• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.168-168
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• 2012

Al doped ZnO (AZO)는 태양전지, 평판 디스플레이, OELD 등 광전자 소자에 적용되는 투명전도막용 재료인 ITO의 대체 재료로서 최근에 가장 각광받고 있는 물질이다. 하지만, $2.5{\times}10^{-4}{\Omega}{\cdot}cm$의 낮은 비저항과 90% 이상의 투과도를 갖는 ITO의 비해 AZO의 특성은 아직 부족한 상황이다. 수십 년간 많은 연구자들에 의해 다양한 제조 방법과 공정 조건들로 전기적, 광학적 특성을 향상시키기 위한 노력들이 진행되어 왔다. 하지만 실리콘 반도체와는 달리 II-VI족 물질의 정확한 근본적인 원리는 아직 불분명한 상태이다. 지금까지 AZO의 특성 향상의 원인을 결정립 크기, 주상구조의 우선 방위, 결정성, Zn-O 구조내의 산소 결핍 등의 메커니즘으로 설명해 왔다. 하지만, 본 연구에서는 지금까지 제안된 상기 요인의 변화 없이 전기적, 광학적 특성을 향상시키는 것이 짧은 열처리만으로도 가능했다. AZO 박막의 전기적, 광학적 특성에 큰 영향을 미치는 보다 근본적인 원인은 도핑 효율이다. ZnO 내에 도핑된 Al의 양보다 실제로로 활성화된 Al의 비율을 올리는 것이 중요하다. 본 연구에서 구조적, 조성적 변화 없이 도핑효율을 8.9%에서 66.7%까지 증가시켰으며, 이동도는 박막 표면의 및 결정립계 사이의 과잉산소를 줄임으로서 optical phonon scattering 감소를 통하여 증가시킬 수 있고, 이러한 과잉산소의 감소는 deep level emission을 감소시킴으로서 투과도 증가에도 영향을 준다. 본 연구에서 짧은 열처리를 통해 구조적 변화 없이 도핑효율의 증가만으로 $4.8{\times}10^{-4}{\Omega}{\cdot}cm$의 비저항과 90%의 투과도를 갖는 AZO 박막을 제조하였다.

• Korean Journal of Materials Research
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• v.2 no.3
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• pp.207-212
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• 1992

The defect structure of calcium titanates with CaO excess or $TiO_2$ excess was studied by measuring electrical conductivities as a funcition of oxygen partial pressure at $85O^{\circ}C$ to $1050^{\circ}C$. Execess CaO may divide itself equally between A and B sites, resulting in $Ca_{Ti}$" and Vo", while excess $TiO_2$ form $V_{Ca}$" and Vo". The equilibrium electrical conductivity data indicate that the solubilities of CaO and $TiO_2$ in $CaTiO_3$ are 5000ppm and 2000ppm, respectively. Oxygen vacancies contributed to the ionic conduction which flatten the conductivity minima and did not make any defect association with oppositely charged defects.ely charged defects.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.3
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• pp.67-75
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• 2013

The numerical analysis for the verification of preburner's cooling characteristics applying to kerosene-LOx rocket engine has been fulfilled. The distribution of combustion gas properties in primary combustion zone was calculated by the mixture ratio based on head injector arrangement, the properties of oxygen flowing in wall channels as coolant were applied under real-gas conditions, and multi-phase mixing model was employed to calculate the mixing process of primary combustion zone with liquid oxygen which was used for wall cooling. The results of numerical analysis were compared with the experimental results, hence thermo-physical properties in cooling channels and a combustor could be quantitatively identified.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.151.2-151.2
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• 2012

터보펌프 구동에 사용된 가스발생기 생성가스를 연소기로 공급하여 주추력 발생에 사용하는 다단연소 사이클 로켓엔진은 고추력을 요하는 우주 발사체에 널리 사용되고 있다. 다단연소 사이클 로켓엔진에 사용되는 가스발생기를 예연소기라 부르며 케로신과 액체산소를 추진제로 하는 다단연소 사이클 로켓엔진에는 산화제 과잉 예연소기가 사용된다. 예연소기는 터보펌프 구동을 목적으로 하기 때문에 예연소기 생성가스의 횡단면 온도분포는 터빈에 의해 제한되는 온도범위 내에서 균일하여야 하며 넓은 운전영역에서 안정적인 연소가 이루어져야 한다. 산화제 과잉 예연소기는 모든 추진제가 혼합헤드를 통해 분사되는 방식과 추진제를 혼합헤드와 연소실로 나누어 공급하는 방식이 있다. 기술검증을 위해 산화제 일부와 연료를 혼합헤드를 통해 연소실에 공급하여 1차 연소시키고 나머지 산화제를 연소실 냉각채널을 거쳐 연소실 중앙의 분사공을 통해 연소실로 주입하여 기화시키는 형태로 최종적으로 연소압 20MPa, 혼합비 60에서 작동하는 산화제 과잉 예연소기를 설계하여 연소시험을 수행하였다. 혼합헤드에는 별도의 점화용 분사기 없이 전체 연료 분사기를 통해 점화용 연료인 TEA/TEB 혼합물을 분사하여 점화하였다. 추진제를 2단으로 공급할 수 있도록 고안된 가압식 연소시험 설비에서 10회, 누적 60초 이상의 연소시험이 성공적으로 수행되었다. 연소시험결과 넓은 작동영역에서 안정적 연소특성과 생성가스 온도 분포의 균일성을 확인할 수 있었다. 고온 고압의 산화제 과잉 예연소기 기술 확보를 통해 케로신/액체산소 다단연소 사이클 로켓엔진 개발을 위한 기술적 기반을 마련하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.869-872
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• 2011

Ignition tests of an oxidizer rich preburner for a staged combustion cycle liquid rocket engine were performed to evaluate combustion performance. Design operation conditions of the tested oxidizer rich preburner are about 60 of OF ratio and 20 MPa of combustion pressure. The entire kerosene and some LOx injected into the mixing head is burned in combustion chamber and the remaining LOx injected through center holes of combustion chamber is vaporized. Full flow ignition method with hypergolic fuel was used. Each propellant was supplied in two stages for soft ignition. Test results, low frequency oscillation was occurred in low flow rate conditions under 45% of design flow rate. Stable ignition in the course of design combustion pressure was able to induce by minimization of low flow rate ignition region to escape low frequency oscillation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.65-69
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• 2012

An oxygen rich preburner was tested and the responses from the pressure sensors were studied with FFT analysis. Since the limited capability of the static sensor, less than 250 Hz frequency domain was investigated and compared to the results of the dynamic sensors. As a result, 60 Hz harmonics were presented dominant in the combustion pressure and oxygen inlet pressure. While similar harmonics were shown with the dynamic sensor, it indicated that harmonics less than 60 Hz were very minor and the high frequency is more important.

• Journal of the Korean Chemical Society
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• v.28 no.4
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• pp.231-237
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• 1984

The x-values in the nonstoichiometric chemical formulas $YO_{1.5+x}\;and\;HoO_{1.5+x}$, have been measured in the temperature range from 700$^{\circ}$C to 1000$^{\circ}$C under oxygen pressures from $2{\times}l0^{-1}\;to\;1{\times}10^{-6}$ atm by gravimetric method. The observed x-values increase with increasing temperature and oxygen pressure. The enthalpies of formation of excess oxygen in yttrium oxide and holmium oxide decrease with decreasing oxygen pressure and are all positive values representing an endothermic process. The 1/n values calculated from the slopes of the plots of log x vs. log $P_{O2}$ increase with temperature and are positive values which means the higher oxygen pressure dependence at higher temperature. We have examined the nonstoichiometric defect and conduction mechanism from x-values and thermodynamic data.

• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.355-360
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• 1998

Reduction activity of precious metal-loaded HZSM-5 for NO has been studied and was compared to that of Cu-HZSM-5 in the presence of excess oxygen. It was found that among the catalysts used in this study, Ru-HZSM-5 was the most active catalyst for the reduction of NO to $N_2$ in the absence of hydrocarbon reductant. The highest conversion obtained was 45%. No severe inhibition of water vapor to the reduction was observed. It is suggested that the higher catalytic activity of Ru-HZSM-5 may result from the better ability to oxidize NO to $NO_2$ in the presence of excess oxygen. A proposed reaction mechanism for the reduction of NO to $N_2$ in the presence of excess oxygen is that NO is oxidized to $NO_2$ on the surface of Ru-HZSM-5 catalyst and the adsorbed $NO_2$ on the surface is then decomposed to $N_2$. $NO_2$ is supposed to the reaction.

• Korean Journal of Materials Research
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• v.8 no.12
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• pp.1090-1098
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• 1998

$RuO_2$ thin films were deposited on Si and Ru/Si substrates by rf magnetron reactive sputtering and annealed in oxygen atmosphere(1atm) to investigate their thermal stability and diffusion barrier property. $RuO_2$ thin films were thermally stable up to 700\ulcorner for 10min. in oxygen atmosphere and showed excellent barrier property against the interdiffusion of silicon and oxygen. After annealing at $750^{\circ}C$ , however, volatilization to higher oxide occurred at the surface and inside of $RuO_2$ thin film and diffusion barrier property was also deteriorated. When annealed at $800^{\circ}C$, $RuO_2$thin film showed a different microstructure from that of $RuO_2$ thin film annealed at 75$0^{\circ}C$. It is likely that surface defect structure of $RuO_2$, $RuO_3$, and excess oxygen had an influence on the mode of volatilization with increasing annealing temperature.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.2
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• pp.135-141
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• 2005

Nitric oxide(NO) reduction by methanol was investigated over $La_2O_3$ catalysts in the presence and absence of oxygen. In the absence of $O_2$, $CH_3OH$ reduced NO to both $N_2$ and $N_2O$, with selectivity to $N_2$ formation decreasing from 81-88% at 623K to 47-71% at 723 K. With 1.2% $O_2$ in the feed, the rates were 4-8 times higher, but the selectivity to $N_2$ dropped from 50% at 623 K to 9% at 723 K. The specific activities with $La_2O_3$ for this reaction were higher than those for other reductants; for example, at 773 K with hydrogen a specific activity of $34\;{\mu}mol\;NO/sec{\cdot}m^2$ was obtained whereas that for methanol was $638\;{\mu}mol\;NO/sec{\cdot}m^2$. The Arrhenius plots were linear under differential reaction conditions, and the apparant activation energy was consistantly near 15 kcal/mol with $CH_3OH$. Linear partial pressure dependencies based on a power rate law were obtained and showed a near-zero order in $CH_3OH$ and a near-first order in $H_2$.