• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.218-222
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• 2011

During the development of the iridium catalyst for domestic production, the catalyst failure, loss, sintering phenomena are observed by high pressure and temperature. By these abnormal failure of catalyst bed, the performance of thruster is degraded. To figure out the detail phenomena on the damaged catalyst bed, a numerical analysis code is developed by assuming the catalyst bed as an one dimensional porous media. The numerical analysis code is validated with experiment data. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure. Through these numerical analyses we figure out the effect of the catalyst loss on the decomposition of hydrazine and ammonia.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.87-90
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• 2007

Fuel cell power system was developed for high-endurance unmanned aerial vehicle (UAV). Liquid chemical hydride was selected as a fuel due to its high energy density. Liquid storage of the fuel is an ideal alternative solution of the existing compressed hydrogen storage. The fueling system that extracts hydrogen from chemical hydride consists of catalytic reactor, micro-pump, fuel cartridge, separator, and controller. The fuel cell power system including the fueling system and the fuel cell that generates electricity was integrated into a proposed UAV. The performance verification of the fuel cell power system was performed to use as a power plant of the UAV.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.85-88
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• 2010

This study has been mainly motivated to numerically model the supercritical mixing and combustion processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the extended $k-{\varepsilon}$ turbulence model. To account for the real fluid effects, the propellant mixture properties are calculated by using SRK (Souve-Redlich-Kwong) equation of state. In order to realistically represent the turbulence-chemistry interaction in the turbulent nonpremixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the real fluid effects and the precise structure of gaseous methane/liquid oxygen coaxial jet flame.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.11a
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• pp.473-474
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• 2003

최근 수 십 년간 발전소의 연소효율은 급속히 향상되어왔으나 $CO_2$, NOx 등과 같은 온실 유해가스의 제어에 관한 심각한 문제점들을 직면한 상태이다. 발전공정에서 발생되는 온실 유해가스의 저감 방법으로 매체순환식 가스 연소발전 공정이 최근에 새로운 대안으로 제시되고 있다 그러나 매체순환식 가스연소시스템 내부의 bead상 매체입자들이 입자간 혹은 입자와 반응기 벽간의 충돌과 마찰에 의하여 마모가 되게 되고, 그 결과 원하지 않는 량의 마모입자가 배출가스와 함께 배출되게 된다. 세라믹 캔들필터는 고온고압 연소공정 등에서 배출되는 가스내의 입자상 오염물질을 회수 처리하는데 효과적인 장치로써 널리 개발되고 있다. (중략)

• JOURNAL OF ELECTRICAL WORLD
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• s.254
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• pp.53-61
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• 1998

오존은, 그 강력한 산화력에 의하여 살균, 탈취, 탈색과 유기물 제거 등의 효과를 복합적으로 얻을 수 있고 또한 신속하게 산소로 분해되어 잔류하지 않기 때문에 환경개선에 사용하기에 이상적인 물질이다. 미쓰비시전기에서는 이러한 오존의 이점에 착안하여 1970년부터 오존발생기와 오존처리설비의 개발, 제품화를 추진하여 왔다. 오존에 의한 고도처리가 널리 일반에게 인정되어 그 수요가 높아지고 있는 오늘날에 있어서도 보다 많은 오존설비의 보급을 위하여 오존기술의 개발에 힘쓰고있다. 본고에서는 상하수도 오존고도처리의 기술동향의 일부로 시도되고 있는 다음의 세 가지 내용을 소개한다. (1)오존처리시스템의 자에너지, 고효율화 기술 방전갭의 단축화, 관분내압력의 고압화로 고농도$\cdot$고효율의 오존발생을 실현하여 자전력화를 가능케 한 신형오조나이저를 개발 제품화하였다. (2)오존 반응조 내에서의 산기장치특성의 파악 모델화가 곤란한 신기장치에 대하여 실설비규모의 실험설비를 사용하여 그 산기특성을 분명히 하였다. (3)과산화수소첨가 오존처리법에 의한 하수처리수의 재생이용 과산화수소첨가 오존처리법에 의하여 장기간에 걸쳐 하수처리수를 전유기탄소(TOC)3mg/$\ell$이하로까지의 처리를 달성하여 하수처리수를 수도수레벨로까지 고도로 정화할 수 있음을 실증하였다.

• Applied Chemistry for Engineering
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• v.26 no.1
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• pp.74-79
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• 2015

In this study, to obtain isoindoline compounds with the high thermal resistance and reddish yellow color using an environmental friendly method without the use of any surfactants, isoindoline derivatives with different structures were added at various reaction temperatures for the synthesis and the product was then crystallized by controlling temperatures and times in autoclave. Chemical structures, particle sizes, color differences, and optical properties were evaluated by the means of FT-IR, FE-SEM, UV-Vis spectroscopy, PSA (particle size analyzer) and Zeta potential analyzer. The samples with an enhanced dispersibility, highly thermal resistance, uniform particle sizes were achieved possibly due to the addition of isoindoline derivatives into the crystallization processing mixtures. The color change trend was also observed depending upon synthesis conditions.

• Applied Chemistry for Engineering
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• v.7 no.6
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• pp.1156-1163
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• 1996

This study is related to the investigation of the characteristics of quaternary ammonium salt catalyst on the addition reaction of carbon dioxide and glycidyl methacrylate(GMA) to form(2-oxo-1,3-dioxolane-4-yl)methacrylate(DOMA). Among the salts tested, the ones with higher alkyl chain length and with more nucleophilic counter anion showed a higher catalytic activity. Mixed catalysts of NaI and 18-crown-6 showed a good yield of DOMA, but when they are used alone, they showed no catalytic activity. The DOMA monomer was obtained in low polar solvents, while poly(DOMA) could be directly synthesized in aprotic dipolar solvents. Kinetic studies carried out by measuring $CO_2$ pressure in a high pressure batch reactor showed that the reaction rate was first order to the concentration of GMA and $CO_2$ respectively. The rate constant(k) was 0.56L/mol hr and Henry's constant(H') of $CO_2$ in diglyme at $80^{\circ}C$ was $6.5{\times}10^{-4}mol/L{\cdot}kPa$.

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.240-248
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• 1990

The catalytic activity and selectivity of metal loaded H-mordenite for transalkylation of $C_9$ aromatics were studied in a continuous flow fixed bed reactor under high pressure. Nickel loaded H-mordenite(T-Ni) catalyst showed high activity and slow decay of activity. Molybdenum and nickel loaded H-mordenite(T-NiMo) catalyst also showed high activity and suppressed coking of hydrocarbons. The selectivity of xylene for T-Ni and T-NiMo catalysts decreased with temperature, but that for T catalyst(commercial grade) monotonically increased with temperature within the experimental range. The performance of T-Ni and T-NiMo catalysts was better than that of T catalyst in terms of initial activity and its decay. The addition of Mo improved slightly stability of T-Ni catalyst.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.1-7
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• 2013

In this study, simulation work of HCNG refueling system was performed. The hydrogen was produced from steam reforming process by natural gas. The conversion of natural gas is increased as SCR is increased. but it was no significant difference more than 3 of SCR and fuel throughput is increased as GHSV is increased. Both conversion and fuel throughput levels was optimized when the $1700h^{-1}$ of GHSV. CNG was compressed from low pressure natural gas. For the mixing of $H_2$ and CNG is mixed with the high pressure conditions such as 400bar of $H_2$ and 250bar of natural gas. Single-stage compression was required more power than multi stage. So, multi stage compression was suggested for high pressure compression. We calculated the intermediate pressure to minimize total required power of compressors. The intermediate pressure for $H_2$ and natural gas were derived at 61 and 65 bar, respectively.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.7
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• pp.1363-1372
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• 1992

The effects on lubricity and the anti-seizure property of lubricant according to base oils and extreme pressure additives of sulfur type and phosphorous type in cold rolling were evaluated by a laboratory scale rolling mill, where the contact conditions between work roll and strip are very close to actual cold rolling mill. The important results were obtained as follows : (1) synthetic oil has better effect on lubricity than tallow, (2) lubricant with extreme pressure additives of sulfur type of phosphorous type has better effect than base oil noly, (3) the more amount of extreme pressure additives is, the better effect on lubricity is, (4) sulfur type has better effect on lubricity than phosphorous type and (6) phosphorous type has better effect on anti-seizure property than sulfur type.