-June;Lee, Gi-Dong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.1
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    • pp.183-187
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    • 2011
  • The polymer-stabilized blue phase liquid crystal (BPLC) cell has advantages such as sub-millisecond response time, wide viewing angle and no rubbing process for the alignment of liquid crystals. However, high operating voltage and low kerr constant of the polymer-stabilized blue phase liquid crystal deteriorate the electro-optical characteristic of the polymer-stabilized BPLC cell. In this paper, we proposed novel zig-zag electrode in cell layout and confirmed that proposed electrode shape could reduce an over 25 percent of operating voltage for BPLC cell without degradation of tranmittance by using Kerr constant simulation.

Variable Optical Attenuator based on Side Polished Fiber Technique (측면 연마 광섬유를 이용한 가변 광 감쇠기)

  • 구숙영;정치섭
    • Korean Journal of Optics and Photonics
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    • v.15 no.3
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    • pp.222-228
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    • 2004
  • The variable optical attenuator based on side polished fiber technique was experimentally demonstrated. Various combination mixtures of poly(vinylidene fluoride) and poly(methyl methacrylate) have been used as the overlay waveguide materials for the variable optical attenuator application. A controllable amount of optical power can be extracted via evanescent coupling by changing the temperature of the polymer mixture, thereby changing its refractive index. The VOA under test provides a maximum attenuation of 30 ㏈ and an insertion loss of 0.1 ㏈.