• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.11
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• pp.749-757
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• 2017

To cope with the development of alternative fuels and international environmental regulations, this study provides a numerical analysis of the effects of composition and temperature changes of n-decane and ethanol on auto-ignition characteristics. CHEMKIN-PRO is used as the analysis program and the LLNL model is used as the reaction model. The numerical results show that the ignition delay time increases as the mole fraction of ethanol increases for temperatures below 1000 K, where low temperature reactions occur. Because of the high octane number of ethanol, the high percentage of ethanol delays the increase in the concentration of OH radicals that cause ignition. The oxygen concentration in the mixture is changed to apply the exhaust gas recirculation and a numerical analysis is then performed. As the oxygen concentration decreases, the total ignition delay time increases because the nitrogen gas acts as a thermal load in the combustion chamber.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.6
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• pp.641-648
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• 2011

Off-gases emitted from the anode of a molten carbonate fuel cell (MCFC) at high temperatures for power generation are used as fuel in catalytic combustion. The heat generated in the catalytic combustor is utilized as the heat for the endothermic reaction required for steam reforming. Among the various operational conditions of the integrated reactor, we varied the inlet gas compositions of the catalytic combustor according to fuel utilization in the MCFC and the ratio of steam to carbon in the reformer. Subsequently, the thermal behaviors and reaction characteristics of the integrated reactor were investigated experimentally. The fundamental data from this experimental study will be useful for the design and fabrication of a more practical integrated reactor in the future.

• Applied Chemistry for Engineering
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• v.28 no.2
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• pp.186-192
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• 2017

In this study, water in oil (W/O) emulsion fuel was prepared with surfactant mixture of OIMS90 and NP12 by varying ratio of water to bunker-C oil, surfactant concentration and composition, emulsification time, stirring intensity, temperature and mixing time. Diesel engine performance and exhaust emissions were measured and analyzed with prepared emulsified fuel and compared with those measured using bunker Coil. The results indicated that bunker C emulsion fuel stabilized by surfactant mixture of OIMS90 and NP12 is efficient in reducing emissions of particulate matter, $NO_2$, CO, $CO_2$ and $SO_2$. The biggest reduction in exhaust emission was achieved by using emulsion fuel prepared by OIMS90/NP12 = 4 : 6, 500 ppm of total surfactant concentration and 10% water content at $80^{\circ}C$. Boiler efficiency test measured with emulsion fuel showed excellent energy efficiency compared with bunker C oil.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.43-49
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• 2009

A catalyzed diesel particulate filter (CDPF) causes the progressive increase in back pressure of an exhaust system due to the loading of soot particles. To minimize pressure drop which is generated by CDPF, the filter should be regenerated when it collects a certain quantity of soot. It is important to know characteristics of regeneration of CDPF with various of exhaust gas temperatures and compositions. The oxidation of HC in DOC leads to increase gas temperature of DOC downstream. The increased gas temperature by DOC has an positive effect on CDPF regeneration. This study presents characteristics of regeneration of CDPF with DOC according to various gas composition, such as HC and $O_2$ concentration. The test-rig is used to control each gas composition and temperature during regeneration of CDPF. Experimental results indicate that the increased concentration of $O_2$ regenerates DPF more actively. With increasing HC concentration, the gas temperature of CDPF upstream increased due to more oxidation of HC. But excessive supply of HC leads to decrease of $O_2$ concentration in the CDPF, which makes it hard to regenerate CDPF.

• Journal of the Korean GEO-environmental Society
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• v.6 no.4
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• pp.27-35
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• 2005

A case study of the assessment for environmental stabilization in open dumping landfill site was carried out physical composition, total solid, moisture, and landfill gas(LFG) analysis in landfill site. The result of physical ratio were represented combustibles 23.64% and incombustibles 76.36%, TS 77.69%, VS 74.24%, FS 25.75%. The biodegradable organic matters were almost degraded and the result of the landfill gas showed that the $CH_4$ gas were measured as 4.5%. As the result of the assessment on the open dumping landfill it appears that this landfill is stabled for the maturation phase and formation $CO_2$ concentration lower than 15%.

• Journal of the Korean Institute of Gas
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• v.14 no.4
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• pp.1-5
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• 2010

Many sorts of fatal accidents like explosion or fire caused by gas leakage have become a social issue with the increasing use of harmful chemicals in laboratories in universities and enterprise-affiliated research institutes in Korea. Importance of safety management has been emphasized and it made Act on the Establishment of Safe Laboratory Environment enacted not only to protect lives and bodies of people working in laboratories in universities and enterprise-affiliated research institutes but also to make pleasant experimental atmosphere. Safety management system has been built and periodical checkups and safety diagnosis have been implementing in universities and enterprise-affiliated research institutes to prevent such accidents. However, in spite of those actions, continuous accidents make analysis of root cause essential. This study will show results of analysis on incidents and accidents occurred in laboratories in universities and enterprise-affiliated research institutes using Root Cause Analysis Method and propose the direction of safety management.

• Membrane Journal
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• v.22 no.1
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• pp.1-7
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• 2012

We make a studyof the hydrogen permeability and chemical stability of $Nb_{56}Ti_{23}Ni_{21}$ metal alloy membrane. For this purpose, we produced the $Nb_{56}Ti_{23}Ni_{21}$ membrane which has 10 mm diameter and 0.5 mm thick, and experiment the hydrogen transport properties under two kinds of feed gas ($H_2$ 100%; $H_2$ 60% + $CO_2$ 40%) at $450^{\circ}C$C with variation of absolute pressure.The maximum hydrogen permeation flux was $5.58mL/min/cm^2$ in the absolute pressure 3 bar under pure hydrogen. And each case of feed gases about gas composition, the permeation fluxes were satisfied with Sievert's law, and the hydrogen permeation flux decreased with decrease of hydrogen partial pressure irrespective of temperature and pressure. After permeation test, we experiment the stability and durability of $Nb_{56}Ti_{23}Ni_{21}$ alloy membrane for carbon dioxide by XRD analysis.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.49-56
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• 2021

Liquefied Petroleum Gas is divided into liquefied gases containing propane (C₃H₈) and butane (C₄H₁₀). The quality of LPG varies greatly depending on the composition of the mixture, so it is important to measure the composition accurately. It is difficult to determine the composition of the mixture because liquid and gas coexist at room temperature. Therefore, the uncertainty in determining the concentration of hydrocarbons by component is high, and there are many problems that differ from the actual content standard. Therefore, it is necessary to develop a mixed liquid propane standard gas for the composition and accurate concentration of hydrocarbon substances. Mixed liquid propane standard gas is manufactured into bellows-type constant-pressure cylinders by ISO-6142 (2015). The homogeneity of the four standard gases manufactured was confirmed to be GC-FID. The manufacturer's uncertainty of expansion was 0.01 % to 0.30 % and homogeneity was 0.03 % to 0.25 %. In this mixed liquid propane standard gas, the relative expansion uncertainty of weight method, manufacturing consistency, cylinder adsorption and long-term stability was developed within 0.26 %-1.3 9% (95% of confidence level, k=2).

• Journal of the Korean Electrochemical Society
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• v.18 no.1
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• pp.31-37
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• 2015

Composition-controlled ternary components chalcogenides germanium tin sulfide ($Sn_xGe_{1-x}S$) nanoparticles were synthesized by a novel gas-phase laser photolysis reaction of tetramethyl germanium, tetramethyl tin, and hydrogen sulfide mixture. Subsequent thermal annealing of as-grown amorphous nanoparticles produced the crystalline orthorhombic phase nanoparticles. All these composition-tuned nanoparticles showed excellent cycling performance of the lithium ion battery. The germanium sulfide nanoparticles exhibit a maximum capacity of 1200 mAh/g after 70 cycles. As the tin composition (x) increases, the capacity maintains better at the higher discharge/charge rate. This novel synthesis method of tin germanium sulfide nanoparticles is expected to contribute to expand their applications in high-performance energy conversion systems.

• Journal of the Korea Organic Resources Recycling Association
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• v.15 no.3
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• pp.90-96
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• 2007

Modern waste management units, so-called "landfills" protect human health and environment from hazardous leachate and gas. Accordingly, it must be constructed with a bottom liner system that includes a gas collection layer. Leachate is the contaminated liquid that drains from the waste material pollutes ground water. For this reason. bottom liner system must have durability and low hydraulic conductivity (in case of compacted clay liner, no more than $1{\times}10^{-7}cm/sec$ ). P county in Kangwon province constructed a solid waste landfill with bottom liner system. In this study. it is mainly introduced that the test results on construction and quality control of bottom liner system by "Multiple composite liner construction technology", which is selected for bottom liner system in P solid waste landfill.