• Title/Summary/Keyword: 고정화율

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A Study of Full Scale PUV/US Hybrid System for Contaminant Treatment in Groundwater (지하수 오염물질 처리를 위한 Full Scale PUV/US Hybrid System 연구)

  • Han, Jonghun;Park, Wonseok;Lee, Jongyeol;Heo, Jiyong;Her, Namguk
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.10
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    • pp.575-580
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    • 2017
  • Chlorinated hydrocarbons (TCE and PCE), petroleum hydrocarbons (BTEX, PAHs, and TPH), and explosive compounds (TNT, RDX, and HMX) have been detected in underground water countrywide. The overall objective of this study is to evaluate sono-catalytic degradation coupled with the use of PUV in order to understand the fate and transport of a representative selection of non-biodegradable contaminants (i.e., TCE, PCE, BTEX, PAHs, TPH, TNT, RDX, and HMX) in groundwater. Both ultraviolet (UV) and ultrasound (US) systems are used in degrading of organic contaminants and they can thus be applicable simultaneously as an UV/US hybrid system in attempts further to increase the degradation efficiency. Results indicate that synergistic effect of UV/US hybrid system is closely correlated to the enhancement of sono-chemical reactivity with the UV-US interaction of increasing the formation rate of OH by providing additional $H_2O_2$ production through the pyrolysis of water molecules during UV/US hybrid irradiation.

An Analysis of the Water Saturation Processes in the Engineered Barrier of a High Level Radioactive Waste Disposal System (고준위폐기물처분시스템 공학적 방벽에서의 지하수 포화공정 해석)

  • Park, Jeong-Hwa;Lee, Jae-Owan;Kwon, Sang-Ki
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.1
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    • pp.23-32
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    • 2011
  • An engineering scale test, which is called KENTEX, was carried out to understand and to analyze the coupled thermal, hydrological and mechanical phenomena in the engineered barrier system(EBS) of Korean reference disposal system. Using the experimental data obtained from KENTEX, the water saturation processes in bentonite could be analyzed. From the comparison between the model calculation using ABAQUS and the experimental results, the difference of the water content between them in the unsaturating part was large because the drying phenomena due to moisture redistribution by the temperature gradient could not be included in the model. In the saturating part, the difference of the water content between them was decreased gradually and showed to be small in the full saturation. And the time of about 95% saturation could be estimated about 500 days from the model calculation and experimental results. Also it could be known that the moisture redistribution in the unsaturated part could not be affected on the saturation time of bentonite in the repository. Therefore, it is considered that this model could be used to quantitatively predict the water saturation time in bentonite as EBS for the disposal system.

Oil Absorptive Properties of Polypropylene Knit Fabric Treated with Oleophilic Acrylic Resin (친유성 아크릴 수지로 처리된 폴리프로필렌 편직물의 유흡착 성질)

  • Jeong, Hwa-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.2
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    • pp.528-535
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    • 2016
  • Two types of oleophilic acrylic prepolymers were prepared by the solution copolymerization of either ethyl acrylate (EA) or lauryl acrylate (LA) with hydroxy ethyl acrylate (HEA). For the formation of oil-absorbent materials, a mixed solution of the prepolymer and hexamethylene diisocyanate (HDI) as a cross-linker in toluene was applied to polypropylene knit velvet fabric through the conventional pad-dry-cure procedure. The gel fraction of the crosslinked resin, EA-HEA-HDI, increased with increasing feed ratio of HEA to total acrylate or HDI concentration. The oil absorbancy and retention ratio of the prepared materials were compared according to the add-on ratio of resin to fabric, and were assessed with n-decane, toluene, soybean oil, lubricant and bunker C oil as test oils. The optimal oil absorbancy of the materials were observed at around 6% of the add-on ratio for all these oils except for soybean oil. On the other hand, the oil retention ratio increased as the add-on ratio increased. Futhermore, heavier and more viscous oil generally showed higher oil retention ratios. In addition, the oil absorbancy of the materials treated with LA-HEA-HDI resin was higher than that treated with EA-HEA-HDI resin, which showed that the acrylic resins are more absorptive with increasing length of their side alkyl chain.

Influence of Thermal Oscillation on Quality of Frozen Foods Stored in Domestic Refrigerator (가정용 냉장고의 제상 주기와 온도 변화가 저장 식품의 품질에 미치는 영향)

  • Kang, Gil-Jin;Auh, Joong-Hyuck;Kim, Myo-Jeong;Cho, Kwang-Yeun;Choi, Young-Hoon;Jung, Dong-Sun;Kook, Seung-Uk;Park, Kwan-Hwa
    • Korean Journal of Food Science and Technology
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    • v.28 no.4
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    • pp.624-631
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    • 1996
  • Effect of fluctuation range and intervals of defrosting temperature on quality of frozen foods stored in a domestic refrigerator equipped with an automatic defrost system was evaluated. As defrost system was operated, temperatures of domestic refrigerators were elevated from $-18^{\circ}C\;to\;-5^{\circ}C\;and\;-15^{\circ}C$, and fluctuation intervals were l6 hrs and 30 hrs, respectively. Quality deterioration such as protein denaturation, vitamin loss, exudate production and changes in appearance of frozen foods was minimized by reducing temperature oscillation during storage. Considerable effects of thermal oscillation on ice crystal sizes were observed for frozen beef tissue and ice cream. TTI (time temperature indicator) system also proved that the temperature control of defrost system in domestic refrigerator can improve the quality of foods during storage.

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Decontamination of Waste Water Polluted with Phenolic and Anilinic Compounds Using Plant Materials (식물체를 이용한 Phenol 및 Aniline성 폐수의 정화)

  • Lee, Jung-Eun;Park, Jong-Woo;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.19 no.3
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    • pp.228-233
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    • 2000
  • This study was carried out to estimate the possibility on the removal of phenols and anilines, which were contained in pulp or dye waste water, and the reusability of plant materials, shepherd's purse and turnip. Most of phenols catalyzed with shepherd's purse were removed more than 90% in the presence of $H_2O_2$, and the removal was ranged from 53.1% for 2,6-DMP to more than 99% for 2,4,6-TCP when turnip was used as catalysts. The removal of anilines catalyzed with shepherd's purse was ranged from 42.2% for 2-CA to 78.7% for 3,4-DCA in the presence of $H_2O_2$, and in case of turnip, from 31.5% for 2-CA to 90.0 % for 2,4-DCA. The reuse of plant materials was proved to be possible for not only the batch method but also the continuous method. No decreasing removal was observed during 30 cycles in waster water contaminated with 100ppm of 2,4-DCP. However, it was observed that the removal was decreased with increasing the number of cycles in higher concentration of 2,4-DCP(800ppm). Therefore, it could be suggested that the number of reusable cycles depends on the initial concentration of substrates.

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Urban Stormwater Runoff Treatment by the RFS (RFS를 이용한 도시유출수처리)

  • Lee, Jun-Ho;Bang, Ki-Woong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.1
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    • pp.159-167
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    • 2000
  • In recent years, combined and separated sewer overflows (CSOs, SSOs) have been recognized as a significant pollution problem. To solve this problem a series of experiments were performed in a small scale Rapid Floc Settler (RFS) device to determine its ability in removing micro particles and dissolved materials from polluted waters. The RFS device is a compact physico-chemical wasterwater treatment system. Polyacrylamide (PAM) is used as a coagulant for treating stormwater in the RFS. The results of Jar test showed that PAM could be an excellent coagulant as compared with aluminum sulfate. and ferric chloride. In several experimental conditions, the influence of different variation parameters was tested to measure the efficiency of the RFS. Tests have been carried out with typical CSOs concentrations (50~1.000mg SS/L). The treatment efficiency with regard to SS and COD, which can be obtained at an overflow rate of $130m^3/m^2/day$, are 90% and 80%, respectively. Comparing other sedimentation technologies with RFS, the overflows rate of RFS is ten times faster. The distribution of particle size and number were analyzed. The RFS is suitable for the treatment of CSOs and also the removal of settleable and dissolved materials in urban stormwater runoff.

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Immobilization of Cyclodextrin Glucanotransferase for Production of 2-O-\alpha-D-Glucopyranosyl L-Ascorbic Acid. (2-O-\alpha-D-Glucopyranosyl L-Ascorbic acid 생산을 위한 Cyclodextrin glucanotransferase의 고정화)

  • 성경혜;김성구;장경립;전홍기
    • Microbiology and Biotechnology Letters
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    • v.31 no.4
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    • pp.368-376
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    • 2003
  • Cyclodextrin glucanotransferase (CGTase) from Paenibacillus sp. JB-13 was immobilized on various carriers by several immobilization methods such as ionic binding, covalent linkage and ultrafiltration to improve the process performance. The ultrafiltration and covalent linkage with CNBr-activated sepharose 4B were found as the best method for immobilization of CGTase. The ability of CGTase immobilization onto CNBr-activated sepharose 4B was as high as 18,000 units/g resin when the conditions was as follows: contact time 9 hrs at $37^{\circ}C$, pH 6.0, 100 nm and enzyme loading 24,000 units/g resin. The optimum conditions for production of 2-O-$\alpha$-D-Glucopyranosyl L-Ascorbic acid by immobilized CGTase turned out to be: pH 5.0, temperature $37^{\circ}C$, 20% substrate solution containing 8% (w/v) of soluble starch and 12% (w/v) of L-ascorbic acid sodium salt, 100 rpm, far 25 hrs and with 800 units of immobilized CGTase/ml substrate solution. Moreover the CGTase activity could be stably maintained for 8 times of repetitive reactions after removing products by ultrafiltration through YM 10 membrane.

A Study of the Utilization of Feldspathic Sand as a Fortified Functional Filtering Material for Water Purification (고 기능성 수질 정화 여과재로서의 장석질 모래 활용연구)

  • 고상모;송민섭;홍석정
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.4
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    • pp.283-293
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    • 2003
  • Domestic water treatment plants operate the rapid and slow filtering system using the filtering sands. Most of them are composed of beach sands, which have less sorption capacity of heavy metals as well as organic contaminants. Therefore, the development of fortified functional filtering materials with high removal capacity of organic and inorganic contaminants is needed to prevent the unexpected load of contaminated source water. This study aims to test the hydrochemical change and the removing capacity of heavy metals such as Cd, Cu, and Pb on the Jumunjin sand, feldspathic sand(weathering product of Jecheon granite), feldspathic mixing sand I(feldspathic sand mixed with 10 wt% zeolite), and feldspathic mixing sand II (feldspathic sand mixed with 20 wt% zeolite). Feldspathic mixing sand I and II showed the eruption of higher amounts of cations and anions compared with the Jumunjin sand and feldspathic sand. They also showed higher eruption of Si, Ca, $SO_4$ ions than that of Al, $NO_3$, Fe, K, Mg, and P. Feldspathic mixing sand II caused higher eruption of some cations of Na, Ca, Al than feldspathic mixing sud I, which is the result controlled by the dissolution of zeolite. Jumunjin sand and feldspathic sand showed very weak sorption of Cd, Cu and Pb. In contrast to this, feldspathic mixing sand I and II showed the high sorption and removal capacity of the increasing order of Cd, Cu and Pb. Feldspathic mixing sand II including 20% zeolite showed a fortified removal capacity of some heavy metals. Therefore, feldspathic mixing sand mixed with some contents of zeolite could be used as the fortified filtering materials for the water filtering and purification in the domestic water treatment plants.

Development of Self-Managed Food Sanitation Check-List and On-Site Monitoring of Food Sanitation Management Practices in Restaurants for Control of Foodborne Illness Risk Factors (식중독 발생 위험요인 관리를 위한 외식업체 자가위생관리점검표 개발 및 현장모니터링)

  • Chung, Min-Jae;Choi, Jung-Hwa;Ryu, Kyung;Kwak, Tong-Kyung
    • Korean journal of food and cookery science
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    • v.26 no.5
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    • pp.603-616
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    • 2010
  • Based on recent dramatic increases in foodborne outbreaks in restaurants, self-managed sanitation systems are now recommended to control contributing risk factors. This study aimed to improve sanitation management practices in restaurants and had two objectives. First, we tried to develop a self-managed sanitation check-list, including risk factors contributing to foodborne illness and Korean food hygiene regulation articles. We also tried to evaluate current sanitation management practices in restaurants according to operation and restaurant type. Thirty restaurants were evaluated by on-the-spot inspectors using an auditing tool consisting of four dimensions, seventeen categories, and forty-one items. Total compliance rate categorized by operation type significantly differed between chain restaurants and self-managed restaurants, with values of 85.5% and 51.6%, respectively. Therefore, self-managed restaurants, which showed the lowest compliance rate of below 30.0%, need more strict control to improve current unsanitary management practices, specifically relating to 'sterilization of knives, chopping boards, and wiping cloths', 'sanitation training', 'not allowing access into the kitchen to outsiders', 'handling of food or utensils on shelves at a 15 cm distance away from floor', 'prevention of cross-contamination of cooked foods or vegetables', and 'records of kitchen access or inspection'. Thus, an effective food sanitation system is essential and should be implemented to improve the existing sanitary conditions in restaurants. However, the most important factor to achieving food sanitation management objectives is food handlers' self-motivation.

Evaluation of Characteristics of Sludge generated from Active Treatment System of Mine Drainage (광산배수의 적극적 처리시설에서 발생하는 슬러지 특성 평가)

  • Jung-Eun Kim;Won Hyun Ji
    • Economic and Environmental Geology
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    • v.56 no.4
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    • pp.409-419
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    • 2023
  • Acid mine drainage(AMD) treatment is classified as both passive and active treatment. During the treatment, about 5,000 tons of neutralization sludge is generated as a by-product per year in Korea. This study was conducted to evaluate the characteristics of sludge generated from physico·chemical treatment processes as an active treatment from 5 different sources (D, H, S, T, Y) and the possibility of the sludges being recycled. The sludges have a pH range of 5.86 ~ pH 7.89, and a water content range of 51% ~ 82%. Most of particle sizes were less than 25 ㎛. In analysis of inorganic elements, the concentration of Al, Fe, and Mn were between 1,189 mg/kg ~ 129,344 mg/kg, 106,132 mg/kg ~ 338,011 mg/kg, and 3,472 mg/kg ~ 11,743 mg/kg, respectively. The concentration of As and Zn in sludge-T, Cd in sludge-D, Ni in sludge-H, Zn in sludge-S, and Cd in sludge-Y exceeded the soil contamination standards of Korea. The results from 2 separate kinds of leaching test, the Korea Standard Leaching Test(KSLT) and Toxicity Characteristic Leaching Procedure(TCLP), showed that all the sludges met the Korea groundwater standards. From the XRD and SEM-EDS analysis, the peaks of calcite and quartz were found in the sludges. The sludge also had a high proportion of Fe and O, and the majority of the composition was amorphous iron hydroxide.