• Title/Summary/Keyword: 가스 물성치

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Study on Combustion Gas Properties of a Fuel-Rich Gas Generator (연료 과농 가스발생기의 연소 가스 물성치에 관한 연구)

  • 서성현;최환석;한영민;김성구
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.10
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    • pp.56-60
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    • 2006
  • It is essential to predict thermodynamic properties of combustion gas with respect to a propellant mixture ratio for the development of a gas generator for a liquid rocket engine. The present study shows the temperature measurement of exit combustion gas as a function of a mixture ratio through the series of combustion tests of a fuel-rich gas generator with liquid oxygen and Jet A-1. The measurements of dynamic and static pressures, and combustion gas temperatures allowed the estimation of thermodynamic properties like a specific heat ratio, a gas constant, and a constant pressure specific heat of the combustion gas. The comparison of the experimental results with predictions made by interpolation parameters obtained from the modification of the chemical equilibrium code indicates that the interpolation method calibrated using the temperature measurements can be utilized as an effective tool for the initial design of a fuel-rich gas generator.

Study on Combustion Gas Properties of a Fuel-Rich Gas Generator (연료 과농 가스발생기의 연소 가스 물성치에 관한 연구)

  • Seo Seong-Hyeon;Han Yeoung-Min;Kim Sung-Ku;Choi Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.118-122
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    • 2006
  • For the development of a gas generator of a liquid rocket engine, the prediction of thermodynamic properties of combustion gas with respect to a propellant mixture ratio becomes critical. The present study focuses on the temperature measurement of exit combustion gas as a function of a mixture ratio through combustion tests of a fuel-rich gas generator propelled by Lox/Jet A-1. The measurement of combustion dynamic and static pressures allowed indirect estimation of thermodynamic properties like specific heat ratio, gas constant, and constant pressure specific heat. Comparing the results with empirical prediction through an interpolation reveals that the interpolation method calibrated using temperature results can be utilized as an effective tool for the design of a fuel-rich gas generator.

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Corrosion and Mechanical characteristics for 9Cr-1MoVNb Steel under SO2 gas environment (SO2 가스 환경 하에서 9Cr 템퍼드-마르텐사이트강의 부식 및 기계적 특성)

  • Jeong, Gwang-Hu;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.109-109
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    • 2018
  • Cr-Mo 합금강은 고온 환경 하에서 높은 크리이프 강도와 우수한 내식성 때문에 발전설비, 석유 화학, 그리고 해양산업과 같은 여러 산업분야에서 널리 사용되고 있다. 특히, Cr-Mo 강의 내식성은 합금 내 Cr 함량에 크게 의존한다. 이는 고온에서 Cr과 O가 화학적 반응을 일으킴에 따라 보호성의 Cr 산화스케일을 형성하기 때문이다. 그러나 화석연료를 사용하는 발전설비의 경우, $SO_2$가 포함된 강한 부식성의 연소 가스가 배출되며, 이에 노출된 금속의 표면에서는 산화와 황화가 동시에 발생한다. 황화스케일은 산화스케일에 비해 매우 빠르게 성장하며, 그 특성이 매우 취약하기 때문에 황화 환경에서 금속의 내식성 및 기계적 물성치는 보다 크게 저하된다. 따라서 본 연구에서는 화력 발전소의 증기발생용 튜브 재료인 9Cr-1MoVNb 강을 선정하였으며, $SO_2$ 가스 환경 하에서의 부식 및 기계적 물성치 저하 특성을 평가하고자 하였다. 본 연구에서 사용된 9Cr-1MoVNb강의 화학 성분 조성은 0.1 C, 0.38 Si, 0.46 Mn, 0.25 Ni, 8.38 Cr, 0.93 Mo, 0.18 V, 0.09 Nb, 그리고 나머지는 Fe이다. 부식시험은 가공된 미소시험편과 인장시험편을 전기열처리로에 장입한 후, $650^{\circ}C$에서 $N_2+O_2+O_2+SO_2$ 조성의 가스를 분당 50 CC로 흘려주었다. 제작된 시험편에 대한 부식거동은 무게 증가량, optical microscope, scanning electron microsope, 그리고 energy dispersive x-ray spectrum을 통해 평가하였다. 그리고 기계적 물성치 평가를 위한 인장시험은 분당 2mm 변위제어를 통해 실시하였다. 그 결과, 9Cr-1MoVNb 강은 $SO_2$ 가스 환경 하에서 비 보호적인 Fe-풍부상의 산화 스케일층이 두껍게 형성됨에 따라 열악한 내식성을 나타냈다. 그에 따라 기계적 물성치는 저하되는 경향을 나타내었다.

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Prediction of Burnt Gas Properties for Kerosene Fuel-rich Preburner (케로신 연료과잉 예연소기의 연소가스 물성치 예측)

  • Son, Min;Seo, Min-Kyo;Koo, Ja-Ye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.123-126
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    • 2011
  • A Fuel-rich preburner using kerosene fuel is operated in a non-equilibrium condition and a prediction of burnt-gas properties is not easy from a chemical equilibrium analysis. A premixed counter-flow flame analysis was conducted for the prediction of burnt-gas properties. JP10 was selected for a representative kerosene fuel and a non-equilibrium combustion analysis was accomplished in supercritical condition using UC San Diego reaction mechanism. The premixed counter-flow flame was assumed for stationary and stable flame, and the temperature result in present study was overestimated rather than the experimental results from Huzel. From the difference of the temperature result, other properties, heat capacity, specific heat ratio and molecular weight had some differences against the experimental results. Moreover, the present results was more similar to the experimental results than those of the equilibrium analysis.

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Modeling of Non-Equilibrium Kinetics in Gas Generator including Soot Formation (Soot 생성을 고려한 가스발생기의 Kerosene/LOx의 비평형 화학반응 모델링)

  • Yu, Jung-Min;Lee, Chang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.150-153
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    • 2006
  • Gas generator should be adopted either fuel rich or oxidizer rich combustion because of the temperature restriction to avoid any possible thermal damages to turbine blade. This study focuses to model the non-equilibrium chemical reaction of kerosene/LOx with detailed kinetics developed by Dagaut using Perfectly stirred reactor(PSR) assumption. To predict more reliable species fraction and other gas properties, Frenklach's soot model was added to Dagaut's detailed kinetics.

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Material Properties and Welding Procedure of Natural Gas Pipeline (천연가스 주배관의 재료물성 및 용접방안)

  • Kim Woo Sik
    • 한국가스학회:학술대회논문집
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    • 1997.09a
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    • pp.39-44
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    • 1997
  • 한국가스공사에서 건설중이거나 관리중인 천연가스 주배관의 길이는 날로 크게 증가하고 있다. 이배관의 건전성확보를 위한 배관 재료물성 및 용접부위 특성 평가를 다양하게 실시하였다. 그 결과 현재 사용중인 배관은 모재와 각종 용접공정에 의한 용접부위의 기계적 특성이 각종 규격에서 제시하고 있는 권고치를 초과하는 높은 안전성을 보이고 있으며, 금속 조직 및 강도학적인 측면에서 충분한 건전성을 확보하고 있음을 알 수 있었다.

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A study on the analysis of laser arc hybrid plasma in helium gas (헬륨 보호가스 내에서의 레이저 아크 하이브리드 플라즈마의 거동에 관한 해석)

  • 조영태;나석주
    • Proceedings of the KWS Conference
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    • v.43
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    • pp.49-51
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    • 2004
  • 레이저 아크 하이브리드 용접에서 보호가스로 헬륨을 사용하였을 때 레이저에 의해 발생하는 금속 증기가 아크 플라즈마의 거동에 미치는 영향에 관하여 시뮬레이션 하였다. 해석에 필요한 기본적인 물성치들은 헬륨과 금속 증기의 부분압에 따라 비율로서 결정하였고 아르곤을 사용하였을 때와 비교하여 헬륨 플라즈마의 특성을 파악하였다. 또한 보호가스의 종류에 따라 레이저 빔의 흡수율을 계산하여 고옥의 플라즈마가 발생할 때 헬륨 보호가스가 적당함을 보였다.

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Macroscopic High-Temperature Structural Analysis of PHE Prototypes Considering Weld Material Properties (용접 물성치를 고려한 공정열교환기 시제품의 거시적 고온구조해석)

  • Song, Kee-Nam;Hong, Sung-Deok;Park, Hong-Yoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.9
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    • pp.1095-1101
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    • 2012
  • A process heat exchanger (PHE) in a nuclear hydrogen system is a key component that transfers the large amount of heat generated in a very high temperature reactor (VHTR) to a chemical reaction that yields a large quantity of hydrogen. A performance test on a small-scale and a medium-scale PHE prototype made of Hastelloy$^{(R)}$-X is being conducted on in a small-scale nitrogen gas loop at the Korea Atomic Energy Research Institute. Previous research on the macroscopic high-temperature structural analysis of PHE prototypes had been performed using base material properties owing to a lack of weld material properties. In this study, macroscopic high-temperature structural analyses considering the weld material properties were performed and the results were compared with those of a previous study.

Modeling of Non-Equilibrium Kinetics of Fuel Rich Combustion in Gas Generator (농후 연소 가스발생기의 비평형 연소 화학반응 모델링)

  • 유정민;이창진
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.7
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    • pp.89-96
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    • 2006
  • The combustion temperature in gas generator should be kept below around 1,000K to avoid any possible thermal damages to turbine blade by adopting either fuel rich or oxidizer rich combustion. Thus, non-equilibrium chemical reaction dominates in the gas generator. Meanwhile, Kerosene is a compounded fuel mixed with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focus to model the non-equilibrium chemical reaction of kerosene/LOX with detailed kinetics developed by Dagaut using PSR(Perfectly stirred reactor) assumption. Also, droplet evaporation time is taken into account by calculating for the residence time of droplet and by decoupling reaction temperature from the reactor temperature. In Dagaut’s surrogate model for kerosene, chemical kinetics of kerosene consists of 1592 reaction steps with 207 chemical species. The comparison of calculation results with experimental data could provide very reliable and accurate numbers in the prediction of combustion gas temperature, species fraction and other gas properties.

Numerical Analysis on Cooling Characteristics of Oxidizer-Rich Preburner (산화제 과잉 예연소기 냉각 성능 수치 해석)

  • Lee, Seon-Mi;Ha, Seong-Up;Lee, Soo Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.3
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    • pp.67-75
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    • 2013
  • The numerical analysis for the verification of preburner's cooling characteristics applying to kerosene-LOx rocket engine has been fulfilled. The distribution of combustion gas properties in primary combustion zone was calculated by the mixture ratio based on head injector arrangement, the properties of oxygen flowing in wall channels as coolant were applied under real-gas conditions, and multi-phase mixing model was employed to calculate the mixing process of primary combustion zone with liquid oxygen which was used for wall cooling. The results of numerical analysis were compared with the experimental results, hence thermo-physical properties in cooling channels and a combustor could be quantitatively identified.