• Korean Journal of Crystallography
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• v.7 no.1
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• pp.30-35
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• 1996

Calcite(CaCO3) single crystals were grown hydrothermally and transmittance of as grown crystals was measured. Instead of platinium, teflon was lined onto the wall of autoclave to prevent the corrosion of autoclave wall by acidic NH4Cl solution. Spontaneous nucleation and growth of calcite crystal on teflon was reduced considerably by addition of NaCl and /or CH3COOH and applying low temperature gradient. When the temperature gradient exceeded to a few degrees from the critical temperature gradient(6-7℃), spontaneous nucleation and growth was rapidly increased in any hydrothermal solutions. Precise temperature control is thought to be the most important factor for the growth of calcite single crystal by hydrothermal technique. As grown calcite single crytal showed high transmittance compared to natural one by UV-visible analysis.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.125-125
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• 2016

남강 권역은 5개의 단위유역으로 구성되어 있으며, 남강A, 남강B, 남강C, 남강D와 남강E로 명명되고 1단계 수질오염총량관리제도 시행 이후 유역 내 개발 등으로 인한 오염원이 증가하고 장기간 퇴적된 저니층으로부터 오염물질이 용출되는 등 수질의 자정능력보다 더 많은 오염물질이 수체내로 유입됨으로써 수질이 악화되자 수량확보 뿐만 아니라 남강의 수질관리에 대해서 관심을 가지기 시작하였다(GNDI, 2010). 남강 하류수계는 하상구배가 매우 완만하며 유속이 느리다. 따라서 물의 체류시간이 호수와 비슷한 양상을 보이고 있다. 더욱이 남강 하류수계는 주변의 도시와 농경지로부터 물의 소모량이 크기 때문에 하류수계의 물의 흐름이 더욱 완만해지고 이로 인하여 수질 악화가 가속화되고 수역의 영양단계가 점점 증가하는 부영양화현상이 발생되고 있다. 남강하류수계와 같이 부영양화 된 수계내의 미처리 된 영양염을 이용한 식물플랑크톤의 생산에 의해 자생BOD가 공급된다. 따라서 남강댐 하류지역과 같은 수리 수문학적 특징을 가진 유역은 수질관리를 위해서 특정 수역에 유입 BOD와 자생 BOD가 어느 정도 기여하는가를 정량적으로 파악한 후, 기여도에 따라 오염원인 물질을 줄이기 위한 수질관리 방안이 설정되어야 한다. 본 연구에서는 남강유역의 오염원의 기여율 분석을 위해 하천수질모델인 QUALKO2를 사용하였으며, 점오염원 뿐만 아니라 수질에 상당한 영향을 끼치는 비점오염원의 영향을 통합적으로 고려하기 위하여 유역 모델인 SWAT과의 연계방안을 제시하였다. 또한 모델의 연계 적용을 통해 산정된 내부오염원과 내부오염원의 기여율과 수질측정결과를 활용하여 분석한 기여도와의 비교를 수행하여 신뢰성을 확보하였다.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.2
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• pp.85-94
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• 1997

The study is aimed to find out the causes of rapidly increasing chloride (Cl$^{－}$) concentration of the Samyang 3rd pumping station originated from coastal springs of Cheju since January 1996. The study results show that it was caused by following complicated natural and anthropogenic effects. Due to severe draught in 1996 with total rainfall of only 41.7% of annual mean of the last 36 years (1991 to 1995), it creates firstly), significant decrease of the spring discharges as well decline of the groundwater level at the site . Sea water level was in general 4.4 cm to 12.4 cm higher than the groundwater level of the site during 2 to 3.8 hours at each high tide. Those higher potential head of sea water motivates the sea water intrusion into the fresh water lens through the permeable clinkers and fracture zones situated beneath the existing grouted zone which was installed to a maximum 10 m below the ground water surface, The repeated expansion and contraction of the fresh water lens occurred by periodic changes of the sea water level at high and low tide accelerates secondly the enlargement of the transition zone between the fresh and sea water at the site. The decrease of recharge amount by rainfall shortage creates thirdly the reverse flow at the interface of sea water and groundwater. The repeated groundwater extraction of 2790${\pm}$450 $m^3$d$^{－1}$ at the time of low tide, when the fresh water lens of the sire is under the contraction stare, makes additional drawdown of the ground water level and induces the upconing of salt water into the fresh water lens. The duration of spring discharge whose Cl concentration is less than 150 mg/1 at the low tide measured at the nearby springs was about two hours with discharge rate of 532 $m^3$d$^{－1}$ and after that Cl$^{－}$ concentration is increased up to more than 1900 mg/ι.eased up to more than 1900 mg/L.