• Title/Summary/Keyword: 계면물성

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Introduce of New Polymerization Methods for Pressure Sensitive Adhesive (새로운 점착제 합성법 소개)

  • Aota, Hashiramoto;Ko, Sei Youn;Lim, Yong Kwann;Lee, Sang Kuk
    • Journal of Adhesion and Interface
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    • v.3 no.2
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    • pp.45-52
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    • 2002
  • 기존의 점착제 합성방법에서 탈피하여 용액형 점착제(Solution)의 장점과 입자형 점착제(Emulsion)의 장점을 동시에 보유한 NAD (Non-Aqueous Dispersion Polymer)를 합성하였다. NAD는 메탄올 분위기에서 6개월 이상의 분산 안정성을 유지하였다. NAD는 용액에서 입자형 고분자의 형태를 이루고 있음을 도공 공정에서 확인하였다. 또한 기존의 아크릴 점착제의 장점과 고무계점착제의 장점을 결합한 고분자량의 점착제, GP (Graft Polymer)를 합성하였다. GP는 자체가 매우 높은 분자량을 보유하여 가교제의 첨가 없이도 우수한 물성을 나타내었다. GP는 일반적으로 고 분자량의 고분자에서 나타나는 Weissenberg effect 현상을 나타내었다. 이들의 점착제로 응용시 각각의 물성을 비교하여 나타내었다.

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Design factors of Rubber Materials for Correspondence to the Environmental Noise Regulation (환경 소음 규제 대응을 위한 고무 재료 설계 인자)

  • Lim, Won Woo
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.1-6
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    • 2002
  • We invested which is major one in rubber materials design factors affecting on noise and showed the design guide for low noise tire development in this study. Tire noise and impact noise for rubber sheets were tested at anechoic room. Hardness, tensile and dynamic mechanical properties were also measured using the rubber sheets. A major design factor of rubber materials affecting on the tire noise was hardness or 300% modulus. There was also positive correlation between two properties. Therefore, designing rubber materials to have low hardness or 300% modulus can reduce noise.

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Properties of $SiO_2$Deposited by Remote Plasma Chemical Vapor Deposition(RPCVD) (원거리 플라즈마 화학증착법으로 증착된 이산화규소박막의 물성)

  • Park, Yeong Bae;Gang, Jin Gyu;Lee, Si U
    • Korean Journal of Materials Research
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    • v.5 no.6
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    • pp.709-709
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    • 1995
  • 원거리 플라즈마 화학증착법을 이용하여 저온에서 이산화규소박막을 제조하였다. 본 연구 에서는 공정변수인 기판의 온도, 반응기체의 조성 및 분압과 플라즈마 전력에 따른 산화막의 재료적인 물성을 평가하였다. XPS결과에서 산화막은 양론비(O/Si=2)보다 약간 적어 실리콘이 많이 함유된 막으로 나타났다. 이 경우 굴절율과 ESR분석에 의해 미결합된 실리콘의 양이 증가함을 알 수 있었다. SIMS분석에 의해 미량의 질소성분이 계면에 존재하는 것과 실리콘 미결함을 관찰하였다. FT-IR로부터 막내 수소량을 정량화하였으며 결합각 분포는 200℃이상에서 열산화막과 비슷한 값을 얻었다. 하지만 열산화막에 비해 높은 식각율을 보여 계면 스트레스에 의해 막내의 결합력이 약해진 것으로 생각된다.

Optimum Conditions for Improvement of Mechanical and Interfacial Properties of Thermal Treated Pine/CFRP Composites (열처리된 Pine/탄소섬유 복합재료의 기계적 및 계면물성 향상을 위한 최적 조건)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Ha-Seung;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.30 no.4
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    • pp.241-246
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    • 2017
  • The brittle nature in most FRP composites is accompanying other forms of energy absorption mechanisms such as fibre-matrix interface debonding and ply delamination. It could play an important role on the energy absorption capability of composite structures. To solve the brittle nature, the adhesion between pines and composites was studied. Thermal treated pines were attached on carbon fiber reinforced polymer (CFRP) by epoxy adhesives. To find the optimum condition of thermal treatment for pine, two different thermal treatments at 160 and $200^{\circ}C$ were compared to the neat case. To evaluate mechanical and interfacial properties of pines and pine/CFRP composites, tensile, lap shear and Izod test were carried out. The bonding force of pine grains was measured by tensile test at transverse direction and the elastic wave from fracture of pines was analyzed. The mechanical, interfacial properties and bonding force at $160^{\circ}C$ treated pine were highest due to the reinforced effect of pine. However, excessive thermal treatment resulted in the degradation of hemicellulose and leads to the deterioration in mechanical and interfacial properties.

Dynamic and Mechanical Properties of PPS/ABS Blends (PPS/ABS 블렌드의 동력학적/기계적 특성)

  • 이영관;김준명;이미영;남재도;박연흠;박찬석
    • Polymer(Korea)
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    • v.26 no.1
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    • pp.139-144
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    • 2002
  • In this study, the PPS/ABS blend system was investigated in order to identify the relationship between the incorporation of compatabilizing moieties and the mechanical properties. ABS resin was chemically modified by the incorporation of maleic anhydride using reactive extrusion method to yield MABS resin, and PPS/MABS blend was prepared by a twin screw extruder. Single glass transition behavior was observed in the various compositions of PPS/MABS blend by dynamic mechanical analysis study. Upon the examination of the mechanical properties, the PPS/MABS blend exhibited an enhanced tensile, flexural and impact strength, which might be due to the better chemical compatibilization to result in the reduced interfacial tension between each components.

Studies on Mechanical Properties of Thermoplastic Vulcanizate Containing Acid Group (Acid Group이 도입된 TPV (Thermoplastic Vulcanizate)계 열가소성 탄성체의 기계적 물성에 관한 연구)

  • Kim, Dong Ho;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.16 no.2
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    • pp.63-68
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    • 2015
  • We synthesized thermoplastic polyurethane elastomer containing carboxylic acid group and TPV (thermoplastic vulcanizate). We measured the mechanical, grip, debris, contact angle and adhesion properties according to introducing acid group in elastomer structure. Mechanical and wet slip properties were improved because of the hydrogen bonding by introduction of acid group. Also adhesion strength was increased as increasing of surface polarity by carboxylic acid group. The debris property of TPV made from TPU containing carboxylic acid group was improved.

A study on the mechanical Characteristics of Bamboo fiber Composites (대나무섬유 복합재의 기계적 특성 변화)

  • Jung, Seong-Hyun;Han, Hyun-Kak;Park, Chan-Wong;Lee, Ki-Woong;Joo, Deuk-Ki
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.448-451
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    • 2012
  • 본 연구에서 matrix간의 계면 결합력을 불리하게 작용하는 Wax성분이나 Lignin, Hemi-Cellulose등의 제거를 위해 화학적 개질방법중인 NaOH, Acetic acid, Silane으로 처리하여 기질 고분자의 계면의 영향을 알아보고 SEM을 이용하여 형태학적 변화와 열적특성 변화를 관찰하였다. 형태학적 변화에서는 NaOH, Acetic acid 처리보다 Silane처리가 계면결합력이 증가하여 기계적 물성이 증가되었다는 것을 볼수 있었고, 열분석에서는 NaOH, Acetic acid, Silanec 처리가 유사하게 나타났지만, 복합재를 전처리하지 않은것보다 기질고분자와 천연섬유간의 계면 결합은 전처리하는 것이 결합에 있어서 좋다는 결과를 확인하였다.

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