• Title/Summary/Keyword: 공극 형성

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Characterization of organic-inorganic hybrid compounds based on silicate for stone conservation (Silicate계 유-무기 복합 석재 강화제)

  • Kim, Eun-Kyung;Cho, Hyun-Dong;Won, Jong-Ok
    • 한국문화재보존과학회:학술대회논문집
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    • 2007.05a
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    • pp.67-68
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    • 2007
  • Tetraethyl orthosilicate (TEOS)로 형성된 gel의 film 형성 특성을 증가시키기 위하여 (3-glycidyloxypropyl)trimethoxysilane (GPTMS)와 1,2-bis(triethoxysilyl)ethane (BTEOS)를 추가한 유기-무기 복합 용액을 제조하였다. 화강암과 사암에 적용한 후, 접촉 각 및 고형화 시간, silicate의 함유량, 수분 흡수율 및 석재에 적용되었을 때의 공극률 변화를 측정하여 silicate를 기본으로 하는 복합제의 특성을 분석하였다.

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Preparation, Characterization and Gas Permeability of Asymmetric Porous Membranes of Poly(carbobenzoxyl-L-Lysin) (비대칭 다공성 폴리(카르보벤족시-L-리신)막의 제조, 평가 및 기체투과)

  • Kawai, Tohru;Lee, Young Moo;Fujita, Hiroshi
    • Membrane Journal
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    • v.6 no.2
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    • pp.96-100
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    • 1996
  • In order to improve the permeability of the homogenous membrane of poly(carbobenzoxy-L-lysin)(PCLL), which has very high selectivity of helium gas to nitrogen gas, asymmetric porous membranes of PCLL were prepared by casting from 20% solutions in dioxane and dimethylformamide(DMF), respectively. The membranes were characterized by measuring the number of the pores, the pore size distribution of the surface(the skin layer) and the thickness of the skin layer by scanning electron microscope and transmission electron microscope. The mean pore size and the pore density were lower for the membrane cast from dioxane than that from DMF, which was explained by the mechanism of the formation of the pores in the asymmetric porous membrane. The permeability coefficient observed could be roughly explained by the viscous flow through the skin layer. However, the selectivity observed was against the theory of the viscous flow.

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formation Mechanisms of 1:1 Clay Minerals by Biotite Weathering In a Granitic Gneiss (흑운모의 풍화작용에 의한 1:1 점토광물의 형성 메커니즘)

  • 이석훈;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.221-230
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    • 2002
  • Weathering of biotite shows a biotite-vermiculite-kaolinite sequence at the early stage, but presents biotite-kaolinite sequence without a significant intermediate phase (vermiculite) at the late stage from the weathering profile of the granitic gneiss. Secondary 1:1 phyllosilicates are kaolinite and halloysite which show different weathering textures originated by a different formation mechanism. Kaolinitization began from the edges of biotite and propagated toward the interior of grain along a multilayered front. $10 \AA$ layers of biotite are interleaving with $7\AA$ layers of kaolinite and c-axis of two phases is consistent. Kaolinite pseudomorph of biotite is isovolumetric, compared to the biotite boundary and includes many band-like porosities parallel to the cleavage. Platy kaolinite formed by 1:1 layer fur layer replacement of biotite. Halloysitization proceeded outward from the grain edges which were foliated as fine flakes and bent at the right angle for cleavage Halloysites were extensively fanning out and greatly increased the volume of grain. This indicated that halloysite tubes were formed by epitaxial overgrowth on the surface of biotite with import of Si and Al from the external solution by dissolution of plagioclase. These halloysites have abnormally high Fe content ( ~11%).

카르스트의 (KARST)의 지표지형과 동굴지형

  • 오종우
    • Proceedings of the Speleological Society Conference
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    • 1994.11a
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    • pp.80-81
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    • 1994
  • 카르스트는 특이한 수문학적 용식지형이며, 암석의 높은 용식성으로 인해 발달된 암석의 공극(1차적 삼투)과 암석의 구조적 변형인 절리면, 균렬면, 단층면, 층리면 등(2차적 삼투)의 확장으로 인하여 발생되어진 경관을 총칭한 것이다. 암석의 용식성만으로 카르스트가 형성된다는 것을 실명하기는 쉽지가 않다. 왜냐면 암석의 구조적인 특성이 중요한 인자가 되기 때문이다.(중략)

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카르스트 지형의 환경 보전

  • 오종우
    • Proceedings of the Speleological Society Conference
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    • 1996.09a
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    • pp.77-78
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    • 1996
  • 카르스트는 특이한 수문학적 용식지형이며, 암석의 높은 용식성으로 인해 발달된 암석의 공극(1차적 삼투)과 암석의 구조적 변형인 절리면, 균열면, 단층면, 층리면 등(2차적 삼투)의 확장으로 인하여 발생되어진 경관을 총칭한 것이다. 암석의 용식성만으로 카르스트가 형성된다는 것을 설명하기는 쉽지 않다. 왜냐하면 암석의 구조적인 특성이 중요한 인자이기 때문이다.(중략)

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Effects of Leveler on the Trench Filling during Damascene Copper Plating (전해전착시 상감 구리 배선의 충전에 미치는 레벨러의 효과)

  • Lee, Yu-Young;Park, Young-Joon;Lee, Jae-Bong;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.5 no.3
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    • pp.153-158
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    • 2002
  • The effects of leveler on the copper trench filling were investigated during damascene plating process. To investigate the trench filling effect with the addition of a leveler, a cross-section images of the electroplated trenches with the width of$0.37{\mu}m,\;and\;0.18{\mu}m$ were observed by field emission scanning electron microscope (FE-SEM). Polyethylene glycol(PEG), 3-mercapto-1-propanesulfonic acid and Janus Green B were used as a carrier, an accelerator and a leveler. $0.37{\mu}m$ trenches were superfilled without voids, but there was voids formation in $0.18{\mu}m$ trenches when the leveler was not added into the electrolyte. On the other hand $0.18{\mu}m$ trenches were superfilled without voids with the addition of the leveler due to the reduction growth rate of copper at protrusions and edges, which yield smooth final deposit surface. The leverer effect becomes more significant as the width of trenches becomes smaller when trenches are filed.

A Study of Three Dimensional Flow Characteristics near the Porous Wall (다공성 방풍벽의 3차원 유동특성)

  • Kim, Sung-Hoon;Kim, Il-Hyun;Chang, Young-Bae
    • Journal of Energy Engineering
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    • v.28 no.4
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    • pp.19-28
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    • 2019
  • A study has been done on the three dimensional turbulent flow characteristic near the porous wall. The porous holes are considered by penetrating the wall in regular arrangement, and porosity is controlled by diameter of holes. Flow characteristics near the three dimensional porous wall are compared with field test results and self-generated experimental results. FLUENT is employed for computational analysis on the effect of three dimensional porosity with flow and pressure characteristics. As a result, drag coefficient is defined and compared for three dimensional effect. The drag coefficient is mostly a function of porosity, whereas the effect of Reynolds number is minimal, and its correlation is presented in terms of three dimensional porosity.

An Experimental Study on the Characteristics of Microporous Structure Formation by Curing Condition of Cement and Blast Furnace Slag Composite (시멘트 및 고로슬래그 경화체의 양생환경에 따른 미세 공극구조 형성 특성에 관한 실험적 연구)

  • Park, Cheol;Jung, Yeon-Sik;Seo, Chee-Ho
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.33 no.12
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    • pp.63-70
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    • 2017
  • When industrial by-products like slag and fly ash are using in concrete with cement, it improves strength and durability against external deterioration factors by densifying the structure through potential hydraulic and pozzolanic reaction. But it has been pointed out that high dependence on the quality variation and the curing condition using a admixure material for concrete. In this study, the characteristics of internal micropore structure according to curing condition were analyzed for pastes and mortar specimens under using blast furnace slag powder. As a result, the variation of compressive strength and the internal microstructure were observed according to curing conditions by binder type. Particularly, using blast furnace slag powder, decrease in compressive strength were clearly observed in indoor and carbonation curing compared with water curing. The pore structure analysis also clearly observed the decrease of the gel pore existing in the CSH hydrate layer and the increase of the capillary pore in indoor and carbonation curing compared with water curing condition.

Morphology and Oxidation Characteristics of Vacuum Evaporated Zn/PET Film (Zn/PET 증착 박막의 구조 및 산화 특성)

  • 이준용;김영환
    • Journal of the Korean Vacuum Society
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    • v.3 no.2
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    • pp.220-226
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    • 1994
  • 본 연구에서는 폴리에스터(PET) 필름 위에 아연을 연속적으로 진공증착하는 실험을 수행한 후 얻어진 박막의 조직 및 조성을 SEM 및 AES로 조사하였다. 박막의 X-선 회절부석 결과, 2$ heta$=36。에서 아연의(0002)면이 주피크로 나타났으며 투과전자 현미경 관찰 결가 hcprn조로 증착시 basal plane인 (0001)면에 평행한 방향으로 우선 성장한다. 대기중 노출시 증착필름은 수분 및 산소와 반응하여 매우 다공성이며 부착성이불량한 산화피막을 형성하기 때문에 1차피막형성 후에도 산화가 지속적으로 진행되 었다. 박막내 존재하는 산소의 농도는 내부로 갈수록 지수함수적으로 감소하다가 증착금속과 기판간의 계면에서 다시 증가하는 경향을 보인다. 박막의 부식 특성을 조사현 결과 균일한 산화막 형성과 더불어 수분 존재하에 아연충에 미세한 pin hole 이 공극 부분부터 형성되어 개수가 증가하며 주위로 확장되는 형태를 나타내고 있다.

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