• Title/Summary/Keyword: 고분자 개발

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Study of Macrophage Stimulating Activity of the Polysaccharide Isolated from Leaves of Carthamus tinctorius L. (홍화(Carthamus tinctorius L.)잎으로부터 분리한 다당류의 Macrophage 활성화에 대한 연구)

  • Kwak, Ji-Eun;Kim, Kyung-Im;Jeon, Hyuck;Hong, Bum-Shick;Cho, Hong-Yon;Yang, Han-Chul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.3
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    • pp.527-533
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    • 2002
  • In the screening of Korean traditional tea sources for the cellular lysosomal enzyme activity of peritoneal macrophage from mice, CT-0, a cold-water extract from Carthamus tinctorius L., showed the highest macro-phage-stimulating activity. CT-1-IIa-2-1, a purified macrophage-stimulation polysaccharide was obtained by a series of purification steps such as anion exchage chromatography with DEAE-Toyopearl 650M, gel permeation chromatography with Sepharose CL-6B, Sephacryl S-200, and HPLC with Superdex G-75. The molecular weight of homogeneous purified polysaccharide was estimated about 68 kDa. CT-1-IIa-2-1 consisted of xylose 27.44%, arabinose 16.14%, mannose 15.92% and glucose 14.47%. To measure acute toxicity, dose of 50, 100, 500, and 1000 mg/kg were intraperitoneally injected to ICR mice. The LD$\_$50/ was about 397 mg/kg.

Synthesized Oil Manufacturing Technology from Natural Gas, GTL (천연가스로부터 합성유 제조 기술, GTL(Gas To Liquids))

  • Bae, Ji-Han;Lee, Won-Su;Lee, Heoung-Yeoun;Kim, Yong-Heon
    • The Korean Journal of Petroleum Geology
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    • v.14 no.1
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    • pp.45-52
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    • 2008
  • The GTL(Gas to Liquids) technology, manufacturing synthesized oil from natural gas, had been developed about 1920 for the military purpose by Fischer and Tropsch, German scientists. And 1960, Sasol company had started commercializing the FT(Fischer-Tropsch) synthesis technology, for the transport fuel in South Africa. Until a recent date, the commercialization of GTL technology had been delayed by low oil price. But concern about depletion of petroleum resources, and development in synthesizing technology lead to spotlight on the GTL businesses. Especially, Qatar, which has rich natural gas fields, aims at utilizing natural gas like conventional oil resources. Therefore, around this nation, GTL plants construction has been promoted. There are mainly 3 processes to make GTL products(Diesel, Naphtha, lube oil, etc) from natural gas. The first is synthesis gas generation unit reforming hydrogen and carbomonoxide from natural gas. The second is FT synthesis unit converting synthesized gas to polymeric chain-hydrocarbon. The third is product upgrading unit making oil products from the FT synthesized oil. There are quite a little sulfur, nitrogen, and aromatic compounds in GTL products. GTL product has environmental premium in discharging less harmful particles than refinery oil products from crude to the human body. In short, the GTL is a clean technology, easier transportation mean, and has higher stability comparing to LNG works.

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Study on the Method of Analyzing the Plasticizer of Petrochemical Products using MD-GC/MS (MD-GC/MS를 활용한 석유화학제품의 가소제(DOA, DOP) 분석방법 연구)

  • Doe, Jin-woo;Youn, Ju-min;Kang, Hyung-kyu;Hwang, In-ha;Ha, Jong-han;Na, Byung-ki
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1085-1093
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    • 2017
  • Plasticizers are materials added to give softness and elasticity to plastics having rigid properties to give soft properties as products, and they are mainly added to high molecular materials to give flexibility to improve workability and to improve cold resistance, resistance to volatility and electrical properties. It is used for the purpose. Most plasticizers are inert liquids, similar in function to solvents but with high molecular weight and no volatility. In addition, when dissolved in petrochemical products, only the plasticizer is separated by the matrix effect with other compounds, and qualitative and quantitative analysis. In this study, qualitative and quantitative analysis of DOA and DOP, which are representative components of petrochemical products, were conducted using MD-GC/MS and developed an optimal plasticizer analysis method.

Recent Progress in Conductive Polymer-based Membranes (전도성 고분자 분리막의 최근 연구동향)

  • Park, Shinyoung;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.2
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    • pp.101-119
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    • 2021
  • The demand for clean water is virtually present in all modern human societies even as our society has developed increasingly more advanced and sophisticated technologies to improve human life. However, as global climate change begins to show more dramatic effects in many regions in the world, the demand for a cheap, effective way to treat wastewater or to remove harmful bacteria, microbes, viruses, and other solvents detrimental to human health has continued to remain present and remains as important as ever. Well-established synthetic membranes composed of polyaniline (PANI), polyvinylidene fluoride (PVDF), and others have been extensively studied to gather information regarding the characteristics and performance of the membrane, but recent studies have shown that making these synthetic membranes conductive to electrical current by doping the membrane with another material or incorporating conductive materials onto the surface of the membrane, such as allotropes of carbon, have shown to increase the performance of these membranes by allowing the adjustability of pore size, improving antifouling and making the antibacterial property better. In this review, modern electrically conductive membranes are compared to conventional membranes and their performance improvements under electric fields are discussed, as well as their potential in water filtration and wastewater treatment applications.

Study on Flexural Properties of Polyamide 12 according to Temperature produced by Selective Laser Sintering (선택적 레이저 소결 제작 폴리아미드 12 시편의 온도별 굴곡 특성 연구)

  • Kim, Moosun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.11
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    • pp.319-325
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    • 2018
  • The use of 3D printing (Additive Manufacturing) technology has expanded from initial model production to the mass production of parts in the industrial field based on the continuous research and development of materials and process technology. As a representative polymer material for 3D printing, the polyamide-based material, which is one of the high-strength engineering plastics, is used mainly for manufacturing parts for automobiles because of its light weight and durability. In this study, the specimens were fabricated using Selective Laser Sintering, which has excellent mechanical properties, and the flexural characteristics were analyzed according to the temperature of the two types of polyamide 12 and glass bead reinforced PA12 materials. The test specimens were prepared in the directions of $0^{\circ}$, $45^{\circ}$, and $90^{\circ}$ based on the work platform, and then subjected to a flexural test in three test temperature environments of $-25^{\circ}C$, $25^{\circ}C$, and $60^{\circ}C$. As a result, PA12 had the maximum flexural strength in the direction of $90^{\circ}$ at $-25^{\circ}C$ and $0^{\circ}$ at $25^{\circ}C$ and $60^{\circ}C$. The glass bead-reinforced PA12 exhibited maximum flexural strength values at all test temperatures in the $0^{\circ}$ fabrication direction. The tendency of the flexural strength changes of the two materials was different due to the influence of the plane direction of the lamination layer depending on the type of stress generated in the bending test.

Development of antimicrobial edible films and coatings: a review (항균 가식성 필름/코팅 개발 현황)

  • Kim, Su Yeon;Min, Sea C.
    • Food Science and Industry
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    • v.50 no.2
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    • pp.37-51
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    • 2017
  • Food packaging strategies have steadily improved with increasing demand for improved food safety, convenience, and shelf life. The development of edible film has been hailed as a technology substituting packaging using synthetic plastics. There has been a surge for research to develop antimicrobial edible films and coatings that can increase microbiological safety while preserving foods. This review addresses recent results that are useful in advancing and extending research into antimicrobial edible films. In this review, we suggest the trend of the development of antimicrobial edible film/coatings by outlining edible film materials, antimicrobial substances, antimicrobial and physical properties of the films, commercial antimicrobial edible films, and methods to statistically predict the efficacy of antimicrobial edible film/coatings, reported in recent studies.

The Degradation Study of Polyethylene Based Mulching Films with Compatibilizer and Biomass (바이오매스 부산물에 상용화제를 첨가하여 제조한 멀칭필름의 분해 실태 연구)

  • Choi, Jae-Suk;Ahn, Kihyeon;Lee, Roun;Park, UoonSeon;Han, Jung-Gu;Chung, Sung Taek;Park, Hyung Woo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.105-113
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    • 2022
  • Mulching film was produced by LDPE and LLDPE adding biomass byproducts and MA(maleic anhydride), talc/clay/CaO/CaCO3. And also surveyed to tensile strength, elongation, TGA and DSC according to the UV irradiation time. The tensile strength and elongation showed 20 N/cm2 and 5% after UV irradiation 100 hours, and those was nearly 0 N/cm2 and 0% after 200 hours, respectively. TGA of film was showed to peak of polymer itself, and DSC was slightly higher than that of initial value. At the pilot scale test, we were able to see the differentiate of degradation between control and developed film after 12 weeks, and also torn off at several part of mulching film. The degradation of mulching film after growing corn showed similar to a pilot scale test. Above the results, the developed mulching film adding biomass will be to used for agricultural farming.

Sensitive and Selective Electrochemical Glucose Biosensor Based on a Carbon Nanotube Electronic Film (탄소나노튜브 전자 필름을 이용한 고감도-고선택성 전기화학 글루코스 센서)

  • Lee, Seung-Woo;Lee, Dongwook;Seo, Byeong-Gwuan
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.188-194
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    • 2022
  • This work presents a non-destructive and straightforward approach to assemble a large-scale conductive electronic film made of a pre-treated single-walled carbon nanotube (SWCNT) solution. For effective electron transfer between the immobilized enzyme and SWCNT electronic film, we optimized the pre-treatment step of SWCNT with p-terphenyl-4,4"-dithiol and dithiothreitol. Glucose oxidase (GOx, a model enzyme in this study) was immobilized on the SWCNT electronic film following the positively charged polyelectrolyte layer deposition. The glucose detection was realized through effective electron transfer between the immobilized GOx and SWCNT electronic film at the negative potential value (-0.45 V vs. Ag/AgCl). The SWCNT electronic film-based glucose biosensor exhibited a sensitivity of 98 ㎂/mM·cm2. In addition, the SWCNT electronic film biosensor showed the excellent selectivity (less than 4 % change) against a variety of redox-active interfering substances, such as ascorbic acid, uric acid, dopamine, and acetaminophen, by avoiding co-oxidation of the interfering substances at the negative potential value.

Role of Graphene Derivatives in Anion Exchange Membrane for Fuel Cell: Recent Trends (연료전지용 음이온교환막에서 그래핀 유도체의 역할: 최근 동향)

  • Manoj, Karakoti;Sang Yong, Nam
    • Membrane Journal
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    • v.32 no.6
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    • pp.411-426
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    • 2022
  • Energy plays a significant role in modern lifestyle because of our extensive reliance over energy-operating devices. Therefore, there is a need for alternative and green energy resources that can fulfill the energy demand. For this, fuel cell (FCs) especially anion exchange membrane fuel cells (AEMFCs) have gained tremendous attention over the other (FCs) due to their fast reaction kinetics without using noble catalyst and allow to use of cheaper polymers with high performance. But lack of highly conductive, chemically, and mechanically stable anion exchange membrane (AEM) still main obstacle to the development of high performance AEMFCs. Therefore, graphene-based polymer composite membranes came into the existence as AEMs for the FCs. The exceptional properties of the graphene help to improve the performance of AEMs. Still, there are lot of challenges in the graphene derivatives based AEMs because of their high tendency of agglomeration in polymer matrix which reduced their potential. To overcome this issue surface modification of graphene derivatives is necessary to restrict their agglomeration and conserved their potential features that can help to improve the performance of AEM. Therefore, this review focus on the surface modification of graphene derivatives and their role in the fabrication of AEMs for the FCs.

Research Trends of Ni-based Catalysts on Steam Reforming of Bio-oils for H2 Production: A Review (수소 생산을 위한 바이오오일 수증기 개질 반응에서의 니켈계 촉매 연구동향)

  • Da Hae Lee;Hyeon Myeong Seo;Yun Ha Song;Jaekyoung Lee
    • Clean Technology
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    • v.29 no.3
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    • pp.163-171
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    • 2023
  • Hydrogen has been gaining a lot of attention as a possible clean energy source that can aid in reaching carbon neutrality. Currently, hydrogen production has relied on the steam reforming of fossil fuels. However, due to the carbon dioxide emissions caused by this process, hydrogen production based on the steam reforming of bio-oil derived from biomass has been proposed as an alternative approach. In order to use this alternative approach efficiently, one of the key issues that must be overcome is that the complexity of bio-oil, which has a large molecular weight and diverse functional groups of hydrocarbons, promotes the catalytic deactivation of nickel-based catalysts. In this review, research efforts to improve nickel-based catalysts for the steam reforming of bio-oil have been discussed in terms of the active phase, support, and promoters. The active phases are involved in activating C-C and C-H bonds of high-molecular-weight hydrocarbons, and noble and transition metals can be utilized. In terms of the support and promoters, the catalytic deactivation of Ni-based catalysts can be inhibited by utilizing reactive lattice oxygen for support or by suppressing the acidity. The development of active and stable Ni-based reforming catalysts plays a critical role in clean hydrogen production based on bio-oils.