• Title/Summary/Keyword: 경화거동

Search Result 482, Processing Time 0.025 seconds

Performance of Fresh and Hardened Ultra High Performance Concrete without Heat Treatment (상온 양생한 초고성능 콘크리트(UHPC)의 경화 전과 후의 성능 관계)

  • Kang, Sung-Hoon;Hong, Sung-Gul
    • Journal of the Korea Concrete Institute
    • /
    • v.26 no.1
    • /
    • pp.23-34
    • /
    • 2014
  • This study investigates the relationship between the performance of fresh and hardened Ultra-High Performance Concrete (UHPC) without heat treatment. The performance of fresh UHPC is determined by the slump flow test related to the fluidity of concrete mixtures, and the air content test. The variables of these tests are the water to binder ratio, superplasticizer dosages and volume fractions of steel fiber. Generally, insufficient fluidity and excessive air contents in concrete mixtures lead to the insufficient packing density related to the performance of harden concrete. The performance of hardened UHPC is determined by the compressive and flexural tensile tests. The results of the fresh UHPC tests show that there is the linear correlation between each variable and the slump flow diameter, and that the slump flow diameter is linearly decreased as the air content ratio increase. Using these results, the formula is developed to predict the fresh performance before mixing UHPC. The results of the hardened UHPC tests show that the hardened performance is not influenced by the air content ratio in the range of 3.2 to 4.2 per cent. However, the flexural tensile strength dominantly influenced by the volume fractions of steel fiber.

Thermal Properties of Polyurethane Elastomers Prepared with MBCA/DMTDA Mixture as Curing Agent (MBCA/DMTDA 혼합경화제를 이용한 폴리우레탄 탄성체의 열적 성질)

  • Ahn, Won Sool
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.6
    • /
    • pp.670-675
    • /
    • 2016
  • Both melting temperature and enthalpy of MBCA/DMTDA mixtures were measured as a function of DMTDA compositions using DSC. The thermal properties of polyurethane elastomer samples prepared with MBCA, DMTDA, and 40/60 MBCA/DMTDA mixture as curing agents were also observed using TGA. MBCA and DMTDA showed good miscibility over the entire composition range, exhibiting individual DSC melting peaks. Peak temperatures were non-linearly reduced as DMTDA concentrations increased, being approximately $60^{\circ}C$ in the case of the 40/60 MBCA/DMTDA mixture. Furthermore, melting enthalpy of the mixture was calculated as 3.8 J/g, which was only 4.3% compared to 87.3 J/g of MBCA. Based on these results, crystallization of the mixture was considered to occur very slowly, and the fluidic gel-state of the mixture was visually confirmed to be maintained over 5 days at room temperature. Thermal decomposition of polyurethane elastomer prepared with 40/60 MBCA/DMTDA curative started at about $190^{\circ}C$, which is similar to that observed for DMTDA, only except decomposition behavior over higher temperature of $400^{\circ}C$.

Study of the Curing Reaction Rate of a Glass Fiber Reinforced Bisphenol-A (BPA) Epoxy Prepreg by Differential Scanning Calorimetry (DSC) (Differential Scanning Calorimetry (DSC)를 이용한 유리섬유 Bisphenol-A(BPA)계 에폭시 프리프레그의 경화 반응 속도 연구)

  • Kwon, Hyeon-Jin;Park, Hee-Jung;Lee, Eun-Ju;Ku, Sang-Min;Kim, Seon-Hong;Lee, Kee-Yoon
    • Composites Research
    • /
    • v.31 no.1
    • /
    • pp.30-36
    • /
    • 2018
  • The curing behavior of glass fiber reinforced epoxy prepregs based on Bisphenol-A (BPA) was studied by differential scanning calorimetry (DSC). The total heat of reaction(${\Delta}H_{total}=280.3J/g$) was determined based on the results of the dynamic heating scanning experiments. Isothermal experiments were carried out at $110{\sim}130^{\circ}C$, and it was observed that the maximum conversion and the maximum reaction rate were increased as temperature increased. Also Kamal equation was applied to analyze autocatalytic reaction of epoxy prepregs. The higher temperatures, the greater reaction rate constants ($k_1$, $k_2$). Theoretical values were calculated by these reaction rate constants and compared with experimental values. And it was confirmed that they were in reasonable agreement. At the beginning of the reaction, the experimental data and theoretical prediction were shown the same tendency, but at the end of reaction, the experimental data were smaller than theoretical predicted values due to reaction rates controlled by diffusion.

Capacity Design of Eccentrically Braced Frames through Prediction of Link Overstrength (링크의 초과강도 예측에 의한 편심가새골조의 역량설계)

  • Hong, Yunsu;Yu, Eunjong
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.34 no.5
    • /
    • pp.271-278
    • /
    • 2021
  • According to the capacity design of eccentrically braced frames (EBFs), non-dissipative members such as columns, link-exterior beams, and braces must remain within the elastic region when a fully-yielded and strain-hardened link transmits force to them. The current AISC 341 standard suggests a strain-hardening factor (SHF) of 1.25 for a link under capacity design, regardless of its properties. However, all the links in an EBF are not likely to yield simultaneously to the extent to which the overstrength corresponding to 1.25 times their expected strength is attained, especially for high-rise buildings. Considering this phenomenon, a technique to predict the SHF of links at the limit state of the structure is proposed in this paper. The exact prediction of the links' SHF could save structural quantities dramatically while achieving the principle of capacity design. To validate the effectiveness of this technique, SHF values predicted by conducting linear analysis were compared with those evaluated by nonlinear analysis. Furthermore, the maximum demand-to-capacity ratios of the non-dissipative members were calculated to verify whether they would remain elastic at the limit state of the structure. Consequently, EBFs designed by the proposed method showed substantially economical quantities through the exact prediction of the SHFs, and the intention of capacity design was successfully achieved.

Surface characteristics for thermal diffusion of FA-BFS-based geopolymer ceramics added alumina aggregate (알루미나 골재를 첨가한 FA-BFS계 지오폴리머 세라믹스의 열확산에 대한 표면 특성)

  • Kim, Jin-Ho;Park, Hyun;Kim, Kyung-Nam
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.29 no.2
    • /
    • pp.61-70
    • /
    • 2019
  • Geopolymer is an eco-friendly construction material that has various advantages such as reduced $CO_2$ emission, fire resistance and low thermal conductivity compared to cement. However, it has not been many studies on the thermal behavior of the surface of the geopolymer panel when flame is applied to the surface. In this study, surface characteristics of hardened geopolymer on flame exposure was investigated to observe its characteristics as heat-resistant architectural materials. External structure changes and crack due to the heat shock were not observed during the exposure on flame. According to the residue of calcite and halo pattern of aluminosilicate gel, decarboxylation and dehydration were extremely limited to the surface and, therefore, it is thought that durability of hardened geopolymer was sustained. Gehlenite and calcium silicate portion was inversely proportional to quartz and calcite and significantly directly proportional to BFS replacement ratio. Microstructure changes due to the thermal shock caused decarboxylation and dehydration of crystallization and it was developed the pore and new crystalline phase like calcium silicate and gehlenite. It is thought that those crystalline phase worked as a densification and strengthening mechanism on geopolymer panel surface.

Analysis of Influential Factors on Wax Deposition for Flow Assurance in Subsea Oil Production System (해저 석유생산시스템에서 유동안정성 확보를 위한 왁스집적 영향요소 분석 연구)

  • Jung, Sun-Young;Kang, Pan-Sang;Lim, Jong-Se
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.39 no.6
    • /
    • pp.662-669
    • /
    • 2015
  • There has been an increased interest in the mitigation of wax deposition because wax, which usually accumulates in subsea oil-production systems, interrupts stable oil production and significantly increases the cost. To guarantee a required oil flow by mitigating wax deposition, we need to obtain a reliable estimation of the wax deposition. In this research, we perform simulations to understand the major mechanisms that lead to wax deposition, namely molecular diffusion, shear stripping reduction, and aging. While the model variables (shear reduction multiplier, wax porosity, wax thermal conductivity, and molecular diffusion multiplier) can be measured experimentally, they have high uncertainty. We perform an analysis of these variables and the amount of water and gas in the multiphase flow to determine these effects on the behavior of wax deposition. Based on the results obtained during this study for a higher wax porosity and molecular diffusion multiplier, we were able to confirm the presence of thicker wax deposits. As the shear reduction multiplier decreased, the thickness of the wax deposits increased. As the amount of water increased, there was also an increase in the amount of wax deposits until 40% water cut and decreased. As the amount of gas increased, the amount of wax deposits increased because of the loss of the light hydrocarbon component in the liquid phase. The results of this study can be utilized to estimate the wax deposition behavior by comparing the experiment (or field) and simulation data.

Behavior of grouted bolts in consideration of seep age forces (침투수력을 고려한 전면접착형 록볼트의 거동연구)

  • Lee, In-Mo;Kim, Kyung-Hwa;Shin, Jong-Ho;Nam, Seok-Woo
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.7 no.3
    • /
    • pp.209-218
    • /
    • 2005
  • In a NATM tunnel, fully grouted bolts are widely used as part of supporting system. Grouted bolts play an important role not as to take some parts of load acting on the tunnel lining but as to reinforce the ground adjacent the tunnel. In conjunction with tunnel construction, the presence of groundwater may pose a number of difficulties. With respect to tunnel design, influences of groundwater on tunnel behavior have been considered in many aspects. However, the effect on grouted bolts has been rarely investigated. In this study, the behavior of grouted bolts, which are affected by the seepage forces, was examined. In order to investigate the effects of seepage forces, the theoretical solutions for a drained condition were proposed. Based on the theoretical solutions, ground reaction curves considering seepage forces were obtained. By comparing the ground reaction curves supported by grouted bolts with those for the unsupported cases, the effect of reinforcement was evaluated. Finally, through comparison between supported ground react ion curve s in the drained condition and those in the case of groundwater flow, it was observed that the grout ed bolts are more structurely beneficial when the seepage occurs towards the tunnel than when there is no groundwater flow.

  • PDF

Numerical analysis of pre-reinforced zones in tunnel considering the time-dependent grouting performance (터널 사전보강영역의 경시효과를 고려한 수치해석 기법에 관한 연구)

  • Song, Ki-Il;Kim, Joo-Won;Cho, Gye-Chun
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.9 no.2
    • /
    • pp.109-120
    • /
    • 2007
  • Auxiliary support systems such as the reinforced protective umbrella method have been applied before tunnel excavation to increase ground stiffness and to prevent the large deformation. However, determination procedure of geotechnical parameters along the construction sequence contains various errors. This study suggests a method to characterize the time-dependent behavior of pre-reinforced zones around the tunnel using elastic waves. Experimental results show that shear strength as well as elastic wave velocities increase with the curing time. Shear strength and strength parameters can be uniquely correlated to elastic wave velocities. Obtained results from the laboratory tests are applied to numerical simulation of tunnel considering its construction sequences. Based on numerical analysis, initial installation part of pre-reinforcement and portal of tunnel are critical for tunnel stability. Result of the time-dependent condition is similar to the results of for $1{\sim}2$ days of the constant time conditions. Finally, suggested simple analysis method combining experimental and numerical procedure which considering time-dependent behavior of pre-reinforced zone on tunnel would provide reliable and reasonable design and analysis for tunnel.

  • PDF

Prediction of Failure Behavior in Composite Motor Cases by Acoustic Emission during Hydroproof Testing (수압보증시험시의 음향방출에 의한 복합재 연소관의 파괴거동 예측)

  • Song, Sung-Jin;Oh, Chi-Hwan;Jeong, Hyun-Jo;Rhee, Sang-Ho;Lim, Soo-Yong;Kim, Ho-Chul
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.18 no.2
    • /
    • pp.92-102
    • /
    • 1998
  • Prediction of failure behavior in filament-wound composite motor cases is one of the important issues for their reliable application. Acoustic emission during hydroproof testing of the cases is used to solve this problem. Based on the acoustic emission behavior, failure sites can be located successfully. The identification of failure modes is also possible using the distribution of acoustic emission amplitude. Due to the limitation in the number of samples, it is not possible to predict the final burst pressure of motor cases and the effect of impact damage on the final burst pressure.

  • PDF

Nonlinear Numerical Analysis for Shear Dominant RC Columns Subjected to Lateral Force (전단거동이 우세한 기둥의 비선형 해석에 관한 연구)

  • Kim Ick-Hyun;Sun Chang-Ho;Lee Jong-Seok
    • Journal of the Korea Concrete Institute
    • /
    • v.16 no.4 s.82
    • /
    • pp.467-476
    • /
    • 2004
  • Because of crack control by steel bars after cracking the material models for reinforced concrete(RC) differ from those for plain concrete(PL). The nonlinear behavior of columns subjected to lateral load was simulated with reasonable accuracy in 3D analysis by applying distinct material models for RC and PL zone subdivided properly on the section. The shear strain is confirmed to develope unstably with ununiform distribution in out-of-plane direction. And this tendency becomes stronger as the thickness of column member increases in out-of-plane direction. If this ununiformity in strain distribution is not taken into consideration the capacity and the deformability of columns in shear dominant failure are overestimated excessively in two dimensional analysis. By introducing equivalent softening model a behavior of columns can be predicted too in two dimensional analysis.