• The Journal of the Petrological Society of Korea
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• v.25 no.1
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• pp.1-12
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• 2016

This study reports the results about the petrography of volcanic rocks in Namoo island and Namhyeongje island, off the southern coast of Busan City. The rocks in the Namhyeongje island composed of dacitic crystal-vitric welded tuff, showing phenocrysts of plagioclase, rock fragment with flow structure of elongated and flattened pumice fragments. In thin section it shows pyroclastic texture. The volcanic rocks in Namoo island are mainly dark grey-bluish dacite with phenocrysts of plagioclase and gradually changed to pink-greyish rhyodacite with auto-brecciated. In the northeastern part of the island, the volcanic rocks occurred as aggromerate with a poorly sorted mixture of blocks, lappili and ash and felsic feeder dike intrude the aggromerate. Major element composition of the volcanic rocks in Namhyeongje island and Namoo island are $SiO_2$ 73.6~74.4 wt.% and 65.5~68.3 wt.%, respectively. The volcanic rocks in these island are felsic volcanic rocks.

• The Journal of the Petrological Society of Korea
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• v.14 no.4 s.42
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• pp.195-211
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• 2005

The Kusandong Tuff, known as a representative key bed in the Cretaceous Gyeongsang Basin, is a crystal-rich tuff of pyroclastic flow and surge origin. It is 1-4 m thick and laterally extends for more than 200 km intercalated in the upper part of the Hayang Croup. Observations and analyses of the feldspar crystals in the tuff, using polarizing microscopes, EPMA, and BSE images, reveal that the plagioclase crystals in the tuff were completely albitized (>$97\%$ Ab) whereas those in the southernmost localities where the tuff is rich in fine ash matrix are unaltered or partly albitized. K-feldspars are partly albitized at all localities, irrespective of the matrix content of the tuff, Perthitic textures, chessboard twinning, albitization along micro-fractures and cleavages, and the relationship between matrix content and the degree of albitization suggest that feldspars in the Kusandong Tuff were albitized by Na-rich fluid after burial. Albitization is interpreted to start preferentially along micro-fractures and cleavages and be hampered in matrix-rich tuffs with a low permeability. Original composition of the plagioclases in the Kusandong Tuff is also interpreted to have ranged between oligoclase and andesine ($Ab_{62.5}-Ab_{83.3}$) before the albitization.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.293-311
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• 2021

The volcanic rocks that make up Yeongdo island, an administrative district located on the southern coast of Busan, are composed of andesitic and rhyolitic rocks. Andesitic rock is mainly composed of volcanic breccia has a phenorysts of plagioclase and contains rock fragments. The rhyolitic rock is composed of volcanic angular rock at the base of Mt. Bongnae, and welded tuff forms the main mass of Mt. Bongnae. The fiamme structure can be easily observed with the naked eye, and the higher the altitude, the weaker the welded structure develops and the less the amount of rock fragments and crystals constituting the welded tuff. It is indicated that the magma that formed this study area is related to the tectonic environment of the continental margin related to subduction, and that it erupted after undergoing fractional cystallization at the same time with some contaminant in the continental crust. As a result of analyzing the main elements by altitude, it is believed to be the result of mixing at least 4 times or more of magma batches.

• Korean Journal of Heritage: History & Science
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• v.45 no.1
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• pp.86-101
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• 2012

The constituting rocks of Multi-storied Round shape stone Pagoda of Unjusa Temple are lithic tuff and rhyolite tuff breaccia which show green or grey and also rock fragment with poor roundness are present in the structure. lithic tuff is composed of feldspar and quartz which are glassy texture and cryptocrystalline and also micro crystalline are scattered. phenocryst quartz and feldspar in the substrate composed of feldspar and opaque minerals are found in rhyolite tuff breaccia. dust, exfoliation, cavity, fracture and crack are observed in all the stone of the pagoda and the result of Infrared Thermography shows partial inter cavities have developed severely which may cause further exfoliation. In addition, a great deal of various grey, green, and yellow brown lichen as well as bryophyte are present at the upper part of eastern and western roof stone located above the third floor. Discolors remarkably shown at stereobate and roof stone are identified as inorganic pollutants such as manganese oxide, iron oxide and iron hydroxide. The stone of the pagoda of the Chemical Index of Alteration (CIA) and the Weathering Potential Index (WPI) are 55.69 and 1.12 respectively and this corresponds to a highly weathered stage. The measured values, average ultrasonic velocity 2,892m/s, coefficient of weathering 0.4k and compressive strength $1,096kg/cm^3$, suggest that the rock strength and durability are weakened.

• Journal of the Mineralogical Society of Korea
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• v.1 no.2
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• pp.117-130
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• 1988

The morphology of the Ca-montmorillonites from the Gampo area was investigated by the use of scanning and transmission electron microscope. These bulk samples show an irregular or rugged surface with well developed cavities and relict outline of original ash material at low magnification by SEM, indicating that montmorillonites are derived from volcanogenic material. Two different types of morphology of montmorillonites by SEM were observed which appear to depend very much on the space available for crystal growth. One is honeycomb structure montmorillonite growing in an open space. The other is the closely packed aggregates of intergrown montmorillonite showing platy particles where available space for the growth is limited. Several different habits of montmorillonite within a single sample can be observed by TEM. The dominant habit observed is the irregularly shaped and foliated aggregates and the platy shaped particles. In general, platy shaped particles are relatively abundant in the samples from Yongdongri compared with those from Jugjeonri area.

• The Korean Journal of Quaternary Research
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• v.13 no.1
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• pp.35-43
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• 1999

Goryeri archaeological site is located in the upstream valley of the Danjang River. The basement rocks of the area are composed of the Cretaceous to Palaeogene biotite granite (KbGr), acidic dyke (Kad), Milyang Andesite (Kma) and Jyunggagsan Formation. Among them Milyang Andesite and Jyunggagsan Formation are prevailed in archaeological site and they are composed of reddish brown tuffaceous shale, sandstone and conglomerate, with intercalations of acidic tuffs and lapilli tuffs. The purpose of this research is not only to compare REE pattern of the soil-sedimentary deposits with those of surrounding rocks, but also to identify vitric tephra in the soil-sedimentary deposits derived from the andesite, acidic tuff and lapilii tuff, in order to illucidate the provenance of the vitric tephra. The rare earth element(REE) of the soils and sedimentary deposits results in the same REE pattern with those analyzed from the surrounding basement rocks. This indicates that the soils and sedimentary deposits are originated from the surrounding basement rocks, most probably from the andesite and lapilli tuff. In addition, vitric tephra were identified both in the Quaternary in-situ weathered soils and sedimentary deposits (PMU-13 and PMU-17), and in the weathered surrounding lapilli tuff. These vitric tephra are considered to be different from those of Japanese AT(Aira Tanzawa) -tephra. The latter is predominant with clean, platty, bubble-walled and Y-shaped vitrics, while the former is conspicuous with those shapes of large and diverse size and devitrified, as well as having secondarily bubbled-surfaces reflecting surface weathering. The size of vitric fragments in the Goryeri site is about 300${\mu}{\textrm}{m}$ and large in size in compasion to 150${\mu}{\textrm}{m}$ of Japanese AT-Tephra. The interim results of the research are contradictary to the explanations based on a series of AT-tephra researches carried by Japanese scholar. In short, the vitric materials of the Goryeri archaeological site are most probably originated from the weathering products of the surrounding basement rocks, and are different from the AT-tephra in their size, shape and devitrification properties. Thus it is highly recommended to have a further comprehensive research which is more emphasized the magmatic genesis of these vitric tephra in addition to the external shape and morphology.

• The Journal of the Petrological Society of Korea
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• v.6 no.1
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• pp.19-33
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• 1997

This study reports the results about the petrography and geochemical characteristics of 10 representative volacanic rocks. The Cretaceous volcanic rocks distributed in the vicinity of the Kageo island composed of andesitic rocks, dacitic welded tuff, and rhyolitic rocks in ascending order. Sedimentary rock is the basement in the study area covered with volcanic rocks. Andesitic rocks composed of pyroclastic volcanic breccia, lithic lapilli tuff and cryptocrystallin lava-flow. Most dacitic rocks are lapilli ash-flow welded tuff. Rhyolitic rocks consists of rhyolite tuff and rhyolite lava flow. Rhyolite tuff are lithic crystal ash-flow tuff and crystal vitric ash-flow tuff with somewhat accidental fragments of andesitic rocks, but dacitic rocks. The variation of major and trace element of the volcanic rocks show that contents of $Al_2O_3$, FeO, CaO, MgO, $TiO_2$ decrease with increasing of $SiO_2$. On the basis of Variation diagrams such as $Al_2O_3$ vs. CaO, Th/Yb vs. Ta/Yb, and $Ce_N/YB_N$ vs. $Ce_N$, these rocks represent mainly differentiation trend of calc-alkaline rock series. On the discriminant diagrams such as Ba/La and La/Th ratio, Rb vs. Y + Nb, the volcanic rocks in study area belongs to high-K Orogenic suites, with abundances of trace element and ternary diagram of K, Na, Ca. According to the tectonic discriminant diagram by Wood, these rocks falls into the diestructructive continental margin. K-Ar ages of whole rocks are from andesite to rhyolite $97.0{\pm}6.8~94.5{\pm}6.6,\68.9{\pm}4.8,\61.5{\pm}4.9~60.7{\pm}4.2$ Ma, repectively. Volcanic rocks in study area show well correlation to the Yucheon Group in terms of rock age dating and geochemcial data, and derived from andesitic calc-alkaline magma that undergone low pressure fractional crystallization dominated plagioclase at <30km.

• Journal of the Mineralogical Society of Korea
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• v.23 no.4
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• pp.377-393
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• 2010

Pumiceous tuffs occurring in the Beomgockri Group are examined applied-mineralogical characteristics and their controling factors to evaluate their potentials as the adsorption-functional mineral resources. The pumiceous tuffs are diagenetically altered to low-grade zeolitcs and bentonites in the Janggi area. Compositional specialty due to the presence of pumice fragments induces the altered tuffs to exhibit the characteristic adsorption property combined with cation exchange capacity, specific surface area, and acidic pH. Unusual lower pH in the adsorption-functional mineral substances is turned out to be originated from the presence of H-smectite having $H^+$ in the interlayer site of the sheet structure. On account of disordered crystallinity resulting from the exchanged $H^+$ in the interlayer site, the smectite commonly forms crenulated edges in the planar crystal form and exhibits characteristic X-ray diffraction patterns showing comparatively lower intensities of basal spacings including (001) peak than conventional Ca-smectite. Based on the interpretation of paragenetic relations and precursor of the H-smectite, a genetic model of the peculiar clay mineral was proposed. The smectite formation may be facilitated resulting from the precipitation of opal-CT at decreasing pH condition caused by the release of H+ during diagenetic alteration of pumice fragments. Because of the acidic smectite, the low-grade mineral resources from the Beomgockri Group may be applicable to the adsorption industry as the raw materials of acid clays and bed-soil.

• The Journal of Engineering Geology
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• v.19 no.4
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• pp.459-474
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• 2009

By the analysis of discontinuity at the outcrop and lineament on the satellite image, the joints have deeply relationship with the lineaments. The joint spaces at the drilling core are mostly 1~20 cm but at the rhyolite which is distributed near fault they have more closely. These volcanic rocks belong to the subalkaline series tuff, rhyolite, basalt in the study area from the diagram of $Nb/Y-Zr/TiO_2$. The composition diagram of Hf/3-Th-Nb/16 show destructive plate-margin basalt and their differentiates. The environment of formation of volcanics are normal continental arc. Most of LREE show high enriched pattern but HREE show depleted pattern. The K/Ar age of intermediate volcanics, tuff, rhyolite, crystal tuff are 55.3Ma, 77.25 Ma~91.22Ma, 63.16~64.39Ma, 54.49 Ma respectively.

• Korean Journal of Heritage: History & Science
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• v.37
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• pp.285-307
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• 2004

Synthesize and examine petrological characteristic and geochemical characteristic by weathering formation of rock and progress of weathering laying stress on stone cultural properties of Unjusa temple of Chonnam Hwasun county site in this research. Examine closely weathering element that influence mechanical, chemical, mineralogical and physical weathering of rocks that accomplish stone cultural properties and these do quantification, wish to utilize by a basic knowledge for conservation scientific research of stone cultural properties by these result. Enforced component analysis of rock and mineralogical survey about 18 samples (pyroclastic tuff; 7, ash tuff; 4, granite ; 4, granitic gneiss; 3) all to search petrological characteristic and geochemical characteristic by weathering of Unjusa temple precinct stone cultural properties and recorded deterioration degree about each stone cultural properties observing naked eye. Major rock that constitution Unjusa temple one great geological features has strike of N30-40W and dip of 10-20NE being pyroclastic tuff. This pyroclastic tuff is ranging very extensively laying center on Unjusa temple and stone cultural properties of precinct is modeled by this pyroclastic tuff. Stone cultural propertieses of present Unjusa temple precinct are accomplishing structural imbalance with serious crack, and because weathering of rock with serious biological pollution is gone fairly, rubble break away and weathering and deterioration phenomenon such as fall off of a particle of mineral are appearing extremely. Also, a piece of iron and cement mortar of stone cultural properties everywhere are forming precipitate of reddish brown and light gray being oxidized. About these stone cultural properties, most stone cultural propertieses show SD(severe damage) to MD(moderate damage) as result that record Deterioration degree. X-ray diffraction analysis result samples of each rock are consisted of mineral of quartz, orthoclase,plagioclase, calcite, magnetite etc. Quartz and feldspar alterated extremely in a microscopic analysis, and biotite that show crystalline form of anhedral shows state that become chloritization that is secondary weathering mineral being weathered. Also, see that show iron precipitate of reddish brown to crack zone of tuff everywhere preview rock that weathering is gone deep. Tuffs that accomplish stone cultural properties of study area is illustrated to field of Subalkaline and Peraluminous, $SiO_2$(wt.%) extent of samples pyroclastic tuff 70.08-73.69, ash tuff extent of 70.26-78.42 show. In calculate Chemical Index of Alteration(CIA) and Weathering Potential Index(WPI) about major elements extent of CIA pyroclastic tuff 55.05-60.75, ash tuff 52.10-58.70, granite 49.49-51.06 granitic gneiss shows value of 53.25-67.14 and these have high value gneiss and tuffs. WPI previews that is see as thing which is illustrated being approximated in 0 lines and 0 lines low samples of tuffs and gneiss is receiving esaily weathering process as appear in CIA. As clay mineral of smectite, zeolite that is secondary weathering produce of rock as result that pick powdering of rock and clothing material of stone cultural properties observed by scanning electron micrographs (SEM). And roots of lichen and spore of hyphae that is weathering element are observed together. This rock deep organism being coating to add mechanical weathering process of stone cultural properties do, and is assumed that change the clay mineral is gone fairly in stone cultural properties with these. As the weathering of rocks is under a serious condition, the damage by the natural environment such as rain, wind, trees and the ground is accelerated. As a counter-measure, the first necessary thing is to build the ground environment about protecting water invasion by making the drainage and checking the surrounding environment. The second thing are building hardening and extirpation process that strengthens the rock, dealing biologically by reducing lichens, and sticking crevice part restoration using synthetic resin. Moreover, it is assumed to be desirable to build the protection facility that can block wind, sunlight, and rain which are the cause of the weathering, and that goes well with the surrounding environment.