• Journal of the Korean Electrochemical Society
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• v.12 no.3
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• pp.203-218
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• 2009

The development of lithium-ion battery (LIB) technologies and their application in the field of large-scale power sources, such as electric vehicles (EVs), hybrid EVs, and plug-in EVs require enhanced reliability and superior safety. The main components of LIBs should withstand to the inevitable heating of batteries during high current flow. Carbonate solvents that contribute to the dissociation of lithium salts are volatile and potentially combustible and can lead to the thermal runaway of batteries at any abuse conditions. Recently, an interest in nonflammable materials is greatly growing as a means for improving battery safety. In this review paper, novel approaches are described for designing highly safe electrolytes in detail. Non-flammability of liquid electrolytes and battery safety can be achieved by replacing flammable organic solvents with thermally resistive materials such as flame-retardants, fluorinated organic solvents, and ionic liquids.

• Journal of Korean Society of Forest Science
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• v.99 no.1
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• pp.96-101
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• 2010

One of the restriction of wood as building material is its combustibility. The purpose of this paper is to examine the combustion properties of the quercus variabilis and zelkova serrata which are dried at room temperature and meet the desirable characteristics for use of construction materials. The cone calorimeter (ISO 5660-1) was used to determine the heat release rate (HRR) and fire smoke index, as well as CO production and smoke obscuration. The $HRR_{mean}$ 77.94 kW/$m^2$ of the quercus variabilis at 50 kW/$m^2$ was high in comparison with $HRR_{mean}$ 13.06 kW/$m^2$ for the zelkova serrata. Furthermore, the quercus variabilis has high specific extinction area ($SEA_{mean}$), 41.11 $m^2$/kg compared with $SEA_{mean}$ 9.23 $m^2$/kg of zelkova serrata. Thease results are depend on the density of tested wood species. In addition, the quercus variabilis has high CO production rate compared with that of zelkova serrata. Also, zelkova serrata showed an increase of retardant properties attributed to char formation compared with that of quercus variabilis.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.48 no.2
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• pp.135-146
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• 2020

To define an interface in a conventional level-set method, an analytical function must be revealed for an interfacial geometry. However, it is not always possible to define a functional form of level sets when interfaces become complex in a Cartesian coordinate system. To overcome this difficulty, we have developed a new level-set formalism that discriminates the interior from the exterior of a CAD modeled interface by parameterizing the stereolithography (STL) file format. The work outlined here confirms the accuracy and scalability of the hydrodynamic reactive solver that utilizes the new level set concept through a series of tests. In particular, the complex interaction between shock and geometrical confinements towards deflagration-to-detonation transition is numerically investigated. Also, a process of flame spreading and damages caused by point source detonation in a real-sized plant facility have been simulated to confirm the validity of the new method built for reactive hydrodynamic simulation in any complex three-dimensional geometries.

• Journal of Bio-Environment Control
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• v.9 no.1
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• pp.47-59
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• 2000

In order to investigate the physical and chemical properties of artificial culture media, the specimens were substituted with 5~20％ clay, 10~30％(w) quick lime, 5~l5％(w) burnt plaster and 10％(w) sawdust. Fly ash-clay bodies were sintered at 1,050~1,20$0^{\circ}C$ and then their properties were determined. It was found that 90FA10JC(fly ash ＋clay(90：10, ％(w)) specimen sintered at 1,15$0^{\circ}C$ for 10 min. had good physical and chemical properties. When this composition was supplement with 10％(w) sawdust, bulk density water absorption, apparent porosity, compressive strength and pH after 240 hrs curing time were 1.14, 54.4％, 39.5％, 54 kgf.cm$^{-2}$ and 7.1 respectively. The physical properties of fly ash-quick lime-burnt plaster system specimens were superior to FAJC systems. However, this composition we not suitable as a artificial culture media because of its high pH. In this study, it was shown that 90FA10JC10SD(90FA10JC ＋10％(w) sawdust) system exhibited the best physical properties.

• Fire Science and Engineering
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• v.15 no.1
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• pp.16-22
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• 2001

Thermal properties of PP and LLDPE dusts from chemical plant and their risks of coexisting with oxidizer were investigated by a pressure vessel. The thermal decomposition of PP and LLDPE dusts with temperature using DSC and the weight loss with temperature using TGA were also investigated to find the thermal hazard of PP and LLDPE dusts. Using the pressure vessel which can estimate ignition and explosion of PP and LLDPE dusts coexisting with oxidizer, a series of bursting of a rupture disc, experiments has been conducted by varying the orifice diameters the weight ratio of the sample coexisting with oxidizers and the species of oxidizer. And fire gases was measured by gas analyser ($ECOM-A^+$). According to the results of the thermal analysis of PP and LLDPE dusts, the decomposition temperature range of PP and LLDPE dusts was 200 to 350 and 300 to $500^{\circ}c$, respectively. The risk of PP and LLDPE dusts coexisting with oxidizer was increased as the orifice diameter was decreased. On the other hand, it was increased as the weight ratio of the sample to the oxidizer were increased. In addition, the risk of PP and LLDPE dusts coexisting with oxidizer was affected by the decomposition temperature of the sample and oxidizer. It is found that the risk of fire becomes high when the decomposition temperature of the sample is about same as that of oxidizer. Also, the fire gases was occurred carbon monoxide and carbon dioxide. The amount of carbon monoxide generated was found to be much higher in PP decomposition than in LLDPE due to incomplete combustion of PP which has high content of carbon in chemical compound.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.16-22
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• 2016

Auto ignition characteristic is an important factor for handling combustible substance and fire prevention. This research studied about auto ignition characteristic and activation energy of Ethylene Glycol (EG) and Diethylene Glycol (DEG) by using ASTM D2155 type ignition temperature measuring apparatus. As the auto ignition temperatures, it was possible to get $434^{\circ}C$ for EG within sample amount range of $75{\sim}160{\mu}l$ and $387^{\circ}C$ for DEG within sample amount range of $130{\sim}150{\mu}l$. Also, it was possible to get $579^{\circ}C$ and $569^{\circ}C$ as instantaneous ignition temperatures with sample amount of $140{\mu}l$ for EG and DEG respectively. By using least square method from Semenov equation on measured ignition temperature and ignition delay time from this study, it was possible to calculate activation energy of EG as 25.41 Kcal/mol and DEG as 14.07 Kcal/mol. Therefore, it was possible to claim that DEG has more risk of auto ignition since the auto ignition temperature, instantaneous ignition temperature and activation energy of DEG is lower than EG.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.39-60
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• 2019

Korea Gas Safety Corporation is developing consequence analysis system for combustible materials release events to enhance risk assessment technology and its efficiency. Unlike general consequence analysis programs, the final consequence area was implemented through ETA analysis based on API-581 standard, and a convenient user interface was constructed based on HTML5-based responsive web technology. In addition, a phase equilibrium module using third-order state equations (such as Peng-Robinson, SRK, and RK) and fugecity was implemented to analyze the mixture quality. Also. using the consequence analysis algorithm introduced in CCPS books and TNO Yellow Book, we developed material leak analysis module, fireball, pool fire, jet fire, flash fire, and vapor cloud explosion consequence assessment module. In addition, the conditions for calculating the safety distance were prepared with using the control values in the EIGA standard, PAC, and Bevi Reference Book.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.17-24
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• 2019

The combustion properties of the flammable substance used in industrial fields include lower/upper flash point, lower/upper explosion limit, autoignition temperature(AIT), fire point, and minimum oxygen concentration(MOC) etc.. The accurate assessment of these characteristics should be made for process and worker safety. In this study, tert-amylalcohol(TAA), which is widely used as a solvent for epoxy resins, oxidizers of olefins, fuel oils and biomass, was selected. The reason is that there are few researches on the reliability of combustion characteristics compared to other flammable materials. The flash point of the TAA was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the TAA was measured by ASTM 659E. The lower/upper explosion limits of the TAA was estimated using the measured lower/upper flash points by Setaflash tester. The flash point of the TAA by using Setaflash and Pensky-Martens closed-cup testers were experimented at 19 ℃ and 21 ℃, respectively. The flash points of the TAA by Tag and Cleveland open cup testers were experimented at 28 ℃ and 34 ℃, respectively. The AIT of the TAA was experimented at 437 ℃. The LEL and UEL calculated by using lower and upper flash point of Setaflash were calculated at 1.10 vol% and 11.95 vol%, respectively.

• Journal of the Mineralogical Society of Korea
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• v.29 no.4
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• pp.179-190
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• 2016

X-ray diffraction analysis, chromaticity measurement, execution and evaluation by Dancheong artisan, accelerated weathering test, and fire resistance test were conducted to test the applicability as a Dancheong pigment raw materials of Korean low grade kaolin in cultural properties. The ores that feldspar rich and composed of fine particles (< $38.1{\mu}m$) showing advantageous for the inherent purpose of the white pigment than that of high grade kaolin. And the test of whiteness, concealment force, outdoor exposure durability and fire resistance shows similar or better result than existing products (Hobun and Sanhwa jidang). In conclusion, it is expected that the use of fine feldspar rich white soil and low-grade kaolin can be used as a white pigment raw materials which have similar to better material properties and economic efficiency than existing products.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.10
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• pp.4679-4688
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• 2011

This study was performed to the municipal waste generation amounts and characteristics for B city in Gangwon province, predicted the methane gas generation rate emitted from landfill, and analyzed the possibility of energy recovery to RDF(Refuse Derived Fuel) using combustible waste. The study results showed that the average bulk density of municipal waste for B city was 144.0 kg/$m^3$, and the average ratios of combustible waste were 36.0 % of paper, 21.6 % of vinyl, and 19.7 % of food waste. respectively. In the experiment for heating value, high and low heating value(moisture) was measured to 3,471 $kca{\ell}$/kg and 2,941 $kca{\ell}$/kg, respectively. After the prohibition of burying of food waste in landfill, the heating value of municipal waste was dramatically increased due to increase of the ratio of paper, vinyl, and plastic waste. The prediction results of methane gas generation rate emitted from landfill showed that the gas generation rate is increasing to 2,505.7 CH4 ton/year in 2021. After then, the rate is decreasing gradually. When the RDF facility is installed, the rate is decreasing after peaking at 1,956.9 CH4 ton/year in 2013. The generation rate of LFG emitted from waste landfill of B city was analyzed to 9.92 $m^3$/min, similar to 10.11 $m^3$/min for other city.