• Clean Technology
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• v.18 no.2
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• pp.123-143
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• 2012

Supercritical fluid technology (SFT) is recently one of the most new techniques, which has been interested various fields of related chemical industries. SFT is the most effective and practical technology with eco-friendly, energy-savings, and high efficiency as the technique using the advantages of supercritical fluid such as high solvation power, solubility, mass transfer rate, and diffusion rate. Especially, it is necessary to analyze, evaluate, and develop the potential of application techniques using SFT with these characterizations. Therefore in this review, the phase behavior in supercritical fluid at high temperature and pressure of monomers/polymers for the optimization of polymerization process are briefly described, and the preparation of molecularly imprinted polymers (MIPs) in supercritical fluid using supercritical polymerization and the performance evaluation of MIPs are introduced.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.272-275
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• 2005

본 실험은 염소계유해유기화합물을 처리하는 목적으로 종래의 초임계수산화법의 결점을 완전히 해결하기 위해서 도달한 것이 질산나트륨을 산화제로서 사용하는 개량된 초임계수 산화법(다단계산화법)이다. 이와 같이 본 연구팀이 개발한 개량된산화법(다단계산화법)은 매우 간단하며 저렴한 염소계유기물 분해처리시스템을 구축하는 것이 가능하다.

• Korean Journal of Materials Research
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• v.7 no.7
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• pp.547-558
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• 1997

Pb(Mg$_{1}$3/Nb$_{2}$3)O$_{3}$[PMN]-PbTiO$_{3}$[PT]계 고용체의 상경계조성(MPB)영역에 대해 La을 첨가하여 변성시킨 La변성 (1-x)PMN-xPT(x=0.35) 고용체를 만들어 온도-유전율 특성, 전계유기 분극특성 및 변위특성을 조사하였다. PMN-PT의 상경영역의 조성인 x=0.35에 대해 La함량을 0-10at%까지 변화시켰다. PMN-PT계 고용체에서 PT 의 함량이 증가함에 따라 전계유기변위 및 히스테리시스 특성이 모두 증가하였다. 전계유기변위 값 $\varepsilon$ 는 능면정과 정방정의 공존영역인 MPB(x=0.35)조성에서 가장 높은 값($\varepsilon$ = 2 x $10^{-3}$)을 보여 주었다. MPB조성에 대해 La을 첨가한 계의 전계유기변위를 조사한 결과 La의 첨가량이 적을 때 (La=0-5at%)는 La의 함량이 증가함에 따라 히스테리시스 특성이 감소하였고 $\varepsilon$ 은 증가하여 고성능의 액튜에이터 재료에 적합한 조성물로 기대된다.

• KOREAN POULTRY JOURNAL
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• v.48 no.11
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• pp.129-132
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• 2016

이 코너는 그 동안 양계산업을 위해 허신해 온 양계인들을 만나 최근의 근황을 들어보고 과거의 추억(업적)을 되새겨 보는 자리를 만들고자 마련하였다. 이번호는 계유농원을 운영해 왔고 전 본회 부회장을 지낸 이재식(74세) 사장을 만나 인터뷰를 진행하였다.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.438-444
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• 1999

The natural full-fat rice bran is reported to contain 8.4 to 14.7 wt % Lipids, but the amount and composition of bran depend on the type of rice, quality of paddy, pretreatments to paddy such as parboiling, type of milling system employed, and the degree of polishing. These lipids are usually mixtures of several class fatty acids containing palmitic acid, linolenic acid, linoleic acid, oleic acid, stearic acid, tocopherol, squalene, etc. In this study the oil rich essential fatty acid (EFA) including squalene was extracted from the domestic brown rice bran using supercritical fluid extraction (SFE) and cosolvent induced SFE process, respectively. And the extracts were analyzed with GC-MSD. The extracted amount of rice bran oil was dependent upon the operating pressure and temperature, and the fatty acid composition of oil was varied with the reduced density (${\rho}_{\gamma}$) of supercritical carbon dioxide. About 70~80% of rice bran oil was extracted in 4hrs. The cosolvent induced SFE process shortened the total extraction time, extracted greater amount of oil than SFE process. Especially squalene which was not found in solvent extract phase was identified in SFE and cosolvent induced SFE process.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.3 no.3
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• pp.137-151
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• 1991

The motion of two-dimensional floating breakwaters with rectangular clots-section which are moored tautly in shallow water has been analyzed using a velocity potential matching method in which the fluid region is devided into sub-regions and then unknown coefficients of velocity potentials are determined from the continuity condition of mass and momentum flux of fluid at imaginary boundaries between sub-regions. The method originally suggested by Ijima et al.(1972) for the motion of submerged body has been modified to analyze the motion of floating body. The total fluid region has been divided into three sub-regions : the incident wave region, the transmitted wave region and the region below the floating breakwater. The restoring forces induced by mooring lines which were ignored by Ijima et al.(1972) have been modeled as linear springs with the initial tension effects. This method has been verified through the comparions with results from hydraulic expriments. Applications to various conditions of floating breakwater have been performed.

• Journal of the Korean Ceramic Society
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• v.37 no.9
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• pp.871-878
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• 2000

본 연구는 3mol% Pb(Sb$_{1}$2/Nb$_{1}$2/)O$_3$가 첨가된 상경계 영역의 Pb(Zr,Ti)O$_3$(PSN-PZT) 세라믹스에 대하여 RT66A와 광섬유센서를 이용하여, 교류강전계 하에서 압전 및 유전특성을 조사하였다. PSN-PZT 세라믹스의 압전 및 유전 특성에 미치는 non-180$^{\circ}$분역 재배열의 영향을 평가하기 위하여 RT66A와 MTI-2000 Fotonic$^{TM}$ sensor를 이용하여 인가전계와 주파수의 함수로 전계유기변위를 측정하였다. 그 결과, 교류강전계 하에서 전계유기변위는 강전계, 저주파수에서 큰 이력현상을 나타내고, 전계유기변위로부터 결정된 유효압전상수는 주파수가 감소할수록 증가하는 거동을 나타내고 있으며, 이러한 거동은 non-180$^{\circ}$분역 재배열의 영향으로 해석되었다.

• Clean Technology
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• v.15 no.1
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• pp.9-15
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• 2009

Catalytic hydrodechlorination of PCBs (polychlorinated biphenyls) included in the transformer oil was carried out to detoxify PCBs and to recycle the treated oil. Catalysts such as 0.98 wt% Pt and 0.79 wt% Pd on ${\gamma}$-alumina (${\gamma}-Al_2O_3$) support, 12.8 wt% Ni on ${\gamma}-Al_2O_3$, and 57.6 wt% Ni on silica-alumina ($SiO_2-Al_2O_3$) support were used for the catalytic hydrodechlorination. Various supercritical fluids such as carbon dioxide, propane and isobutane were used as reaction media. The effects of reaction temperature, reaction time, catalysts, and supercritical fluids on the catalytic hydrodechlorination were examined in detail. The detoxification degree increased in the order of Ni > Pd > Pt. This is possibly due to higher metal loading and larger metal size of the Ni catalyst. Below $175^{\circ}C,\;scCO_2$ was found as the most effective reaction media for the catalytic hydrodechlorination of PCBs included in the transformer oil.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.171-174
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• 2001

초임계유체(supercritical fluid, SCF)는 친환경적 용매로서 고분자 합성과 기능화를 비롯하여 RESS(rapid expansion of supercritical solution)와 초임계염색 등의 섬유공정 분야에서 연구자들의 흥미로운 관심을 받아 오고 있다. 초임계유체는 기체와 액체의 중간적인 특성을 가지면서도 가스와 같이 우수한 확산력을 가지며 또한 아주 낮은 점도를 갖는다. SCF 중에서 비교적 온화한 조건(31.1℃의 임계온도, 73.8기압의 임계압력, Figure 1)에서 초임계상태를 가질 수 있는 이산화탄소가 가장 많이 이용되고 있는데 이는 자원이 풍부하며 쉽게 회수하여 사용할 수 있어 응용 면에서 유리하다. (중략)

• KLA journal
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• v.8 no.1
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• pp.25-32
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• 1967