• Title/Summary/Keyword: 고압수소

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Volumetric Hydrogen Sorbent Measurement at High Pressure and Cryogenic Condition - Basic Measurement Protocols (부피법을 이용한 고압·극저온 수소 흡착량 측정 방식의 기본 원리)

  • OH, HYUNCHUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.4
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    • pp.349-356
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    • 2016
  • Volumetric capacity metrics at cryogenic condition are critical for technological and commercial development. It must be calculated and reported in a uniform and consistent manner to allow comparisons among different materials. In this paper, we propose a simple and universal protocol for the determination of volumetric capacity of sorbent materials at cryogenic condition. Usually, the sample container volume containing porous sample at RT can be directly determined by a helium expansion test. At cryogenic temperatures, however, this direct helium expansion test results in inaccurate values of the sample container volume for microporous materials due to a significant helium adsorption, resulting significant errors in hydrogen uptake. For reducing this container volume error, therefore, we introduced and applied the indirect method such as 'volume correction using a non-porous material', showing a reliable cold volume correction.

The Evaluation of Reliability for the High Pressure Hydrogen Storage System of Fuel Cell Vehicle (연료전지자동차의 고압수소저장시스템 신뢰성 평가)

  • Jang, Gyu-Jin;Choi, Young-Min;Ahn, Byung-Ki;Lim, Tae-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.266-275
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    • 2008
  • The performance improvement of each part for durability, safety and cost of high pressure storage system for fuel cell vehicle has been focused so far. However, for the mass production of fuel cell vehicle, it is necessary to evaluate durability and safety in system module and vehicle level. The test procedure to evaluate vibration and collision safety of high pressure hydrogen storage system for the fuel cell vehicle is established and its reliability is verified.

Series Stacking Techniques of Electrochemical Hydrogen Compressors (전기화학식 수소 압축기 직렬 스택 기술)

  • SANG HOON CHO;CHANG JONG KIM;MIN SOO KIM;DONG KYU KIM
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.168-174
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    • 2024
  • The electrochemical hydrogen compressor was run under diverse operating conditions in order to probe its capabilities and limitations. It was found that, unlike single-cell operations, the electrochemical hydrogen compressor stack performance improved with a rise in temperature. This improvement in performance was attributed to the gradual weakening of the electro-osmotic drag over time, impacting membrane resistance. As a result of these experiments, compression levels, up to an impressive 120 bar, using the electrochemical hydrogen serial stack were achieved.

Process Simulation of HCNG Refueling System (HCNG 충전 시스템 공정모사)

  • Kim, Sang-Min;Han, Jeong-Ok;Lee, Yeong-Cheol;Lee, Joong-Seong;Kim, Yong-Cheol;Chae, Jeong-Min;Hong, Seong-Ho
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.1-7
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    • 2013
  • In this study, simulation work of HCNG refueling system was performed. The hydrogen was produced from steam reforming process by natural gas. The conversion of natural gas is increased as SCR is increased. but it was no significant difference more than 3 of SCR and fuel throughput is increased as GHSV is increased. Both conversion and fuel throughput levels was optimized when the $1700h^{-1}$ of GHSV. CNG was compressed from low pressure natural gas. For the mixing of $H_2$ and CNG is mixed with the high pressure conditions such as 400bar of $H_2$ and 250bar of natural gas. Single-stage compression was required more power than multi stage. So, multi stage compression was suggested for high pressure compression. We calculated the intermediate pressure to minimize total required power of compressors. The intermediate pressure for $H_2$ and natural gas were derived at 61 and 65 bar, respectively.

A Suggestion of the Hydrogen Flame Speed Correlation under Severe Accidents (중대사고시 수소연소에 의한 화염속도 상관식 제시)

  • Kang, Chang-Woo;Chung, Chang-Hyun
    • Nuclear Engineering and Technology
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    • v.26 no.1
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    • pp.1-8
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    • 1994
  • The flame speed correlation considering thermal-hydraulic phenomena under severe accidents is proposed and correction coefficients are defined. This correlation modifies the pressure dependency in Iijima-Takeno correlation and adds the steam suppression effects to it in the anticipated hydrogen and steam concentration ranges under severe accidents. The existing models of flame speed due to hydrogen combustion under severe accidents are based on the experiments which were performed merely at room temperature and atmospheric pressure. They have difficulty in predicting a accurate flame speed in a case of high temperature and pressure during severe accidents. Thus the flame structure is assumed as a prerequisite to the reliable determination of flame speed and theoretical model is developed. To examine the validity, flame speeds in various conditions calculated by this model are compared with those obtained by the calculation of the existing correlations of the codes such as improved HECTR and MAAP. Also the steam suppression ratio is quantified and the steam suppression coefficient is defined as a composition of mixture. Initial temperature and pressure dependencies are investigated and correction coefficents are determined. More experimental studies can be recommended to improve this correlation to its further works.

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TNT Explosion Demonstration and Computational Fluid Dynamics for Safety Verification of Protection Wall in Hydrogen Refueling Station (수소충전소 방호벽 안전성 검증을 위한 TNT 폭발실증 및 전산유동 해석)

  • Yun-Young Yang;Jae-Geun Jo;Woo-Il Park;Hyon Bin Na
    • Journal of the Korean Institute of Gas
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    • v.27 no.4
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    • pp.102-109
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    • 2023
  • In realizing a hydrogen society, it is important to secure the safety of the hydrogen refueling station, which is the facility where consumers can easily meet hydrogen. The hydrogen refueling station consists of compressed gas facilities that store high-pressure hydrogen, and there is a risk that the high-pressure compressed gas facility will rupture due to a fire explosion due to hydrogen leakage in the facility or the influence of surrounding fires. Accordingly, the Korea Gas Safety Corporation is making every effort to find out risk factors from the installation stage, reflect them in the design, and secure safety through legal inspection. In this study, a TNT explosion demonstration test using a protection wall was conducted to confirm the safety effect of the protection wall installed at the hydrogen refueling station, and the empirical test results were compared and verified using FLACS-CFD, a CFD program. As a result of the empirical test and CFD analysis, it was confirmed that the effect of reducing the explosion over-pressure at the rear end of the protection wall decreased from 50% to up to 90% depending on the location, but the effect decreased when it exceeded a certain distance. The results of the empirical test and computer analysis for verifying the safety of the protection wall will be used in proposals for optimizing the protection wall standards in the future.

Performance and Thermal Endurance Tests of a High Pressure Pump Fueled with DME (DME를 연료로 하는 고압펌프의 성능 및 내열 특성 평가)

  • BAEK, BUM-GI;LIM, OCK-TAECK
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.1
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    • pp.89-95
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    • 2020
  • The main scope of this paper is to see if the conventional pump can be properly used for a specific fuel, Di-methyl Ether (DME) despite of its low lubricity and high reactivity in the experimental conditions. A wobble plate type fuel pump was connected to the common rail to verify that the pump could deliver the fuel at the required pressure and resultantly DME could be used as fuel without modifying the original pump. At each required pressure (30 Mpa, 35 Mpa, 40 Mpa, 45 Mpa, and 50 Mpa), the pump met the pressure required by the common rail. In addition, pump performance experiments tended to follow the usual performance curve while the flow rate decreased as the pressure increased. The maximum flow rate of the pump was 470 kg/h at 30 Mpa and all measurements were taken with keeping DME temperature below 60℃.

A Computational Work of Critical Nozzle Flow for High-Pressure Hydrogen Gas Mass Flow Measurement (고압수소 유량계측용 임계노즐 유동의 수치해석적 연구)

  • Lee, Jun-Hee;Kim, Heuy-Dong;Park, Kyung-Am
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.227-230
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    • 2006
  • The method of mass flow rate measurement using a critical nozzle is well established in the flow satisfying ideal gas law. However, in the case of measuring high-pressure gas flow, the current method shows invalid discharge coefficient because the flow does not follow ideal gas law. Therefore an appropriate equation of state considering real gas effects should be applied into the method. The present computational study has been performed to give an understanding of the physics of a critical nozzle flow for high-pressure hydrogen gas and find a way for the exact mass flow prediction. The two-dimensional, axisymmetric, compressible Navier-Stokes equations are computed using a fully implicit finite volume method. The real gas effects are considered in the calculation of discharge coefficient as well as in the computation. The computational results are compared with the previous experimental data and predict well the measured mass flow rates. It has been found that the discharge coefficient for high-pressure hydrogen gas can be corrected properly adopting the real gas effects.

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Effect of Tempering Temperature on Hydrogen Embrittlement of Cr-Mo Low Alloy Steels for High-pressure Gaseous Hydrogen Storage (고압수소 저장용 Cr-Mo계 저합금강의 수소취성에 미치는 템퍼링 온도의 영향)

  • M. S. Jeong;H. C. Shin;S. G. Kim;B. Hwang
    • Transactions of Materials Processing
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    • v.33 no.3
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    • pp.185-192
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    • 2024
  • This study examined how varying tempering temperatures affect the susceptibility of Cr-Mo low alloy steels to hydrogen embrittlement. A slow strain-rate test (SSRT) was carried out on the steels electrochemically pre-charged with hydrogen in order to examine the hydrogen embrittlement behavior. The results showed that the hydrogen embrittlement resistance of the Cr-Mo low alloy steels improved with increasing tempering temperature. Thermal desorption analysis (TDA) revealed that diffusible hydrogen content decreased with increasing tempering temperature, accompanied by a slight increase in the peak temperature. This decrease in hydrogen content was likely due to a reduction in dislocation density which served as reversible hydrogen trap sites. These findings underline the significant role of tempering temperature in enhancing the hydrogen embrittlement resistance of Cr-Mo low alloy steels.