• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.625-633
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• 2000

The mechanical and curing properties of short nylon66 fiber reinforced Chloroprene rubber have been investigated as functions of interphase conditions and fiber content. The tensile strength exhibits a dilution effect at a low fiber content in each interphase. It is found that the interphase conditions have an important affect on the dilution ratio and critical fiber content. Double coatings of bonding agent 402 and rubber solution become the best interphase model in this study. The yield strength, tensile modulus, tear strength and fracture toughness at rupture, Jr are significantly improved due to fiber concentration.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.1151-1156
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• 2003

The dynamic properties of short-fiber reinforced Chloroprene rubber for vibration isolators have been studied as functions of interphase conditions and fiber content. The loss factor showed the maximum at strain amplitude 2%, and increased 0.09 for matrix, 0.05 for reinforced rubber with increasing frequency respectively. The dynamic ratio rapidly decreased with increasing strain amplitude, and some increased with increasing frequency. The better interphase condition showed the lower dynamic ratio. Therefore, the short-fiber reinforced rubber could have the better isolation in frequency ratio(${\sqrt{2}}min$.) compared to frequency ratio(${\sqrt{2}}max$.). And we have investigate the possibility of applying short-fiber reinforced rubber to automotive engine mount.

• The Korean Journal of Rheology
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• v.10 no.1
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• pp.14-23
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• 1998

비상용성 고분자 브렌드계인 PS/PP와 EPDM/PP의 유변학적 거동에 미치는 계면의 영향을 알아보았고 그실험 결과를 Park & Lee 모델과 비교하였다. PS/PP와 EPDM/PP 블 렌드계에서의 계면에 의한 전단응력과 법선 응력차에의 기여도는 $textsc{k}$와λ(1-$\mu$), 두 개의 변 수에 의해 잘설명되었다. 특히 계면의 탄성적인 효과와 관련있는 법선응력차 항이 전단 응 력 항보다 더 뚜렷하게 나타났다. 30PS/70PP 블렌드 조성에서는 블렌드의 유변학적 특성이 주로 연속상을 이루는 고분자의 의해 좌우된 반면에 50PS/50PP 블렌드조성에서는 계면에 의한 영향이 더두드러지게 나타났다. 이것은 50/50 블렌드 조성에서 계면의 넓이가 증가한 것과 관계 있다. 그러나 EPDM/PP 블렌드계에서 계면에 의한 응력 항들이 모두 PS/PP 블 렌드계의 그것보다 매우 큰 값을 가졌지만, 그 상대적인 비를 나타내는 $textsc{k}$값은 작았다. 이것 은 블렌드를 구성하고 있는 순수한 성분의 법선응력차 값의 차이가 크기 때문이다. 또한 PS/PP 블렌드계에 대한 동적 계면장력을 Park & Lee 모델을 이용하여 예측해 보았다.

• Proceedings of the Korean Magnestics Society Conference
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• 2009.12a
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• pp.125-126
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• 2009

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.11a
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• pp.62-63
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• 1998

• Composites Research
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• v.16 no.2
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• pp.18-25
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• 2003

The tensile properties of short nylon6 fiber reinforced NR and SBR have been investigated as functions of fiber aspect ratio(AR), diameter ratio(DR), interphase condition, and fiber content. The tensile strength increased with increasing fiber AR(20 min.) and good interphase conditions. The short-fiber(DR=3 and AR=20 min.) reinforced SBR did not show the dilution effect for all interrhase conditions. And the short-fiber(DR=3 and AR=20min.) reinforced NR did not show the dilution effect except for the no-coating. The tensile moduli were significantly improved due to fiber AR. fiber content, and good interphase at same DR. The better interphase condition showed the higher pull-out force at same DR. Also, the stress analysis near the fiber end carried out using axisymmetric FEA to be convinced of the reinforcing mechanism. It is found that the fiber AR, interphase and DR have an important effect on tensile properties.

• Applied Chemistry for Engineering
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• v.8 no.3
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• pp.473-481
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• 1997

Enhanced videomicroscopy was used to observe the dynamic behavior which occurred when water containing pure nonionic surfactant was carefully contacted with equal volumes of polar oils such as oleyl alcohol and oleic acid at various temperatures. A key component of the system is a vertical-stage microscope which provides for stable interfaces by locating the oil above the denser aqueous phase. This arrangement allowed intermediate phases formed at the surface of contact to be clearly observed, as well as any spontaneous emulsification which developed. Contacting experiments with $C_{12}E_5$ as the surfactant and with pure oleyl alcohol and oleic acid soils showed little activity below the cloud point but vigorous activity at higher temperatures including formation of an intermediate lamellar liquid crystalline phase. Diffusion path theory, which allows prediction of spontaneous emulsification resulting from diffusion and of intermediate phase formation during contacting processes, was used to understand the dynamic behavior seen during contacting experiments. Tentative diffusion paths for the contacting experiments with pure oleyl alcohol were presented with the aid of a partial phase diagram of the oleyl alcohol-water-$C_{12}E_5$ system.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.44-44
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• 2003

Scandium을 소량 첨가한 Al합금은 용체화 처리 후 시효에 의해 강화되며, 합금의 주 강화상은 Ll2 type의 규칙구조를 갖는 A1$_3$Sc상으로 열처리시 아주 미세한 정합의 구형입자로 석출한다. Scandium은 Al합금에서 첨가원소의 at%에 따른 경량화 효과가 Gold 다음으로 크다. 현재까지의 Al-Sc계 합금에 대한 연구는 시효경화에 따른 기계적 특성 변화에 대해서만 이루어져 왔으나 본 연구에서는 투과전자현미경을 이용하여 열처리에 따른 미세조직의 변화, 급냉 상태에서 생성된 A13Sc입자의 형성 및 계면구조, 시효에 따른 석출거동을 규명하였다. 실험에 사용된 alloy는 미국의 Ashurst 사에서 제조된 Al-2wt%Sc모합금과 순도 99.9%의 Al을 혼합하여 Arc melting법으로 제조하였다. Primary A13Sc상은 Ll2 type으로 응고시에 용융상태에서 먼저 핵생성되어 Al의 핵생성 site로 작용한다. 635$^{\circ}C$에서 용체화 처리한 시편에서는 수백 nm 크기를 갖는 $Al_3$Sc상이 계면과 matrix내에 구형으로 존재함을 확인하였다. 수백 nm 크기의 $Al_3$Sc상의 내부에는 역위상 경계(Antiphase boundary)이 존재로 인한 특징적인 contrast가 관찰되었으며, 이 $Al_3$Sc상은 응고시 생성된 작은 $Al_3$Sc상들이 모여져 생성된 것으로 추측된다. 수백 nm 크기 의 $Al_3$Sc사와 Al matrix 사이의 계면에는 격자상수 차이에 의한 많은 edge dislocation들이 관찰된다.

• Composites Research
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• v.17 no.3
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• pp.45-50
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• 2004

The dynamic properties of short-fiber reinforced chloroprene rubber with different interphase conditions and fiber contents have been studied as functions of frequency, amplitude and temperature. The loss factor(LF) slightly increased more than 1.33% of strain and the dynamic ratio(DR) rapidly decreased with increasing strain amplitude. The LF rapidly decreased with increasing frequency especially more than 50Hz. The DR showed the lower when it compared to virgin material with increasing frequency. The LF showed the maximum at $65^{\circ}$ and rapidly decreased after that temperature. The DR showed the lower when it compared with virgin rubber with increasing temperature. Generally, the better interphase condition showed the lower LF and DR at the same testing condition. Therefore, the short-fiber reinforced rubber could have the better isolation when the frequency ratio is more than $\sqrt{2}$ compared with frequency ratio less than $\sqrt{2}$.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.516-520
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• 2016

Concentrated liquid detergents have 2~3 times higher surfactant contents [35~45% (w/w)] compared to those of normal type detergents. In general, a single surfactant forms a lyotropic liquid crystal (LC) phase when the concentration is in the region of 30~60% (w/w). Whereas the concentrated liquid detergent at about 40% (w/w) concentration in a mixed surfactant system shows an opaque appearance of gel or LC. In order to meet consumer needs and preference for product appearance, we applied hydrotropes and various surfactants systems in concentrated liquid detergents to obtain an opaque gel-phase and also a clear transparent phase at even below zero $^{\circ}C$ temperature. The more effective hydrotropes for making concentrated liquid detergents are 1,6-hexanediol, adipic acid and dipropylene glycol (DPG) which have two hydrophilic groups in both terminated positions. In order to prepare an excellent concentrated liquid detergent, good hydrotropes alongside secondary type surfactants like LAS and SAS were used. The formation of LC phase of concentrated liquid detergents at about 40% (w/w) concentration could be prevented by the use of both hydrotropes and secondary type surfactants. The result indicate that concentrated detergents having excellent low temperature stability and controlled viscosity can be prepared.