• 방재와보험
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• s.118
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• pp.48-51
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• 2007

본 고에서는 상온일 때 액체상태가 됨에 따라 포화증기압이 1bar 이하가 되는 물질의 보관에 대해 알아보고자 한다. 대체적으로 증류된 석유제품들(가솔린, 나프타, 케로신, 디젤이 그러하다. Zalosh의 '산업화재 예방공학(Indusrtial Fire Protection Engineering)' 과 Crowl의 '폭발의 이해(Understanding Explosions)' 를 통해 많이 다루어져왔던 내용이다.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 1999.06a
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• pp.93-98
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• 1999

톨루엔, o-크실렌등의 유기용제는 도료공업 등의 혼합용제와 기계부품의 세척등에 많이 사용되고 있다. 그러나 이들 물질들은 공정상의 제조, 저장, 처리과정 및 취급과 사용 중에 부주의로 인한 밀폐구역에서의 누출로 폭발과 화재사고가 자주 발생하고 있다. 97년 5월 $\Delta$$\Delta$조선소에서 건조 중이던 선박 기관실의 선체 탱크내부 도장작업 중 화재ㆍ폭발이 발생하였으며, 97년 10월 $\square$$\square$조선소에서 수리중이던 유조선의 Tank 내부와 pipe line에 체류중인 가연성 증기가 인화되어 화재ㆍ폭발사고가 98년 6월 김해시 소재 00공업(주)에서 솔벤트로 공작기계 부품을 세척하던중 가연성 증기가 인화되어 화재가 발생하였다. (중략)

• Journal of the Korean Institute of Gas
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• v.19 no.3
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• pp.18-24
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• 2015

The flash point is one of the most important indicators of the flammabiliy of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of binary flammable solutions, 2-propanol+propionic acid and n-hexanol+formic acid systems, were measured using Seta flash closed cup tester. Particularly n-hexanol+formic acid system exhibited minimum flash point behavior. The measured values were compared with the calculated values using Raoult's law and optimization method. The calculated data by optimization method described the measured values more effectively than those calculated by Raoult's law.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 1999.06a
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• pp.73-76
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• 1999

인화성 액체는 소방법상의 4류 위험물로 분류되며 공업용 연료, 세척, 용제 등의 원료로서 그 사용빈도, 취급, 저장되는 양이 타 위험물에 비하여 매우 많을 뿐 아니라 그 종류도 다양하며 화학공업 분야에서 광범위한 사용이 이루어지고 있다. 이러한 대부분의 인화성 액체는 낮은 B.P. 빠른 증발속도, 저인화점의 물리적 특성으로 가연성 증기의 형성이 용이하고 화재 및 폭발의 위험성과 다량의 유독성 증기의 발생 위험이 존재하고 있다. (중략)

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2007.11a
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• pp.323-327
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• 2007

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2000.04a
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• pp.19-22
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• 2000

• Journal of the Korean Institute of Gas
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• v.17 no.6
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• pp.67-72
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• 2013

The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. The flash point is a major physical property used to analyse the fire and explosion hazards of a flammable liquid solution. The flash point data for pure components are easily available in several literature. But the flash points of the flammable binary solutions appear to be scarce in the literature. The objective of this study is to measure and estimate the flash point of acetic acid-formic acid system. Cleveland open cup tester was used to measure the flash point. The experimental data were compared with the values estimated by the Raoult's law and the optimization methods based on van Laar and Wilson equations. As a result, the estmated values by optimization methods were found to be better than those based on the Raoult's law.

• Journal of the Society of Disaster Information
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• v.15 no.4
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• pp.634-647
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• 2019

Purpose: Currently, many chemicals are used in industrial and real life, and many substances are used in the form of a single substance, but most of them are used in the form of a mixture, and there is a need for a criterion for judging the danger of these substances. Method: Therefore, this study aims to confirm the risk criteria of the mixture through experimental studies on flammable mixtures in order to secure the effectiveness of the details of the existing Dangerous Goods Safety Management Act angerous Goods Judgment Criteria and to ensure the reliability and reproducibility of the dangerous goods judgment. Result: Experimental results show that alcohol flash point is mixed with water, which is a non-flammable liquid. Similar flash point trends occurred around 60% on an alcohol basis. In addition, in the case of flammable-combustible mixtures, there was little change in flash point if the flash point difference of the two materials was not large, and if the flash point difference of the two materials was low, the flash point tended to increase with the increase of the high flash point material. Conclusion: In the future, the test results may provide reference data on the experimental criteria for the flammable liquids that are cracked at the fire site.

• Fire Science and Engineering
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• v.15 no.3
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• pp.14-20
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• 2001

The flash points are one of the most important fundamental properties used to determine the potential for fire and explosion hazards of flammable substances. A classification of the flash points is important for the safe handling of flammable liquids which constitute the solvent mixtures. Basic to all flash points behavior are vapor pressure and explosive limits(lower explosive limit and upper explosive limit). The flash points of flammable solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this study, the reference values of lower flash points were compared with the calculated values by using Raoult's law and MRSM(modified response surface methodology) model. The lower flash points were in agreement with the predicted by Raoult's law and MRSM model. By means of this methodology, it is possible to evaluate reliability of experimental data of the flash points of the flammable mixtures.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2009.04a
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• pp.276-285
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• 2009

화학물질의 분류 및 표시의 국제표준화시스템(GHS)을 조기에 구축하고 국내에 사용하는 화학물질을 보다 안전하게 제조, 저장 및 운송하기 위하여 위험물안전관리법과 GHS시험 방법으로 다양한 인화성액체 시험을 실시하여 이들의 결과에 대한 연관성을 도출하고, 국내 실정에 적합한 국제표준화 시험방법을 선택가능방식(Building Block Approach)으로 제시하고자 한다. 위험물의 80%를 차지하는 인화성액체의 분류에 필요한 시험은 인화점이 가장 중요한 요소지만, 도료류와 같은 혼합물은 가연성액체량과 GHS-연소지속성에 따라 위험물/비위험물로 분류될 수 있다. 도료류는 두 시험의 분류결과가 대부분 비슷하게 나타나 GHS-연소지속성시험을 선택가능방식을 통해 우리나라에 적합하게 도입하는 것이 바람직 할 것으로 보인다.