• Polymer(Korea)
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• v.27 no.4
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• pp.330-339
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• 2003

Three kinds of macro-reticular bead-typed chelating resins having thiol groups were obtained from basic resins like poly(strene-co-divinylbenzene) (PSD) and poly(styrene-co-methyl methacrylate-co-divinylbenzene) (PSMD): the chelating resin (I) was prepared by chloromethylation of phenyl rings of PSD followed by thiolation using thiourea. The chelating resin (ll) was designed to provide enough space to chelate heavy metal ions; one chloromethyl group was obtained by chlorination of hydroxymethyl group provided by reduction of carboxylic ester group of PSMD and another chloromethyl group was obtained by direct chloromethylation of pendent phenyl group using chloromethyl methyl ether. Both of chloromethyl groups were thiolated by using thiourea. The chelating resin (III) was prepared by chlorosulfonation of phenyl rings of PSD followed by thiolation using sodium hydrosulfide. The adsorbtivity toward heavy metal ions was evaluated. The hydrophobic chelating resin (I) with thiol groups showed highly selective adsorption capacity f3r mercury ions. However, the chelating resin (II) with thiol groups showed mere effective adsorption capacity toward mercury ions than chelating resin (I) with thiol groups, and showed some adsorption capacity for other heavy metal ions like Cu$\^$2＋/, Pb$\^$2＋/, Cd$\^$2＋/ and Cr$\^$3＋/. On the other hand, the chelating resin (III) which have hydrophilic thiosulfonic acid groups was found to be effective adsorbents for some heavy metal ions such as Hg$\^$2＋/, Cu$\^$2＋/, Ni$\^$2＋/, Co$\^$2＋/, Cr$\^$3＋/ and especially Cd$\^$2＋/ and Pb$\^$2＋/.

• Journal of the Korean Chemical Society
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• v.33 no.6
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• pp.588-595
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• 1989

Log K, ${\Delta}$H and ${\Delta}$S for the complexation of $La^{3+},\;Ce^{3+}$ and $Eu^{3+}$with various multidentate ligand containing crown ether, diaza crown ether and diamine ether have been determined in methanol and acetonitril solutions at $25^{\circ}C$ by solution calorimetric titration method. The greater stability constant of $La^{3+}$-15C5 than those of 18C6 diaza [2.2] in methanol are discussed in terms of the size of metal ion and the ligand cavity and of metal ion solvation. The stabilities of $Ce^{3+}$ and $La^{3+}$ ion complexes with a various multidentate ligand in acetonitril are in the order of (diamine ether)<18C6<15C5$Ce^{3+}$, $La^{3+}$ and $Eu^{3+}$-diaza [2.2] complexes in acetonitril are increased with the following order: $Eu^{3+}$ < $La^{3+}$ < $Ce^{3+}$, that is increasing order of the optimum size and of the charge density of metal ion.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.252-257
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• 2023

In this study, to replace phthalate-based plasticizers known as endocrine disruptors, compounds as plasticizer candidates were synthesized by using alcohols containing rings and fatty acids extracted from animal and vegetable oils, and their properties as plasticizers, including their plasticization efficiency, were evaluated. Nine compounds synthesized by esterification of fatty acids (caprylic acid, capric acid, lauric acid) and alcohols (solketal, benzyl alcohol, cyclohexanol) were identified by ¹H-NMR. The nine synthetic compounds were evaluated for their plasticity by adding them to PVC resin, and compared with the commercial plasticizers DEHP, DINCH, and ESO. According to the results, plasticization efficiency was 0.96 to 1.02 times higher than DEHP, 0.94 to 0.98 times higher than ESO, and 1.05 to 1.10 times higher than DINCH. Thermal stability was somewhat lower than that of DEHP and DINCH, but showed better results than ESO. The results of the solvent extraction test showed that both aqueous and oily solvents showed higher values than DEHP and DINCH but showed similar or superior properties to ESO.

• Journal of the Korean Chemical Society
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• v.20 no.1
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• pp.15-18
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• 1976

The preferred conformation of benzenesulfenyl chloride was determined by EHMO calculation. It was found that the stability was dictated by the n-${\pi}$ conjugation of S atom with the benzene ring. The ethanolysis reaction of benzenesulfenyl chlorides has been studied. The rate constants obtained have been discussed in terms of substituent effects and d-orbital participation of sulfur atom. From a non-linear Hammett plot, bipyramid type of intermediate has been suggested.

• Journal of the Korean Chemical Society
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• v.37 no.5
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• pp.523-526
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• 1993

Absorption spectra of photochromic spironaphthoxazine dye in various solvents were examined and exhibited a positive solvatochromism. The positive solvatochromism of this dye strongly suggests that the structure of open chain forms is keto type structure, 4a. The effect of structural change on the electronic spectra, on replacement of the C=C bond by C=N bond, is discussed.

• Journal of the Korean Chemical Society
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• v.24 no.1
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• pp.64-72
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• 1980

The synthesis of N-acrylylpyrrolidone has been carried out by the reaction of pyrrolidone and acrylyl chloride. The study on the copolymer of N-acrylylpyrrolidone and styrene is attempted.The copolymerization of N-acrylylpyrrolidone and styrene is carried out in benzene.Monomer reactivity ratio of N-acrylylpyrrolidone and styrene was calculated by Fineman and Ross equation. It is observed that the copolymer of N-acrylylpyrrolidone and styrene has random distributed acyl-lactam function on the vinyl polymer backbone.

• Journal of The Institute of Information and Telecommunication Facilities Engineering
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• v.2 no.4
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• pp.28-41
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• 2003

A micros-strip ring patch antenna with ultra wide band characteristics is presented. The proposed antenna is designed by a modified form of the annular ring patch antenna with modified microstrip feedline. The designed antenna gives 5.6GHz bandwidth with regular radiation pattern from 4.4GHz to 12.0GHz for -10dE return loss or VSWR of less than 2.0 in simulation, which is also excellently agreed with the measured data.

• 한국IT서비스학회:학술대회논문집
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• 2007.11a
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• pp.485-492
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• 2007

정보화 사업에서 발생할 수 있는 위험(Risk)은 다양하다. 정보화 사업 관련 위험 요인 중 가장 대표적이고 보편적인 것은 발주 및 제안단계에서 발주자가 가진 요구사항의 불명확을 꼽을 수 있는데, 이로 인해 정보화 사업 수행 도중 요구범위 증가와 변경, 그리고 사업원가 구조의 악성화가 발생하게 됨은 자명하다. 그러나 안타까운 현실은 그 동안 우리나라 정보화 사업의 관행이 요구사항 불명확이라는 잠재적 위험 아래에서도 발주자와 사업자 간의 계약이 보호장치가 미흡한 확정가(firm fixed price) 방식으로 수립되어 왔다는 것이다. 확정가로 계약이 수립될 경우 사업자는 발주자의 요구사항 불명확으로 인해 파생된 원가 위험까지 불합리하게 책임져야 하는 고리에 묶이게 된다. 이러한 문제를 본질적으로 해결하는 한가지 방법은 발주자와 사업자간의 정보화 사업 획득 절차를 혁신하는 것인데, 본 논문은 이를 위해 가칭, 한국형 정보화 산업 활성화 획득 절차(KIPAP: Korea If Proliferation Acquisition Process)의 기본 개념을 고안하여 소개한다. 이 획득 절차는 정보화 사업이 내재하고 있는 요구사항의 불확실성을 계량화, 가시화하여, 그 정도에 따라 차등화된 계약방식의 선정방법 을 제시한다.

• Journal of KIISE:Software and Applications
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• v.27 no.9
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• pp.973-985
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• 2000

함수형 프로그래밍 언어는 전통적인 프로시저형 언어에 비하여 많은 장점이 있다. 그러나 함수 언어 프로그래머를 위한 실용적인 디버깅 환경은 상대적으로 빈약하다. 그동안 유용한 디버거 구현을 위해서 많은 시도가 있었고, 그 결과로 하향식 기법으로 이용한 알고리즈믹 디버거와 상향식 기법을 이용한 레덱스 트레일 디버거가 연구되었다. 두가지 기법은 모두 실제 프로그래밍에 적용하기에는 유지해야 하는 디버깅 정보의 양이 많다는 단점이 있다. 이 논문에서는 선택적 레덱스 트레일 디버깅 방법을 제안한다. 이 방법을 이용하면 디버거 사용자는 프로그램에서 오류가 예상되는 부분에 포커스를 설정할 수 있고 단지 선택된 부분에 한하여 트레일을 생성하게 된다. 이 방법은 프로그램의 오류에 대한 디버거 사용자의 예측을 반영하고 디버깅에 필요한 정보의 양을 줄이는 장점이 있다. 구현된 디버깅 시스템은 선택적 레덱스 트레일을 생성하는 추상기계와 실제 디버깅이 이루어지는 레덱스 트레일 탐색기로 구성된다.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.244-250
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• 1996

고리 2호기에서 2주기 동안 연소된 1개 KOFA 연료봉에 대한 조사후 검사결과, 핵분열기체 방출량 및 소결체 밀도가 연료봉 설계코드의 예측범위내에 있음을 확인하였으며, 소결체의 미세구조 및 연료봉내의 축방향 분포 검사를 통해 $UO_2$ 소결체가 아무 이상이 없이 안정적으로 연소되었음을 확인하였다. 단지 1개 연료봉에 대한 조사후 검사만으로는 KOFA 핵연료 $UO_2$ 소결체의 노내 거동을 검증하였다고는 할수 없기 때문에 연소된 핵연료에 대한 지속적인 조사후 검사가 필요한 것으로 사료된다. 특히 한국형원자로의 핵연료인 영광 3호기 핵연료에 대해 조사후 검사를 수행하고, 또한 일부 시험연료봉을 고연소도까지 연소시킨후 조사후 검사를 수행하면, 핵연료의 성능 검증뿐만 아니라 국내 고유의 핵연료 성능자료를 생산하게됨으로써, 앞으로 국내 고유의 고연소도핵연료개발 및 연료봉성능분석코드 개발에 활용할 수 있다.