• Polymer(Korea)
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• v.30 no.4
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• pp.298-304
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• 2006

Blends of poly (acrylic acid-co-maleic acid)(PAM) with poly (vinyl alcohol)(PVA) were obtained by solution blending. The blends were solvent-on to a film to examine thermo-mechanical properties and gas permeability. The transition temperatures $(T_g\;and\;T_m)$ of the blends remained constant regardless of PAM contents. However, the values of enthalpy changes corresponding to melting transition $({\Delta}H_m)$ and initial degradation temperature $({T_D}^i)$ were decreased with increasing PAM content. The values of ultimate strength and initial modulus gave the maximum value at the 12 wt% PAM then decreased with further increase of PAM content up to 15 wt%. To measure the gas permeability of the PVA/PAM blend films, the PVA blend solutions were coated onto both biaxially oriented propylene (BOPP) and poly (ethylene terephthalate)(PET) films. The oxygen transmission rate $(O_2\;TR)$ permeability values mono- tonically decreased with increasing PAM content. However, moisture vapor transmission rate was not affected by PAM content.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.4
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• pp.288-297
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• 2009

A serpentine channel geometry often used in a fuel cell has a strong pressure gradient between adjacent channels in specific regions. The pressure gradient helps some amount of reactant gas penetrate through a gas diffusion layer(GDL). As a result, the overall serpentine flow structure is slightly different from the intention of a designer. The purpose of this paper is to examine the effect of serpentine flow structure on current density distribution. By using a commercial code, STAR-CD, a numerical simulation is performed to analyze the fuel cell with high aspect ratio of active area. To increase the accuracy of the numerical simulation, GDL permeabilities are measured with various compressive forces. Three-dimensional flow field and current density distribution are calculated. For the verification of the numerical simulation results, water condensation process in the cathode channel is observed through a transparent bipolar plate. The result of this study shows that the region of relatively low current density corresponds that of dropwise condensation in cathode channels.

• Proceedings of the Membrane Society of Korea Conference
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• 1994.10a
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• pp.24-25
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• 1994

고분자 분리막을 통한 메탄과 이산화탄소의 분리는 천연가스에서 불순물로 작용하는 이산화탄소를 분리시켜 천연가스의 순도를 향상시키는데 활용할 수 있으며, 바이오가스나 제철소 폐가스로부터의 이산화탄소의 분리, enhanced oil revovery 공정에서의 이산화탄소의 분리, 그리고 지구 온난화의 원인이 되는 대기중의 이산화탄소 농도의 감소등에서 활용될수 있다. 이러한 분리막 공정은 여러 혼합기체에 대해 단순하고 간편하며 에너지 소비가 적다는 장점에 의해 기체분리에 효과적이고 응용성있는 공정으로 대두되고 있는데, 그 중에서도 분리막의 투과도(Permeability)와 선택도(Selectivity)를 동시에 높일수 있는 새로운 막재료의 개발에 관한 연구가 활발히 진행되고 있다. 이를 위해 고분자 구조를 화학적으로 변화시키는데, 이 경우에는 고분자의 구조 변화와 투과특성간의 관계를 밝히는 것이 매우 중요하다.

• Tunnel and Underground Space
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• v.27 no.1
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• pp.26-38
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• 2017

In this study, bedding rock permeability was measured using Berea sandstones with three different beddings. The fracture permeability was also measured using tight sandstone with two different fracture regimes considering in-situ stress conditions. The Berea sandstone with vertical, horizontal and non-bedding was used to analyze evolution of permeability upon in-situ stress conditions. In order to describe applied effective stress around rock in underground, the triaxial pressure cell & hydrostatic pressure cell was designed and permeability experiments were performed with controlled axial and confining pressures. The measurement of permeability was conducted by increasing and decreasing effective stress. The permeability of non-bedding rock sample is the most sensitive to applied stress conditions and fracture permeability of tight sandstone increases with fracture treatment with proppant.

• Membrane Journal
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• v.14 no.4
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• pp.320-328
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• 2004

Ionomer-Clay hybrid membranes were prepared by melt intercalation method with twin extruder. MMT was intercalated or exfoliated by the ionomer and it was confirmed by X-ray diffraction method. D-spacing of the characteristic peak from MMT plate in WAXD was moved and diminished. Gas permeability, mechanical properties and thermal properties of the ionomer-clay hybrid membranes were investigated. Gas permeability through the ionomer-clay hybrid membranes decreased due to increased tortuosity made by intercalation of clay in Ionomer.

• Membrane Journal
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• v.15 no.1
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• pp.62-69
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• 2005

SEBS-clay hybrid membranes were prepared by melt intercalation method with internal mixer. In the hybrid, the amount of clay content was fixed to 5 phr. MMT was intercalated or exfoliated by the ionomer and it was confirmed by X-ray diffraction method. D-spacing of the characteristic peak from MMT plate in SAXD was moved and diminished. Gas permeability, mechanical properties and thermal properties of the SEBS-clay hybrid membranes were investigated. Gas permeability through the SEBS-clay hybrid membranes decreased due to increased tortuosity made by intercalation of clay in SEBS.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.18 no.5
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• pp.1-8
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• 2019

Breath analysis using a portable device is better than the classical breath analysis system in terms of installation and operation. There is an increasing need to develop cost-effective equipment for testing gas sensors from the viewpoint of functionalities that can be applied applicable to portable devices. In the present study, an economical gas chamber for in-situ gas measurement is implemented with a single gas chamber without using expensive gas storage and control equipment; the gas response characteristics are analyzed using the above-described chamber. The main features of the implemented gas chamber are simple injection procedure, improved gas diffusion, easy measurement and cleaning, support for low-power mode measurement function for portable devices, and open source platform. Moreover, an analysis of gas response characteristics based on changes in sensor voltage show that the sensitivity and 90% response time are affected by the sensor voltage. Furthermore, the sensitivity graph has an inflection point in a specific range. The gas sensor applied in this study showed fast response speed and high sensitivity for sensor voltages of 3.0-3.5 V, regardless of the concentration of acetone gas, the target gas used in this study.

• Economic and Environmental Geology
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• v.46 no.4
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• pp.279-289
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• 2013

The most critical factor in developing coalbed methane(CBM) reservoir is absolute permeability. Both productivity and economics of the CBM depend on the absolute permeability. The methods to estimate it are core analysis and well test. However, absolute permeability determined by core analysis cannot be a good representative of CBM reservoir. Therefore, it is generally estimated by well test. In this study, well test methods applicable of CBM reservoir were classified with their characteristics. Merits and demerits of each well tests were also analyzed. Based on those parameters, design considerations and procedures of well test were derived. After each well tests was performed, the procedure of well test interpretations to estimate reservoir properties such as absolute permeability and skin factor was presented.

• Journal of Adhesion and Interface
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• v.14 no.4
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• pp.192-196
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• 2013

In this study, a series of bi-axially oriented films based on homo polypropylene (PP) and hydrocarbon resin (HCR) modified PP were prepared to investigate their mechanical properties, optical properties, permeability to gases and water vapors and shrinkage ratio. Hydrogenated dicyclopentadiene (DCPD) resin and hydrogenated C9 resin were used as HCR in this study. Bi-axially oriented polypropylene (BOPP) films made with PP/HCR blends showed better mechanical properties (higher Young's modulus), better optical properties (lower haze), lower permeability to gases and water vapors and increased shrinkage ratio than BOPP films made with homo-PP. Hydrogenated DCPD resin and hydrogenated C9 resin showed similar contribution to the improvement in mechanical properties and optical properties of BOPP films, but there are a differences in permeability to gases and water vapors and shrinkage ratio.

• Tunnel and Underground Space
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• v.23 no.3
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• pp.169-179
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• 2013

Well testing in unconventional reservoirs, such as tight or shale gas formations, presents considerable challenges. It is difficult to estimate the reservoir properties in ultra-low permeability formation because of poor inflow prior to stimulation and excessive test duration. Moreover, radial flow may not develop in hydraulically fractured horizontal wells. For these reasons, the cost of test is high and the accuracy is relatively low. Accordingly, industry is turning to an alternate testing method, diagnostic fracture injection test (DFIT), which is conducted prior to the main hydraulic fracture treatments. Nowadays, DFIT are regarded as the most practical way to obtain good estimates of reservoir properties in unconventional reservoirs. Various methods may be used for interpreting DFIT data. This paper gives an explanation of those methods in detail and examines three actual field data. These show how various analysis methods can be applied to consistently interpret fracture closure pressure and time, as well as before and after closure flow regimes and reservoir properties from field data.