• Journal of the Korean Institute of Gas
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• v.17 no.6
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• pp.67-72
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• 2013

The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. The flash point is a major physical property used to analyse the fire and explosion hazards of a flammable liquid solution. The flash point data for pure components are easily available in several literature. But the flash points of the flammable binary solutions appear to be scarce in the literature. The objective of this study is to measure and estimate the flash point of acetic acid-formic acid system. Cleveland open cup tester was used to measure the flash point. The experimental data were compared with the values estimated by the Raoult's law and the optimization methods based on van Laar and Wilson equations. As a result, the estmated values by optimization methods were found to be better than those based on the Raoult's law.

• Journal of the Korean Institute of Gas
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• v.22 no.3
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• pp.20-31
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• 2018

There was an amazing growth in the korean shipbuilding industry considering the industrial magnitude and the technical level. On the contrary of the growth, there are a number of accidents in the shipbuilding yard. According to the statistic data of the industrial accident in the last 7 years, the number of accidental fatalities in shipbuilding industries are 1.48 ‱ which are over more than doubles of the average in the Korean industries, 0.66 ‱. Thus, through an accident investigation of fire and explosion case during painting work in the tank of the crude oil carrier, it have been tried to diagnose actual conditions in the shipbuilding yards.

• Journal of the Korean Institute of Gas
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• v.22 no.5
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• pp.31-37
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• 2018

The distrust about chemical plant safety have been increased by occurring the major industrial accidents. Chemical plants have become more and more enlarged and sophisticated to increase production amount and decrease cost. So hazard of industrial accidents also have been increased. In this situation, quantitative risk assessment is activated by introducing OCA(Off-site Consequence Analysis). So it is possible to analyze the objective hazard of chemical plant. Currently OCA focus on the end point of hazardous area by fire/explosion/dispersion. But in this case, it is possible to analyze the industrial accident effect to near the chemical plant but hard to consider the actual hazard by frequency and population density. This study analyzes the validity about application of F-N curve to OCA by compare end point with F-N curve about accident.

• Journal of the Korean Institute of Gas
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• v.16 no.5
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• pp.41-46
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• 2012

The flash point the lowest temperature at which the concentration of vapor of the substance in the air reaches the lower flammability limit(LFL), and is one of the most important physical properties used to determine the potential for fire and explosion hazards of industrial materials. The most published flash point data was for pure components and the flash points of the binary solutions that have flammable components, appear to be scarce in the literature. In the present study, the flash points of tert-pentanol+n-decane system were measured by Tag open-cup tester. The measured data were compared with the values calculated by the Raoult's law and the optimization methods based on the Wilson and NRTL equations. The calculated values by optimization methods were found to be better than those based on the Raoult's law.

• Journal of the Korean Institute of Gas
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• v.3 no.2 s.7
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• pp.77-84
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• 1999

The XX company that is handling the class IV hazardous materials, located in Bu-Chon City and the LPG station in front of the XX company which is about 20 meters apart, was chosen as the standard model for this study In carrying out the consequence analysis, PHAST and Super-Chems were used for the study and utilizing the output of the simulation, we have evaluated the consequences throughout the probit analysis and explosion overpressure analysis. In case of Acetone, the effect distance of the damage on facilities-that is the result of radiation heat flux of $37.5kW/m^2$ by TNO model-is 68.51m by PHAST model and 40.93m by Super-Chem model. The risk assessment of the LPG station which is based on the explosion resulted as the analysis of the fire ball showed the diameter 125.2m, the height 206.2m and the duration 11.28sec and the effect distance for the radiant heat flux $37.5kW/m^2$ was 137.0m.

• Journal of the Korean Institute of Gas
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• v.18 no.3
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• pp.44-52
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• 2014

Small petrol stations have great potential for a wide distribution in metropolitan area in which the land value possesses primary installation cost of the facility. The objective of the present study is to propose appropriate facility regulations of small petrol stations in Korea that can be popularly installed in the future in terms of securing safety in addition to serviceability. The hazard analysis and damage prediction from the possible fire and explosion accidents were performed using a software, PHAST v.6.5. As essential components of the facility regulations proposed in this study, the regulations about the refueling lot, maximum capacity of underground tank, location of fixed refueling facilities, height of firewall for small petrol stations were subsequently compared with those for regular-sized petrol stations.

• Journal of the Korean Institute of Gas
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• v.21 no.5
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• pp.56-63
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• 2017

Hydrogen charging station was invested and supported around the world. In this study, the extent of damage caused by VCE in the charging station handling liquefied hydrogen was calculated, and the human and material damage was estimated through the Probit model. In addition The optimal height of vent stack for low temperature hydrogen was set. The damage range is 8.24m in small scale, 14.10m in medium scale, and 22.38m in large scale based on interest overpressure 6.9kPa. In case of death due to pulmonary hemorrhage, 50m of the small and medium scale and 100m of the large scale were injured. Structural damage was 200m in small scale, 300m in medium scale and 500m in large scale. The optimum height of the vent stack is 4.7 m in small scale, 8.8 m in medium scale and 16.9 m in large scale.

• Journal of the Korean Institute of Gas
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• v.24 no.5
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• pp.47-55
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• 2020

Hazardous materials accidents are not limited to the leakage of the material, but if the early response is not appropriate, it can lead to a fire or an explosion, which increases the scale of the damage. However, as the 4th industrial revolution and the rise of the big data era are being discussed, systematic analysis of hazardous materials accidents based on new techniques has not been attempted, but simple statistics are being collected. In this study, we perform the systematic analysis, using machine learning, on the fire accident data for the past 11 years (2008 ~ 2018), accumulated by the National Fire Service. The analysis results are visualized and presented through text mining analysis, and the possibility of developing a damage-scale prediction model is explored by applying the regression analysis method, using the main factors present in the hazardous materials fire accident data.

• Journal of the Korean Institute of Gas
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• v.22 no.2
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• pp.52-58
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• 2018

The flash point is one of the most important properties to characterize fire and explosion hazard of flammable liquid mixture. In this paper, the flash points of ternary liquid mixture, n-nonane+n-decane+n-tridecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and multiple regression analysis. The absolute average errors(AAE) of the results calculated by Raoult's law is $0.6^{\circ}C$. The absolute average errors of the results calculated by multiple regression analysis is $0.4^{\circ}C$. As can be seen from AAE, the calculated values based on multiple regresstion analysis were found to be better than those based on Raoult's law.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.49-54
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• 2018

In the Active Pharmaceutical Ingredient(API) manufacturing company, since the product is produced by the chemical reaction, fire and explosion are frequently occurred in the process of inputting the raw powder as the chemical reaction stage. There are not many studies on safety measures through analysis of cause of accident in the actual chemical reaction stage. In this study, we investigated the heat flow in the boron removal reaction process to investigate the risk in the chemical reaction stage. The study reaction process was performed by using the reaction calorimeter for the products synthesized at the actual raw material in pharmaceutical factory. The risk was estimated by comparing the maximum temperature of the synthesis reaction, which can generate heat due to the failure of cooling in the actual manufacturing process, and the technical temperature. These results are applied to commercial manufacturing sites and safety measures to control the risk of runaway reaction due to reaction heat are suggested.