• Title/Summary/Keyword: 공극 형성

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Investigation on the Characteristics of Interfacial Transition Zone (ITZ) of High-Strength Cement Mortar Incorporating Graphene Oxide (그래핀 옥사이드 혼입 고강도 시멘트 모르타르의 Interfacial Transition Zone (ITZ) 특성에 관한 연구)

  • Im, Su-Min;Cho, Seong-Min;Liu, Jun-Xing;Lim, Seungmin;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.343-350
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    • 2022
  • In recent years, nanomaterials, such as nano-silica, carbon nanotubes, and graphene oxide (GO), have been suggested to improve the properties of the interfacial transition zone (ITZ) between aggregates and cement pastes, which has most adversely affected the strength of quasi-brittle concrete. Among the nanomaterials, GO with superior dispersibility has been reported to be effective in improving the properties of ITZ of normal-strength concrete by forming interfacial chemical bonds with Ca2+ ions abundant in ITZ. In this study, the effect of GO on the properties of ITZ in the high-strength mortar was elucidated by calculating the change in hydration heat release, ITZ thickness, and the porosity around ISO sand, which was obtained with isothermal calorimetry tests and scanning electron microscope image analysis, respectively.

Study on Mechanical and Electrical Properties of Expanded Graphite/Carbon fiber hybrid Conductive Polymer Composites (팽창흑연/탄소섬유 혼합 보강 전도성 고분자 복합재료의 특성 평가)

  • Oh, Kyung-Seok;Heo, Seong-Il;Yun, Jin-Chul;Han, Kyung-Seop
    • Composites Research
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    • v.20 no.6
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    • pp.1-7
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    • 2007
  • Expanded graphite/carbon fiber hybrid conductive polymer composites were fabricated by the preform molding technique. The conductive fillers were mechanically mixed with a phenol resin to provide an electrical property to composites. The conductive filler loading was fixed at 60wt.% to accomplish a high electrical conductivity. Expanded graphites were excellent in forming a conductive networking by direct contacts between them while it was hard to get the high flexural strength over 40MPa with using only expanded graphite and phenol resin. In this study, carbon fibers were added in composites to compensate the weakened flexural strength. The effect of carbon fibers on the mechanical and electrical properties was examined according to the weight ratio of carbon fiber. As the carbon fiber ratio increased, the flexural strength increased until the carbon fiber ratio of 24wt.%, and then decreased afterward. The electrical conductivity gradually decreased as the increase of the carbon fiber ratio. This was attributed to the non-conducting regions generated among the carbon fibers and the reduction of the direct contact areas between expanded graphites.

Investigation on the Technical Characteristics and Cases of Salt Cavern for Large-Scale Hydrogen Storage (대규모 수소 저장을 위한 암염 공동 저장 기술 특성 및 적용 사례 분석)

  • Seonghak Cho;Jeonghwan Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.7-16
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    • 2024
  • This study presents investigation on the technical characteristics and field cases of the salt cavern storage method for large-scale hydrogen storage. The salt cavern storage method enables effective hydrogen storage compared to other methods due to the low porosity and permeability of the rock salt that constitutes the cavern, which is not likely to leak and requires a small amount of cushion gas for operation. In addition, there is no chemical reaction between rock salt and hydrogen, and multiple injection/withdrawl cycles can be performed making it effective for peak shaving and short-term storage. The salt cavern is formed in three stages: leaching, debrining, and filling, and leakage tests are conducted to ensure stable operation. Field applications are currently performing to meet industrial demand in the surrounding area of four sites in the UK and Texas, USA, and salt cavern operation is being prepared for energy storage in European countries such as Germany and France. The investigated results in this study can be utilized as a basic guideline for the design of future hydrogen storage projects.

Selection of Concrete Surface Impregnant through Durability Tests (내구성 실험을 통한 최적 표면침투제의 선정)

  • Kwon, Seung-Jun;Park, Sang-Sun;Lee, Sang-Min;Kim, Jong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.6
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    • pp.77-86
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    • 2007
  • The repair technique utilizing surface impregnant is widely used due to its simple construction procedures and economical benefit. Surface protection through this reparing technique cannot increase the bearing capacity of concrete members much but increase the durability performance and service life efficiently. In this study, fundamental tests such as water suction and permeation are performed for concrete specimens with several organic/inorgarnic impregnant and suitable impregnant is selected on the basis of the results. Finally, durability tests such as carbonation, freezing and thawing, and chloride attack are carried out for the concrete specimens with selected impregnant and it is experimentally verified that they have good resistance to deteriorations.

An Experimental Study on the Pore Structure and Thermal Properties of Lightweight Foamed Concrete by Foaming Agent Type (기포제 종류에 따른 경량기포콘크리트의 기포구조 및 열적특성에 관한 실험적 연구)

  • Kim, Jin-Man;Choi, Hun-Gug;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.4
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    • pp.63-73
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    • 2009
  • Recently, the use of lightweight panels in building structures has been increasing. Of the various lightweight panel types, styrofoam sandwich panels are inexpensive and are excellent in terms of their insulation capacity and their constructability. However, sandwich panels that include organic material are quite vulnerable to fire, and thus can numerous casualties in the event of a fire due to the lack of time to vacate and their emission of poisonous gas. On the other hand, lightweight foamed concrete is excellent, both in terms of its insulation ability and its fire resistance, due to its Inner pores. The properties of lightweight concrete is influenced by foaming agent type. Accordingly, this study investigates the insulation properties by foaming agent type, to evaluate the possibility of using light-weight foamed concrete instead of styrene foam. Our research found thatnon-heating zone temperature of lightweight foamed concrete using AP (Aluminum Powder) and FP (animal protein foaming agent) are lower than that of light-weight foamed concrete using AES (alkyl ether lactic acid ester). Lightweight foamed concrete using AES and FP satisfied fire performance requirements of two hours at a foam ratio 50, 100. Lightweight foamed concrete using AP satisfied fire performance requirements of two hours at AP ratio 0.1, 0.15. The insulation properties were better in closed pore foamed concrete by made AP, FP than with open pore foamed concrete made using AES.

Implant restoration considering maintenance for a patient with excessive crown height space (과도한 치관높이 공간을 가진 환자에서 유지관리를 고려한 임플란트 수복증례)

  • Ma, Juri;Yang, Hong-So;Park, Sang-Won;Lim, Hyun-Pil;Yun, Kwi-Dug;Vang, Mong-Sook
    • The Journal of Korean Academy of Prosthodontics
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    • v.51 no.2
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    • pp.107-112
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    • 2013
  • Complications increases when crown height space is excessive and one should be careful of choosing type of fixed prosthesis in case crown height space is over 12 mm. In this condition, tooth seems to be longer, therefore, it is needed to use gingival shade in aesthetically important area for fixed prosthesis. In this case, fixed prosthesis which has inappropriate maintenance and hygiene could hold food, plaque, calculus, thus increase incidence of inflammation and infection. Moreover, it could lead to chronic inflammation and infection and in that case surgical improvement could be necessary. In present case report, gingival inflammation and swelling developed around prosthesis after having made it considering articulation and aesthetic view in patient who had excessive crown height space. Finding out that design of prosthesis is a factor to make it hard to maintain oral hygiene, a temporary prosthesis which has enough interproximal space and proper emergence profile was fabricated. After two months of observation, significant abnormal symptoms are not found and oral reconstruction is performed using fixed prosthesis with zircornia infrastructure and porcelain build-up based on convenient self hygiene design. Through serial treatment, inappropriate soft tissue response is not observed and satisfactory result in functional aspect comes out.

Evaluation of settlement behavior of ballasted layer mixed with specially shaped artificial ballasts under train loading (열차 하중 작용 시 특정형상 인공자갈이 혼합된 도상층에서의 침하 거동 평가)

  • Kim, Dae Sang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.35-40
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    • 2020
  • The ballast layers play a key role in distributing and supporting a trainload. On the other hand, it settles down by dynamic train loading due to large void ratios. Consequently, it requires continuous maintenance. In this paper, ballast layers mixed with three types of specially shaped artificial ballast (AB) (Rectangular, Tetrapod, Hexagonal) were modeled by using a two dimensional DEM (Discrete Element Method). Repeated loading tests were performed to evaluate the settlement behavior of the ballast layers. The smallest settlement was observed in the case of the ballast layer mixed with Tetrapod AB than in other cases, according to an analysis of the force transfer routes. In addition, contact force analysis showed that the Tetrapod AB, which has a concave shape, could easily make small and multi-channel force-transfer routes. This means that the stress in the ballast layer by the train loading transferred through the sleeper uniformly was distributed well by the AB. Therefore, the settlement of the ballast layer mixed with the concave-shaped Tetrapod AB could be reduced effectively under a repeated train loading. The effects of a decrease in settlement of the ballast layer highlight the possibility of a maintenance-free ballasted track.

Elemental Composition of Authigenic Siderites in the Early Holocene Coastal Sediments, Western Coast of Korea and Their Depositional Implication (한국 서해 초기현세 퇴적물중 자생 능철석의 원소 성분과 퇴적학적 의미)

  • Cho, J.W.;Lim, D.I.
    • Journal of the Korean earth science society
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    • v.23 no.8
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    • pp.697-706
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    • 2002
  • Authigenic siderite grains, ranging 100 to 250-${\mu}$m in diameter, are abundant in an about 8,600-year-old sediment layer in Namyang Bay, west coast of Korea. The siderites exhibit the aggregated spherulitic morphology with well-developed rhombs on the grain surfaces. They consist mostly of FeCO$_3$ (average, 65%) and MnCO$_3$ (average, 22%) with low Mg/Ca ratio (less than 0.4) in their bulk composition. A series of compositional ternary discrimination diagrams, together with high Mn and low Mg contents, show that only meteoric porewater was involved in siderite precipitation, assuming that depositional environment of host sediment is an organic-rich freshwater system. Considering a series of results such as radiocarbon age, authigenic Mn-rich siderite and lithological features, siderite-hosting sediment (unit Tl) is interpreted as freshwater swamp or bog deposition, infilling the topographic depressions that locally existed before the formation of mid-to-late Holocene tidal deposits. Center-to-margin compositional variation within individual grain is very systematic; Mn and Ca decrease towards the margin of a siderite grain, while Fe and Mg increase. It suggests that the spherulitic siderites were precipitated in this sedimentary layer in a series during the early diagenesis of MnOx-FeOx reduction under steady-state.

Gas Hydrate Exploration by using PCS(Pressre Core Sampler): ODP Leg 204 (압력코어를 이용한 가스 하이드레이트 탐사: ODP Leg 204)

  • Lee Young-Joo
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.165-176
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    • 2005
  • Natural gas in deep sediment may occur in three phases based on the physical and chemical conditions. If the concentration of gas in pore water is less than the solubility, gas is dissolved. If the concentration of gas is greater than its solubility (water is saturated or supersaturated with gas), gas occurs as a fee gas below the gas hydrate stability Lone (GHSZ) and is present as solid hydrate within the GHSZ. The knowledge of gas concentration in deep sediment appears critical to determine the phase of natural gases and to understand the formation and distribution of gas hydrate. However, reliable data on gas concentration are usually available only from the upper section of marine sediment by the headspace gas technique, which is widely used for sampling of gases from the sediments. The headspace gas technique represents only a fraction of gases present in situ because sediments release most of the gases during recovery and sampling. The PCS (Pressure Core Sampler) is a downhole tool developed to recover a nominal $1{\cal}m$ long, $4.32{\cal}cm$ diameter core containing $1,465cm^3$ of sediment, pore water and gas at in situ pressure up to 68.9 MPa. During Leg 204, the PCS was deployed at 6 Sites. In situ methane gas concentration and distribution of gas hydrate was measured by using PCS tool. Characteristics of methane concentration and distribution is different from site to site. Distribution of gas hydrate in the study area is closely related to characteristics of in situ gas concentration measured by PCS.

Large-scale, Miocene Mud Intrusion into the Overlying Pleistocene Coastal Sediment, Pohang City, SE Korea: Deformation Mechanism, Trigger, and Paleo-seismological Implication for the 2017 Pohang Earthquakes

  • Gihm, Yong Sik;Ko, Kyoungtae;Choi, Jin-Hyuk;Choi, Sung-ja
    • Economic and Environmental Geology
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    • v.53 no.5
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    • pp.585-596
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    • 2020
  • The 2017 Pohang Earthquakes occurred near a drill site in the Pohang Enhanced Geothermal System. Water injected for well stimulation was believed to have reactivated the buried near-critically stressed Miocene faults by the accumulation of the Quaternary tectonic strain. However, surface expressions of the Quaternary tectonic activity had not been reported near the epicenter of the earthquakes before the site construction. Unusual, large-scale water-escaped structures were identified 4 km away from the epicenter during a post-seismic investigation. The water-escaped structures comprise Miocene mudstones injected into overlying Pleistocene coastal sediments that formed during Marine Isotope Stage 5. This indicates the vulnerable state of the mudstones long after deposition, resulted from the combined effects of rapid tectonic uplift (before significant diagenesis) and the development of an aquifer at their unconformable interface of the mudstone. Based on the detailed field analysis and consideration of all possible endogenic triggers, we interpreted the structures to have been formed by elevated pore pressures in the mudstones (thixotropy), triggered by cyclic ground motion during the earthquakes. This interpretation is strengthened by the presence of faults 400 m from the study area, which cut unconsolidated coastal sediment deposited after Marine Isotope Stage 5. Geological context, including high rates of tectonic uplift in SE Korea, paleo-seismological research on Quaternary faults near the study area, and historical records of paleoearthquakes in SE Korea, also support the interpretation. Thus, epicenter and surrounding areas of the 2017 Pohang Earthquake are considered as a paleoseismologically active area, and the causative fault of the 2017 Pohang Earthquakes was expected to be nearly critical state.