• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.4
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• pp.262-270
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• 2001

This paper deals with a prediction method for the condensation of ternary refrigerant mixture inside a horizontal smooth tube. Based on some reliable assumptions, the governing equations for the local heat and mass transfer characteristics are derived, and the prediction for the condensation of ternary zeotropic refrigerant mixtures composed of HFC32/HFC125/HFC134a, including R407C, is carried out. The local values of vapor quality, thermodynamic states at bulk vapor, vapor-liquid interface and bulk liquid, mass flux etc. are obtained for a constant wall temperature and a constant wall heat flux conditions, and the effects of the composition of HFC32/HFC125/HFC134a on heat transfer characteristics are examined. The prediction result is also compared with experimental data for condensation of ternary refrigerant mixtures. The predicted wall temperature distribution has a similar trend with experimental data but the predicted local heat transfer coefficients are 20-30% higher than the experimental data.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.9
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• pp.2131-2137
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• 1993

This study, examines the performance and the heat pump cycle systematizing characteristics for non-azeotropic refrigerant systems. In order to conduct such an examination, the cycle characteristics of heat pumps for pure R-22, R-114, and their mixtures were experimentally investigated. The results show that cooling/heating capacities for the mixtures was more suited at the evaporating temperature of $5^{\circ}C$ than that of $0^{\circ}C$, $-5^{\circ}C$, and $-10^{\circ}C$. The C.O.P of the 50 wt% mixtures was considerably higher than for pure R-22, and the compression power of the 25 wt% was as much as 60% lower than that of pure R-22. Even small fractional mixture variations can lead to significant changes in the characteristics of the heat pump cycle. This experiment verified the importance of accurate weight fractions of refrigerant mixtures.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.12
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• pp.1049-1056
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• 2000

In this study, condensation heat transfer coefficients(HTCs) of 2 nonazeotropic refrigerant mixtures of HFC32/HFC134a and HFC134a/HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lower than the ideal values calculated by the mass fraction weighting of the pure components HTCs. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against the predicted ones by Colburn and Drew\`s film model and a good agreement was observed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.3
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• pp.381-388
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• 2003

An experimental study was carried out to measure the heat transfer coefficient in flow boiling to mixtures of HFC-l34a and HCFC-123 in a uniformly heated horizontal tube. Tests were run at a pressure of 0.6 MPa and in the ranges of heat flux 1-50 kw/$m^2$, vapor quality 0-100 % and mass velocity 150-600 kg/$m^2$s. Heat transfer coefficients of mixture were less than the interpolated values between pure fluids both in the low quality region where the nucleate boiling is dominant and in the high quality region where the convective evaporation is dominant. Measured data of heat transfer are compared to a few available correlations proposed for mixtures. The correlation of Jung et. al. satisfactorily predicted the present data, but the data in lower quality was overpredicted and underpredicted the high quality data. The correlation of Kandlikar considerably underpredicted most of the data. and showed the mean deviation of 35.1%.

• Journal of Advanced Marine Engineering and Technology
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• v.20 no.3
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• pp.91-100
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• 1996

Experimental results for forced convection condensation of non-azeotropic refrigerant mixtures inside a horizontal smooth tube are presented. The mixtures of R-22+R-134a and pure refrigerants R-22 and R-134a are used as the test fluids and a double pipe heat exchanger of 7.5mm ID and 4800mm long inside tube is used. The range of parameters are 100-300kg/h of mass flow rate, 0-1.0 of quality, and 0, 33, 50, 67, and 100 weight percent of R-22 mass fraction in the mixtures. The heat flux, vapor pressure, vapor temperature and tube wall temperature were measured. Using the data, the local and average heat transfer coefficients for the condensation have been obtained. In the same given experimental conditions, the liquid heat transfer coefficients for NARMs were considerally lower than that of the pure refrigerant of R-22 and R-134a. Local heat transfer characteristics for NARMs were different from pure refrigerant R-22 and R-134a. In some regions, local heat transfer coefficients for NARMs were increased in the following order ; Bottom$\rightarrow$Top$\rightarrow$Side. The condensation heat transfer coefficients for NARMs increased with mass velocity, heat flux, and quality, but were considerably lower than that of pure refigerant R-22 and R-134a.

• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.17-17
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• 2018

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.2
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• pp.225-233
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• 1995

Experiments were performed to investigate the heat transfer characteristics of nonazeotropic mixture R-22+R-114 in a heat pump system. The ranges of parameter, such as heat flux, mass flow rate, and quality were $8,141{\sim}32,564W/m^2$, 24~58kg/h, and 0~1, respectively. The overall compositions of the mixtures were 50 and 100 per-cent of R-22 by weight for R-22+R-114 mixture. The results indicated that there were distinct different heat transfer phenomena between the pure substance and the mixture. In case of pure refrigerant the heat transfer rates for cooling were strongly dependent upon quality of the refrigerant. Overall evaporating heat transfer coefficients for the mixture were somewhat lower than pure R-22 values in the forced convective boiling region. For a given flow rate, the heat transfer coefficient at the circumferential tube wall(top, side, and bottom of the test tube) for R-22/R-114(50/50wt%)mixture, however, was higher than for pure R-22 at side and bottom of the tube. Furthermore, a prediction for the evaporating heat transfer coefficient of the mixtures was developed based on the method of Yoshida et.al.'s. The resulting correlation yielded a good agreement with the data for the refrigerant mixtures.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.4
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• pp.1125-1133
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• 1995

Experiments were performed to investigate the condensing heat transfer characteristics of non-azeotropic mixtures of R-22 and R-114 in a heat pump system with a horizontal smooth tube as a condenser. The ranges of parameters, such as heating capacity, mass flow rate of refrigerant and quality were 780-3,480W, 24-71kg/h, and 0-1, respectively. The overall compositions of R-22 in a R-22/114 mixture were 25, 50, 75 and 100 per cent by wight. The results show that the overall condensing heat transfer coefficients for the mixtures were lower than the pure R-22 values. Local heat transfer coefficient of the pure R-22 was hghest at the top of the test tube. The local heat transfer coefficient of R-22/114 (50/50 wt%) at side and bottom of the test tube was higher than that at the top. From the obtained data, a prediction for the condensing heat transfer coefficients of the mixture was done based on the method of Fujii.

• Journal of Advanced Marine Engineering and Technology
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• v.18 no.4
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• pp.53-61
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• 1994

An experimental study on heat pump cycle systematizing characteristics for non-azeotropic refrigerant mixtures of R-22+R-114 was reported. Data were obtained under steady state condition at the ranges of parameters, 550- 2, 170kcal/h, 670-2, 990kcal/h, 24-71kg/h, and 0-1, for as cooling capacity, heating capacity, mass 25, 50, 75, and 100 per cent of R-22 by weight fraction for R-22+R-114 mixtures. The results shown that the C.O.P of the 50wt% of R-22 mixture was considerably larger than for pure R-22 and other weight fraction of R-22 mixtures, but the compression power of the 25wt% of R-22 was lower than that of the pure R-22 and the other weight fraction of R-22 mixtures. The hightest value of cooling capacity was obtained at the conditions of evaporating temperature 5.deg.C and R-22 50wt% mixture. In general, with an increase in the R-22 weight fraction for fixed values of the other parameter, the cooling capacity increased at first, obtained a maximum, and then decreasd. This verified the importance of accurate weight fractions od refrigerant mixtures in the heat pump cycle.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.15 no.7
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• pp.563-571
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• 2003

The forty vapor-liquid equilibrium data of the binary system, HFC125＋Propane, were measured between 273.15 and 313.15 K at 10 K interval and the composition range 0.2∼0.75, respectively. Experiments were performed in a circulation type apparatus in which the vapor phase was forced through the liquid phase. The composition at equilibrium were mea-sured by gas chromatography, and its response was calibrated using gravimetrically prepared mixtures. Vapor-liquid equilibrium data were calculated by using CSD equation of state and compared with the experimental data.