• Title/Summary/Keyword: 경쟁 반응

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The Kinetics and Mechanism of Hydrolysis of Styrylphenylsulfone Derivatives (Styrylphenylsulfone 유도체의 가수분해 반응 메카니즘)

  • Nack-Do Sung;Ki-Sung Kwon;Tae-Rin Kim
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.120-126
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    • 1989
  • The Kinetics of hydrolysis of styrylphenylsulfone derivatives in 50% methanol-water at 25$^{\circ}$C and ionic strength of 0.10 was investigated by UV spectrophotometry in the pH range of 0.0-14.0. The rate equations, which can be applied over a wide pH range, were obtained. The Hammett rho constants for the hydrolysis are 1.85 at pH 7.0 and 1.54 at pH 13.0, respectively. On the basis of the evidence, it is proposed that the general base-catalysis occurs in the hydrolysis of styrylphenylsulfone derivatives; above pH 11.0, Michael type nucleophilic addition take place, while below pH 9.0, the reaction is initiated by addition of water and from pH 9.0 to pH 11.0 these two reactions occur com-petitively.

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Effect of Sulfate and Heavy Metals on Methanogenic Activation of in the Anaerobic Digestion of Tannery Wastes (피혁폐수의 혐기성 소화시 황산염과 중금속이 메탄균 활성에 미치는 영향)

  • Shin, Hang Sik;Oh, Sae Eun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.1
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    • pp.13-21
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    • 1996
  • For treating tannery wastewater containing high sulfate and heavy metals, test was performed to assess their performance, competition between SRB (sulfate reducing bacteria) and MPB (methane producing bacteria), and the activity of MPB according to change of chromium concentrations. COD removal efficiency was above 70% at VLR (volumetric loading rate) of 2.0 gCOD/I.day and HRT (hydraulic retention time) of 18hrs at $35^{\circ}C$. In the competition between SRB and MPB, about 15% of the removed COD was utilized by SRB in the begining, but it became 43% at the end. It indicated that MPB was strongly suppressed by the occurrence of significant sulfate reduction since a large electron flow was uptaken by SRB. For the entire experiment, removal efficiencies of chromium concentration were more than 90%. Despite high removal efficiencies of chromium concentration, performance of reactor did not change significantly during the experimental periods. Expecially, chromium (III) is tannery wastewater is less toxic than chromium (VI).

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Bioreactor Systems for the Cometabolic Biodegradation of Trichloroethlene (트리클로로에틸렌의 공동대사적 생분해를 위한 생물반응기 시스템)

  • 이은열
    • KSBB Journal
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    • v.16 no.6
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    • pp.527-532
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    • 2001
  • Trichlooethylene (TCE) has become a widespread contaminant in air, soil, and underground water due to extensive industrial used and improper disposals. Since TCE is a suspected carcinogen and constitutes public health concerns, many treatment systems have been investigated to remove this hazardous waste. One of the most premising reactor systems for the treatment of TCE is trickling biofilter (TBF), in which monooxygenase (MO), the corresponding enzyme for initiating primary substrate oxidation, fortuitously degrades TCE via cometabolism. TCE, however, is not easily treated by simple TBF. This is mainly due to the toxicities of TCE and its degradation products to microbial film in TBF. In this paper, recent progresses on the development of bioreactor system for the treatment of TCE, especially gas-phase TCE, are reviewed. The potentials of novel biofilm reactor systems were also discussed for the long-term continuous treatment of TCE.

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Econometric Study on Forecasting Demand Response in Smart Grid (스마트그리드 수요반응 추정을 위한 계량경제학적 방법에 관한 연구)

  • Kang, Dong Joo;Park, Sunju
    • KIPS Transactions on Computer and Communication Systems
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    • v.1 no.3
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    • pp.133-142
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    • 2012
  • Cournot model is one of representative models among many game theoretic approaches available for analyzing competitive market models. Recent years have witnessed various kinds of attempts to model competitive electricity markets using the Cournot model. Cournot model is appropriate for oligopoly market which is one characteristic of electric power industry requiring huge amount of capital investment. When we use Cournot model for the application to electricity market, it is prerequisite to assume the downward sloping demand curve in the right direction. Generators in oligopoly market could try to maximize their profit by exercising the market power like physical or economic withholding. However advanced electricity markets also have demand side bidding which makes it possible for the demand to respond to the high market price by reducing their consumption. Considering this kind of demand reaction, Generators couldn't abuse their market power. Instead, they try to find out an equilibrium point which is optimal for both sides, generators and demand. This paper suggest a quantitative analysis between market variables based on econometrics for estimating demand responses in smart grid environment.

Strategies to Attract Transshipment Container Cargos from/to China by Korea Ports (우리나라 항만의 대중국 환적화물 유치방안에 관한 연구)

  • 정태원;곽규석
    • Journal of Korean Society of Transportation
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    • v.20 no.2
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    • pp.7-16
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    • 2002
  • Rapid growth rate of container traffic in China has caused the fierce competition to attract Trans-shipment Container Cargos from/to China among competitive ports in Asia. Therefore, this paper aims to suggest some strategies to attract them from/to China by Korea ports. To do so, it evaluates the preference of important ports in the competitive situation and the competitiveness of important ports in Asia, and finally proposes the relative order of important factors. Based on the evaluation of it, Both the Pusan and the Kwangyang ports have to strengthen port facility to attract move traffic and in detail, reinforce the number of berth, yard areas and handling equipment. they also have to provide high qualify of services to deliver cargos in time. not being damaged and swiftly response to shipowner and shipper's claim.

Research on Emotional Convergence Technology based on Non Contact Sensing and Social Interaction. (비접촉 센싱 기술과 사회적 상호작용에 따른 감성융합기술 연구)

  • Hwang, Sung Teac;Whang, Mincheol
    • Journal of the Korea Convergence Society
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    • v.8 no.6
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    • pp.163-170
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    • 2017
  • In this paper want to recognize competition and cooperation as a non-contact sensing method among the social emotion that are caused by interaction. Experiments were conducted in a pattern matching task divided into competition and cooperation situations. Data collection was performed by extracting the micro-movement data of 15Hz component from the upper body image. We compared and analyzed the amount and the variation and synchronization. As a result, Amount and variation are bigger in competition than cooperation. Synchronization was higher in cooperation than competition. This can be seen as the difference between two people trying to win when they are in competition and trying to breathe each other in cooperation. This study is significant in confirming the possibility of competition and cooperation through non contact sensing method based on physiological response.

Modeling and Analysis the Competition Dynamics among Container Transshipment Ports : East-Asian Ports as a Case Study (컨테이너 환적 항만 간의 동태적 경쟁에 관한 연구 : 동아시아 항만을 중심으로)

  • Abdulaziz, Ashurov;Kim, Jae-bong;Park, Nam-ki
    • Journal of Korea Port Economic Association
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    • v.32 no.4
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    • pp.165-182
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    • 2016
  • This study examines the competitiveness and cooperativeness among the container ports in East Asia by analyzing their monthly dynamics in eight years (2008-2015). Time series data on container throughput divided into origin and destination (O/D), such as the top six Chinese ports and the transshipment (T/S) ports such as Hong Kong, Busan, and Singapore, are computed with two methods based on the Vector Error Correction Model (VECM). The first Granger causality test results show that Busan T/S has significant bilateral relations with three Chinese O/D ports; and significant unidirectional relations with three other O/D ports. Shenzhen port has significant bilateral relations with Singapore, and has a significant unidirectional relation with Hong Kong port. Co-integrating test results showed that Busan holds negative co-integration with all Chinese O/D ports. Impulse response function (IRF) results show an opposite direction between paired ports. The ratios of the impulse from T/S ports are significantly high to one another in the short-run, but its power declines as time passes. The ratio of the impulse from the Chinese ports to T/S ports is less significant in the short-run period, however, it becomes more significant as time passes. The significance of most shocks was high in the second period, but was diluted after the sixth period.