• Proceedings of the Materials Research Society of Korea Conference
• /
• 2003.03a
• /
• pp.227-227
• /
• 2003

흑연(graphite), 석탄(coal), 숯(char), soot(검댕이) 등의 탄소로 이루어진 재료들은 비정질부터 완전한 흑연결정까지 다양한 구조를 나타낸다. 이러한 탄소재료의 구조의 출발물질 뿐 아니라 열처리에 따라 강한 영향을 받는다 이러한 구조는 여러 구조인자에 의해 특성화되는데, 구조인자로는 층간거리 d, 결정립 크기 Lc 그리고 결정립 직경 La이다. 이런 구조 인자의 지식은 흑연화, 탄소화, 가스화 등과 같은 다양한 공정을 이해하는데 매우 중요하다. 많은 연구자들은 XRD, Raman 분광, 고분해능 TEM 등과 같은 여러 기술을 통하여 이러한 구조인자에 대한 해석을 시도하였다. 그 중 XRD는 정량적 분석에 있어서 가장 많이 이용되는 기술이다. XRD 회절피크의 위치로부터 층간거리 d를 구할 수 있으며, 결정립 크기 Lc 및 결정립 직경 La는 피크의 line 퍼짐(반가폭)으로 직접 구할 수 있다. 한편 섬유상 흡착제로 이용되는 등방성 탄소섬유는 이산화탄소 또는 수증기에 의해 쉽게 활성화되어 최고 약 2,500 $m^2$/g의 고 비 표면적을 얻을 수 있다. 이렇게 활성화 후 고 비표면적을 나타내는 이유는 좁은 분포를 나타내는 미세기공의 기공구조 때문에 발생하는 것으로 알려져 있다.

• Journal of Korean Society for Atmospheric Environment
• /
• v.4 no.2
• /
• pp.11-19
• /
• 1988

대기오염물질 속에 함유되어 있는 다환방향족 탄화수소 (PAHs)는 분자식 구조가 비슷한 수십개의 이성질체가 여러 종류의 유기화합물과 혼합되어 존재한다. 본 연구에서는 환경오염 시료중의 PAHs를 분석하는데 있어서 분석방법과 결과를 비교하기 위하여 지침이 될 수 있는 환경표준 기준물을 개발할 목적으로 굴뚝 안쪽벽에서 긁어 채취한 검댕을 시료로 선책하여 액체/액체 용매 추출방법에 의해 PAHs 분류부분을 얻었다. Phenanthrene 이외의 30여종의 PAHs 화합물을 가스크로마토그라피의 머무른시간과 가스크로마토그라피/질량분석기에 의하여 분리, 판명하였고 5종의 주 PAHs 화합물을 정확하게 정량 분석하였다. 정량분석 결과의 신뢰도, 정확도, 정밀도는 미국 NBS의 표준기준물 1647을 분석하여 검정치와 비교함으로써 평가하였다.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.18 no.4
• /
• pp.48-53
• /
• 2010

Roadside measurement of ultrafine particles, black carbon, and NOx was carried out to investigate air pollution at a junction area contaminated with vehicle emissions in Seoul from March 19 to 23, 2007. Diurnal variation of ultrafine particles, black carbon, and $NO_x$ concentrations at a roadside showed minimum at around 2-4 a.m. and two peak modes during the morning and evening rush hours. Since these pollutants might be mainly emitted from vehicles, the roadside was highly contaminated with vehicles.

• Resources Recycling
• /
• v.8 no.5
• /
• pp.34-43
• /
• 1999

An elecmc arc cracking reaclor is developed for the productiol~o f ieusuble fuel gas by the thennal destruction of waste oil. The churaclensucs of product gas and ~esiduesf rom arc crachng of wnste lubr~cat~nogil are sludird. Thc product gas is mainly coruposcd of hydrogen 135-4076), acetylene (13-4076), ethylene 13-476) and olher hgdrocnrbons. The contenr of carbon monomde, one or the main product in a conventional low-temperature Lhennal cracking umt, 1s very slnvll in lhis atc cracking expcnmcnt. Total calocctic wlue of product gas shows 11,000-13.000 kcizlkg, which is hiph cnough to use as a ~ L I I I Cga~ s . and the concentralions oC loxic gases arc well below the rcguliltury emission critena The GCIMS analysis of llquld-phase residues shows that the high rnalccular welgllt hydrocilrbons in the waste oil arc cracked into the low malecular weight hydrocarbons snd hydroem,. The dehydrogcnntion is found lo be Lhe main cracking rcacuon due lo the high temperalure ~ ~ ~ d ubcyc edle ctric arc. The average parucle size of soot as the solid-phase residue is 10 3 wm, and the conlents of cabon a ~ hdea vy metals are abovc 60% and under 0.01 ppm, respecttrely. Thc utllizvtion or sool, as industl-id1 rcsource seems lo he reasible aIter refimng.

• Journal of Korean Society for Atmospheric Environment
• /
• v.23 no.4
• /
• pp.466-477
• /
• 2007

To understand particle pollution phenomena caused by vehicles, black carbon (BC) concentrations were continuously monitored using an aethalometer at a roadside in Seoul during the period of May 79 to 25, 2005. The BC concentration was highly fluctuated for a short duration, responding to the traffic situation on the road. The lowest BC concentration was observed between 2 and 5 a.m. The local highest BC concentrations were observed during the periods of both morning and evening rush hours. Change in traffic volume accounts for the trend of hourly averaged BC concentrations from the late evening to the morning. Particularly, the slower increase of BC concentration on Sunday seems to respond directly the lower traffic volume in the morning rush hours. From the comparison with a previous work, it is concluded that the BC concentration around midday hours might be dependent on the distance from a road.

• The Korean Journal of Mycology
• /
• v.20 no.3
• /
• pp.195-203
• /
• 1992

Eight species of genus Entoloma were collected from the areas of Mt. Naejang National park, Mt. Jiri National park, Mt. Manduck and Mt. Balwang and newly recorded in Korea: Entoloma fuscodiscum, E. incanum, E. fracturans, E. lignoputridum, E. nigroviolaceum var. striatulum, E. grayanum (Pk.) Sacc. var. grayanum, E. maleoens and E. pungens.

• Journal of ILASS-Korea
• /
• v.20 no.4
• /
• pp.254-260
• /
• 2015

The objective of this study is to investigate the effect of multi-hole nozzle on the performance of small CRDI engine. Combustion and exhaust emission characteristics of engine were studied by using CFD simulation with ECFM-3Z combustion model. The conditions of simulation were varied with nozzle geometry, injection timing and injection quantity. In addition, the results were compared in terms of combustion pressure, rate of heat release, $NO_x$ and soot emissions. It was found that combustion pressure was increased when injection timing was advanced. The rate of heat release of 6 hole nozzle was higher than that of 12 hole nozzle since the quantity of fuel impinged at the bottom of piston rim was different under different injection timing conditions. In the case of $NO_x$ emission, 6 hole nozzle generated more $NO_x$ emission than 12 hole nozzle. On the other hand, in the case of soot emission, 12 hole nozzle showed higher value than 6 hole nozzle because injected fuel droplets from multi-hole nozzle were coalesced.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.04a
• /
• pp.143-147
• /
• 2007

Kerosene and diesel are compounded fuels with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focuses on the prediction of the non-equilibrium reaction of fuel-rich combustion with detailed kinetics developed by Dagaut using PSR(perfectly stirred reactor) assumption. In Dagaut's surrogate model for kerosene and diesel, chemical kinetics consists of 2352 reaction steps with 298 chemical species. Also, Frenklach's soot model was implemented along with detailed kinetics to calculate the gas properties of fuel rich combustion efflux.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.43 no.7
• /
• pp.593-600
• /
• 2015

In this study, a combined hybrid rocket system is newly introduced which has characteristics of both gas generators and afterburner type hybrid rockets. In particular, a combined gas generator utilizing solid fuel and liquid/gas oxidizer was designed as a primary combustor of the system. Combustion tests were carried out with various equivalence ratio affected by parameters such as fuel length, oxidizer flow rate, fuel port diameter and fuel type. In general, fuel-rich gas generator produces low combustion gas temperature to meet the temperature requirement and the target temperature was transiently set less than 1600 K. Since it was found that controlling parameters showed limited effects on the change of equivalence ratio, mixture of $O_2$ and $N_2$ as an oxidizer was additionally introduced. As a result, a combined gas generator successfully produced combustion gas temperature of less than 1600 K Future studies will carry out more combustion tests to attain fuel-rich combustion gas temperature less than 1200 K, which was a temperature requirement of a gas generator system in the previous studies.

• Journal of Korean Society for Atmospheric Environment
• /
• v.25 no.6
• /
• pp.571-578
• /
• 2009

$PM_{2.5}$ black carbon (BC) concentrations were measured to investigate the filter spot loading effect in raw BC data at 5-minute time-based resolution using a single-wavelength aethalometer at a Gwangju site. Also the elemental carbon (EC) concentrations from 24-hr integrated filter-based measurements of $PM_{2.5}$ particles were determined to compare with the loading compensated BC values. Close examination of the time-series BC data showed clearly the "gaps" when the filter tape advances, suggesting the correction of raw BC data. Therefore, we calculated the average BC concentration in each range of attenuation (ATN) to decide if there was (or was not) an effect on the aethalometer data according to the loading of the filter spot. A consistent decrease of average BC concentration was found with increasing ATN values for every month, suggesting there was a consistent "spot loading effect" in the raw BC data. The loading compensated BC concentration according to a simple compensation model with loading effect was 1.01~1.15 times greater than the raw BC data. The 24-hr average concentration of EC observed during summer sampling period was about 3% higher than the original 24-hr average BC value and 2% lower than the loading compensated BC concentration.