• Title/Summary/Keyword: 고도정수처리

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A Literature Study on the Ozone Degradation of Concrete Structures in Water Treatment Facilities (수처리 시설 콘크리트 구조물의 오존 열화에 관한 문헌적 연구)

  • Park, Jin-Ho;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.177-178
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    • 2015
  • Recently, Advanced water treatment facilities with Ozone are being introduced owing to domestic water pollution. However, waterproofing/corrosion prevention construction method of concrete structure for existing advanced water treatment makes waterproofing/corrosion prevention materials and concrete deteriorated because of strong oxidation of ozone. it causes increase of maintenance cost and water quality degradation. Therefore, in this study, it will figure out problems of waterproofing/corrosion prevention construction method being applied to through existing studies.

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Removal characteristics of NOM in advanced water treatment using ceramic MF membrane (세라믹막(MF) 고도정수처리에서 NOM 제거 특성)

  • You, Sang-Jun;Park, Sung-Han;Lim, Jae-Lim;Suh, Jeong-Min;Jang, Seong-Ho;Hong, Sung-Chul;Yi, Pyong-In
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.367-376
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    • 2014
  • This study assessed the removal efficiency of NOM which is known as the precursors of DBPs in advanced water treatment using the ceramic membrane filtration, introduced the first in the nation at the Y water treatment plant (WTP). It is generally well-known that the removal of NOM by MF Membrane is very low in water treatment process. But, the result of investigation on removal efficiency of NOM in advanced water treatment using the ceramic membrane was different as follows. The removal rate of organic contaminant by the ceramic membrane advanced water treatment was determined to be 65.5% for the DOC, 85.8% for UV254, and 77 to 86% for DBPFP. The removal rate of pre-ozonation was found to be 6 to 15% more effective compared with the pre-chlorination. The removal rate of DOC and $UV_{254}$ in biological activated carbon(BAC) process was over 50% and 75%, respectively although the rate was decreased 10 ~ 20% according to analysis items in converting from GAC to BAC.

Molecular Size Distributions of NOM in Conventional and Advanced Water Treatment Processes (기존수처리 공정 및 고도정수처리 공정에서 NOM의 분자크기 분포 변화)

  • Choi, Il-Hwan;Jung, Yu-Jin
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.682-689
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    • 2008
  • The purpose of this study was to find out the variation between molecular size distribution (MSD) of natural organic matter (NOM) in raw waters after different water treatment processes like conventional process (coagulation, flocculation, filtration) followed by advanced oxidation process (ozonation, GAC adsorption). The MSD of NOM of Suji pilot plant were determined by Liquid Chromatography-Organic Carbon Detection (LC-OCD) which is a kine of high-performance size-exclusion chromatography (HPSEC) with nondispersive infrared (NDIR) detector and $UV_{254}$ detector. Five distinct fractions were generally separated from water samples with the Toyopearl HW-50S column, using 28 mmol phosphate buffer at pH 6.58 as an eluent. Large and intermediate humic fractions were the most dominant fractions in surface water. High molecular weight (HMW) matter was clearly easier to remove in coagulation and clarification than low molecular weight (LMW) matter. Water treatment processes removed the two largest fractions almost completely shifting the MSD towards smaller molecular size in DW. No more distinct variation of MSD was observed by ozone process after sand filtration but the SUVA value were obviously reduced during increase of the ozone doses. UVD results and HS-Diagram demonstrate that ozone induce not the variation of molecular size of humic substance but change the bond structure from aromatic rings or double bonds to single bond. Granular activated carbon (GAC) filtration removed 8~9% of organic compounds and showed better adsorption property for small MSD than large one.

Effect of pH and Oxygen Back-flushing on Hybrid Water Treatment of Tubular Ceramic MF and Photocatalyst Loaded Polyethersulfone Beads (관형 세라믹 정밀여과와 광촉매 첨가 PES 구를 이용한 혼성 수처리 공정에서 pH 및 산소 역세척의 영향)

  • Park, Jin Yong;Park, Sung Woo;Byun, Hongsik
    • Membrane Journal
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    • v.24 no.1
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    • pp.39-49
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    • 2014
  • The effects of pH and oxygen back-flushing were investigated in hybrid process of ceramic microfiltration and PES (polyethersulfone) beads loaded with titanium dioxide ($TiO_2$) photocatalyst for advanced drinking water treatment in viewpoints of membrane fouling resistance ($R_f$), permeate flux (J), and total permeate volume ($V_T$). As increasing pH, $R_f$ decreased and J increased. Finally the maximum $V_T$ could be acquired at pH 9. Treatment efficiencies of turbidity was almost same independent of pH. Treatment efficiency of dissolved organic matters (DOM) decreased as increasing pH. As results of comparing the oxygen and nitrogen back-flushing, $R_{f,180}$ at oxygen back-flushing was the lower than that at nitrogen back-flushing, and the dimensionless final permeate flux ($J_{180}/J_0$) by initial permeate flux ($J_0$) at oxygen back-flushing was maintained the higher than that at nitrogen back-flushing except 10 and 12 min of back-flushing period (FT). Treatment efficiency of turbidity at oxygen back-flushing was a little higher than that at nitrogen back-flushing. Treatment efficiency of the DOM at nitrogen back-flushing was the higher than that at oxygen back-flushing. Also, treatment efficiency of turbidity at saturated oxygen was similar with those of oxygen and nitrogen back-flushing, but the treatment efficiency of DOM was increased significantly because OH radical could be generated by reaction between saturated oxygen and photocatalyst.

Development of Feature-based Classification Software for High Resolution Satellite Imagery (고해상도 위성영상의 분류를 위한 형상 기반 분류 소프트웨어 개발)

  • Jeong, Soo;Lee, Chang-No
    • Journal of Korean Society for Geospatial Information Science
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    • v.12 no.2 s.29
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    • pp.53-59
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    • 2004
  • In this paper, we investigated a method for feature-based classification to develop a software which is suitable for the classification of high resolution satellite imagery. We developed algorithms for image segmentation and fuzzy-based classification required for feature-based classification and designed user interfaces to support interaction with user, considering various elements required for the feature-based classification. Evaluation of the software was accomplished using real image. Classification results were compared and analysed with eCognition software which is unique commercial software for feature-based classification. The classification results from both softwares showed essentially same results and the developed software showed better result in the processing speed.

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Analysis of the cost effectiveness according to T-P standard enforcement of public sewage treatment facilities (공공하수처리시설의 총인기준 강화에 따른 비용효과분석)

  • Jeong, Won-Gu;Rim, Jay-Myung
    • Journal of Industrial Technology
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    • v.31 no.A
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    • pp.135-145
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    • 2011
  • This study was conducted to analyze the cost effectiveness in line with total phosphorus standard enforcement of public sewage treatment facilities. The additional cost for the total phosphorus removal process was calculated to analyze the cost effectiveness of the advanced water purification process. The analysis results showed that the T-P removal by coagulation sedimentation was more efficient than the advanced water purification facilities in terms of facilities investment cost, and if the coagulation filteration was used for T-P removal, the activated carbon process among the advanced water purification techniques was more efficient in terms of facilities investment cost. In this study, the effects of the T-P removal process that will be additionally introduced according to the tightening of the effluent T-P standard were analyzed within a limit. The actual benefits of improved T-P concentration in the water source will provide diverse values, including the leisure water, environment improvement water, eco-system in the water source and industrial water, in addition to the advanced water purification.

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Development of Real-time Groundwater Quality Monitoring and Advanced Groundwater Purification Technology for Groundwater using Photoinduced Reactive Oxygen Species (지하수 수질 실시간 모니터링 및 광유도 활성산소를 이용한 고도수처리 기술)

  • Kang-Kyun Wang;Byung-Woo Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.15-15
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    • 2023
  • 2020년 기준 국내 상수도 보급률은 99.1% 차지하고 있으며(환경부, 2019), 수도관리차원에서 수돗물은 먹는 물로 시판되어질 만큼 우수한 관리체계를 유지하고 있다. 그 반면에 지하수는 생활용수, 식품가공, 농·축산, 양어, 군부대를 비롯한 전국지역에서 연간 10억 8천만톤 용수를 소비하고 있음에도 (환겨례 신문, 2013; 환경부, 2019) 사용되는 지하수의 약 65%가 음용수 불가판정을 받았으며, 최근 지하수의 오염비율은 급격히 증가하는 추세이다. 특히, 지하수관정의 관리부주의에 의한 수질오염 및 수인성 다제내성균(슈퍼박테리아) 등에 의한 오염사례가 국내는 물론, 국제적으로 다수 보고되고 있는 실정이다 (환경부, 2013). 현재 지하수 수질관리는 공공기관 및 지자체 지정기관을 통해 진행되고 있으며, 검사기간은 수질채취로부터 통상 7~15일정도 소요되어 수질 관리 및 기준, 검사주기에 대한 애로가 많다. 현장 지하수관정에서 실시간 수질을 모니터링하고 이에 연동된 자동 수처리 시스템의 개발 및 도입은 나날이 심각해지는 환경오염 상황에서 선제적 예방과 해결방법으로 중요한 요소기술이다. 현재 지하수오염 및 부적합 음용의 수질처리는 화학약품, 필터여과, UV살균, O3 (플라즈마)을 이용하는 것이 대표적이나, 화학약품의 경우 2차 오염이나 식품 세척 및 가공에 있어 부적합성의 한계점이 있다. 필터여과의 대표적인 RO필터의 경우 약 50% 순손실이 발생하고, UV 살균의 경우 UV에 의한 사용관리자의 위험 및 장비의 광부식 문제, O3 의 경우 고압전류 사용에 따른 위험성 등의 한계점이 나타나고 있다. 지하수 수질정화를 위한 광유도 활성산소(1O2, ·O-2)는 광감응제에 가시광의 빛 조사를 통해 생성되는 활성산소로의 에너지 및 전자 전이가 동시 진행되어 단일항 산소(1O2)와 슈퍼옥사이드 이온(·O-2)을 생성하게 된다. 생성된 활성산소는 유해미생물 또는 유기화학물과 개열, 제거, 치환 반응 등을 통해 미생물사멸 및 유해화학물질들이 분해 가능하다. 이를 이용한 지하수 유해미생물 사멸기술, 장비, 실시간 지하수의 분석기술 및 정수처리, 지하수 물순환 시스템 개발뿐만 아니라 지하수 음용수 및 오염개선, 지하수 기저유출에 의한 오염원 저감으로부터 지류·지천, 하천 본류 수질개선 등의 대상지역에 활용 가능하다. 또한 광유도 활성산소는 기존 상수도 수처리에 있어 오존(O3) 처리와 이산화티탄을 이용한 AOP과정을 단일처리 공정으로, 기존 O3 의 특성상 확산 거리가 매우 길어 사람을 포함한 생체 내에 유입 시 다양한 부작용 발생과 O3 차폐시설 요구의 문제점 극복의 대안으로 환경 및 인체에 무해한 광유도 활성산소 시스템을 적극적으로 도입 및 적용해야 한다. 본 연구 목적은 정류상태 흡광분광기술을 이용한 실시간 수질 모니터링과 광유도 활성산소를 이용한 유해 미생물의 멸균효능 및 지하수 수질관리 기술로의 적용 가능성을 제시하고자 한다.

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Operation of Advanced Water Treatment Processes for Downstream River Source Water (상수원수의 고도정수처리 공정 파일롯 운전 연구)

  • Wang, Chang-Keun;Oh, Sang-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.1
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    • pp.1-6
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    • 2012
  • Down Stream K River has high COD (4-10 mg/L) and high $NH_3$-N concentration (3.5 mg/L during winter period). Although $NH_3$-N itself is not reported harmful at this level, it must be removed to meet drinking water standard (0.5 mg/L). We constructed a pilot plant modifying the processes of conventional drinking water facilities. Prechlorination and powdered activated carbon (PAC) dechlorination was adopted prior to a flocculation tank to remove ammonia and prevent disinfection byproducts (DBPs) formation. Also, GAC processes was included after sand filter to remove residual DOC. This pilot having a capacity of 36 ton/day was operated for one year. The GAC processes were successful to remove ammonia and many organic pollutants (DOC, MBAS, UV-254 nm absorbance, etc). Influent DOC concentrations were very high as 3~6 mg/L throughout the plant operation. It was impossible to achieve 1.0 mg/L effluent DOC, indicating that bed depth (2 m) should be increased to achieve more strict DOC quality standards. When $Cl_2$ dose was well controlled ($Cl_2/NH_3$-N ratio 10~11 on a weight basis), $NH_3$-N removal was 98% and THMs was very low possibly due to low free residual chlorine and PAC dechlorination.

Oxidation of Organics Using a Direct Reaction of Peroxyl Radical and Ozone (페록시라디칼과 오존의 직접 반응을 이용한 유기물의 산화)

  • Choi, Seungpil;Kim, Jongoh
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.8
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    • pp.41-47
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    • 2010
  • This study was conducted to assess the applicability of pilot scale system and to evaluate the treatment efficiency on operational parameters such as humic acid concentration, initial pH and air flow rate on the ozone/peroxyl radical reaction system. The decolorization of ozone/peroxyl radical system was higher than that of only process. Removal efficiency of ozone/peroxyl radical system was generally increased with the increase of intial concentration of humic acid but decreased over the range of 30mg/L. Treatment efficiency of HA at acid pH was smaller compared to that of neutral or basic pH and increased with increasing the air flow rate from 1L/min to 3L/min. In pilot-scale test, average removal of TOC and $COD_{Cr}$ was about 70% and 60%, respectively and ozone/peroxyl radical reaction system was indicated a potential in water treatment application.

Hybrid Water Treatment of Tubular Ceramic MF and Photocatalyst Loaded Polyethersulfone Beads : Effect of Water Back-flushing Period and Time (관형 세라믹 정밀여과와 광촉매 첨가 PES 구의 혼성 수처리 : 물 역세척 주기와 시간의 영향)

  • Park, Jin Yong;Park, Sung Woo;Byun, Hongsik
    • Membrane Journal
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    • v.23 no.4
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    • pp.267-277
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    • 2013
  • The effect of water back-flushing period (FT) and water back-flushing time (BT) was compared with the previous study of nitrogen back-flushing in viewpoints of resistance of membrane fouling ($R_f$), permeate flux (J), and total permeate volume ($V_T$) in hybrid process of tubular ceramic microfiltration and PES (polyethersulfone) beads loaded $TiO_2$ photocatalyst for advanced drinking water treatment. As FT decreasing, Rf decreased, but J and $V_T$ increased. Turdity treatment efficiency was the maximum at NBF (no back-flushing) and increased a little as FT decreasing in both water and nitrogen back-flushing. Organic matter treatment efficiency was the maximum at FT 4 min in water back-flushing, but increased as FT decreasing in nitrogen back-flushing. As BT increasing, Rf and resistance of reversible membrane fouling ($R_{rf}$) decreased, but J and $V_T$ increased. The turdity treatment efficiency was almost constant beyond 98% in water back-flushing, but increased as BT increasing except NBF in nitrogen. The organic matter treatment efficiency was the maximum at BT 6 sec in water back-flushing, but increased as BT increasing except NBF in nitrogen. The $V_T$ was the maximum at BT 30 and FT 2 min, and optimal condition was BT 30 sec per FT 2 min in this experimental range.