• Journal of the Korean Applied Science and Technology
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• v.38 no.3
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• pp.832-839
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• 2021

We tried to investigate the effects of substituent position, temperature, and additives such as NaCl and n-butanol on the solubilizations of cresol isomers by tetradecyltrimethylammonium bromide (TTAB), using the UV-Vis spectrophotometric method. The measured solubilization constants (K_s) values for each cresol isomer increased in the order o-cresolo and ∆H^o values for the solubilizations of cresols were all negative values but the ∆S^o values were all positive values within the measured ranges. The values of ∆G^o increased also with increasing the concentration of n-butanol but decreased with increasing the concentration of NaCl. From these facts, we could conclude that both the enthalpy and entropy changes contribute together for the solubilizations of cresols isomers by cationic surfactant of TTAB and they are solubilized in the polar palisade region or at the surface of micelle.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.123-123
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• 2022

자연유역 내에 도시가 자리잡고 발달해 나가면 유역의 특성에 급격한 변화를 가져온다. 이러한 변화로 인해 도시유역은 자연유역과는 상이한 수문학적 특성을 나타낸다. 그 동안 도시수문학의 주된 관심사는 도심지 홍수예방, 상수관망 등에 주어졌고, 장기적인 관점에서 도시유역의 물순환에 대한 정량화는 별로 다루어지지 않았다. 이 연구에서는 비교적 최근에 급격하게 도시화가 이루어진 탄천 유역에 대해 도시유역의 장기적인 물순환에 대해 정량화하고 자연유역과의 차이를 분석하고자 한다. 강수량, 유출량, 증발산량, 상수공급량, 하수처리량 등의 가용한 자료를 동원하여 탄천 유역의 물수지 분석을 수행하였다. 탄천유역은 유역 외부에서 상수를 공급받고 사용된 용수는 하수처리시설을 통해 하천으로 방류되고 있으며 이로 인해 유출 특성이 자연유역과 많은 차이를 보이고 있다.

• Journal of the Korean Applied Science and Technology
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• v.38 no.4
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• pp.994-1002
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• 2021

The solubilization constants (K_s) of 4-halogenated aniline derivatives by cationic surfactants (DTAB, TTAB, and CTAB) were measured by the UV-Vis method. As a result, the K_s values decreased as the temperature increased for all the aniline derivatives and showed a tendency to increase as the radius of the halogen substituent and the hydrophobic length of surfactant increased. The calculated values of ΔG^o and ΔH^o for these solubilizations all showed negative values within the measured range, but all the ΔS^o values showed positive values. For all the 4-halogenated anilines, the ΔG^o values all tended to decrease as the temperature increased, but both values of ΔH^o and ΔS^o showed a tendency to increase. In addition, as the radius of the halogen substituent increased, the values of ΔH^o and ΔS^o tended to decrease in general. However, when the hydrophobic group length of the surfactant was increased, the values of these thermodynamic functions showed a tendency to increase in general, although it differed depending on the type of aniline derivative. From the changes of such functions, it was possible to estimate the type and strength of interactions between 4-halogenated aniline and micelle, and the location at which they were solubilized in the micelle.

• Journal of the Korean Applied Science and Technology
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• v.37 no.2
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• pp.250-259
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• 2020

The solubilization constant (K_s) was determined by the UV-Vis method to investigate the interaction between organic matter (solubilized substance) and surfactant in solubilization. Solubilization constants and thermodynamic functions, according to the hydrophobic interaction between organic mater (4-alkylanilines with different alkyl substituent length) and cationic surfactants (DTAB, TTAB, and CTAB, having different hydrophobic lengths), were measured and calculated at various temperatures and compared with each other. As a result, the hydrophobic interactions between organic matters and cationic micelles increased with increasing the chain length of solute's substituent as well as surfactant's hydrophobe. However, the hydrophobic effect by the alkyl substituent of organic matter was greater than the hydrophobic effect by the surfactant. In addition, the results of the calculated thermodynamic functions showed that 4-alkylaniline was solubilized at the deep place in the micelle and its solubilization was greatly dependent on both the hydrophobic effects of organic matter and surfactant. At the calculated iso-structural temperature, the difference between the maximum and minimum values was less than 1K within the experimental conditions.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2002.05a
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• pp.590-597
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• 2002

LNG고압펌프계통은 천연가스 고압 송출에 있어 가용도가 매우 중요한 계통이다. 본 연구에서는 현재 적용되고 있는 예방(계획)정비주기를 가용성 측면에서 재검토했다. 확률적인 운전대수와 운전 및 보전 형태에 연관된 여러제약이 고려할 때 계통 불가용도를 정량화하기 위하여 시뮬레이션 기법을 적용했다. 중도 절단된 형태의 펌프 수명 데이터를 분석해 욕조형의 고장율 함수를 도출했으며 보수시간 데이터를 분석해 확률분포모수를 구했다. 또한 주요 펌프부대설비에 대해서는 상수형의 고장율과 보전율을 도출했다. 분석된 확률모수를 작성된 시뮬레이션 모형에 입력하고 과거의 운전대수 시나리오를 설정해 실험한 결과와 실제 보수 및 운전 자료를 비교해 모형의 유효성을 보였다. 그리고 차후 예상되는 운전요구대수 시나리오를 기정하고 각 예방정비주기별로 반복 실험하여 계통의 불가용도를 보이고 적합한 예방정비주기를 도출했으며 펌프부품 교체비용의 기대 절감액을 보였다.

• Journal of the Korean Chemical Society
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• v.30 no.3
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• pp.296-300
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• 1986

The pseudo-first order rate constants have been obtained for the solvolysis of pseudo-saccharinechloride in MeOH-$H_2O$, EtOH-$H_2O$, MeOH-MeCN and MeOH-$(Me)_2$CO solvents mixtures at various temperatures. Values of n and m in the Kivinen and Grunwald-Winstein plots, respectively, have been determined and the Taft's solvatochromic parameters were obtained; based on these solvent effect parameters as well as on the activation parameters it was concluded that reaction proceeds via an $S_N2$ mechanism.

• Journal of the Korean Chemical Society
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• v.32 no.6
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• pp.581-587
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• 1988

The solvolysis of substituted benzyl bromides was studied in binary solvent mixtures of acetone-water and ethanol-water at $25^{\circ}C$ and $45^{\circ}C$. The rate constants increase with electron-donating substituents in benzene ring and increasing of water contents in both of solvent mixtures. The sensitivity parameter (m) of the solvolysis of substituted benzyl bromides to solvent ionizing power (Y) was decreased in going from the electron-donating group to electron-withdrawing one, whereas their nucleophilic sensitivity increased continuously in going to above same substituents. It was shown that electron-donating (electron-withdrawing) groups make the transition state looser (tighter). The above results were consisted with the account for the potential energy surface model and the quantum mechanical approach.

• Journal of the Korean Chemical Society
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• v.27 no.2
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• pp.95-101
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• 1983

The pseudo-first order rate constants have been obtained for the solvolysis of benzoyl cyanide in various aqueous solvent mixtures and ethanol-trifluoroethanol mixtures at 1, 5, 10, 15 and $20^{\circ}C$. Values of n in the Kivinen polt, m values of Grunwald-Winstein polt, $\beta$ values of Leffler relationship and values of m and l in the extended Grunwald-Winstein polt have been calculated and studied the transition state variation caused by solvent changes using the More O'Ferrall polt and quantum mechanical approach. It has been shown that the reaction proceed via the associative $S_N2$ mechanism, using the transition state parameters and quantum mechanical model approach.

• Journal of the Korean Chemical Society
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• v.38 no.8
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• pp.539-546
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• 1994

The critical micelle concentration(CMC) and the counterion binding $constant(\beta)$ at the CMC of cetyltrimethylammonium bromide(CTAB) in a series of aqueous solutions containing medium chain-length n-alcohols(Propanol, Butanol, Pentanol and Hexanol) have been determined from the concentration dependence of electrical conductance at serveral temperature from $17^{\circ}C\;to\;41^{\circ}C.$ Thermodynamic parameters $({\Delta}G^o_m,\;{\Delta}H^o_m,\;{\Delta}S^o_m,\;and\;{\Delta}C_p)$ associated with micelle formation of CTAB have been also estimated from the temperature dependence of CMC and $\beta$ values, and the significance of these parameters and their relation to the theory of micelle formation have been considered. The results show that an enthalpy-entropy compensation effect is usually observed for the micellization of CTAB. The effects of n-alcohols on the micellar properties (CMC and $\beta$) of CTAB solutions have been also investigated. The addition of n-alcohol to the CTAB solution in a small quantity decreases the CMC value and the counterion binding constant $(\beta)$ at the CMC, but the addition of n-alcohol in an excessive quantity increases the CMC values on the conterary. These results have been explained in terms of the effect of the micelle-solubilized alcohol on the micellar surface charge density.

• Journal of the Korean Chemical Society
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• v.32 no.2
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• pp.85-93
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• 1988

Solvolyses of t-butylhalides (X = Cl, Br, I) in quasi isodielectric solvent system, MeOH-nitromethane, MeOH-nitrobenzene and MeOH-ethyleneglycol have been studied kinetically. Methanolyses for t-butylhalides in MeOH-NM and MeOH-NB show rate maxima at 40~100 % (v/v) MeOH. The rate maxima observed have been interpreted as a result of cooperative enhancement of polarity-polarizability and hydrogen bonddonor ability of solvents. The influences of polarity-polarizability and hydrogen bonddonor ability on reactivities of substrates have been discussed in terms of Y value changes. The solvolysis rates for t-butylhalides in E.G. are more than 20 fold faster than those in MeOH and this was attributed to the solvent structure of E.G.