• Title/Summary/Keyword: 가속노화

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A Study on the Storage Life Estimation Method for Applying Gamma Process Model to Accelerated Life Test Data (가속수명시험 자료에 감마 과정 모델을 적용한 저장 수명 예측 기법 연구)

  • Park, Sungho;Kim, Jaehoon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.3
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    • pp.30-36
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    • 2013
  • This paper presents a method to estimate a storage life for loss of stabilizer content as storage periods using accelerated life test data. The estimate of storage life based on deterministic accelerated life test and degradation data cannot describe a condition distribution and storage life distribution. Previously, the method to show the condition distribution and storage life distribution by using gamma process has been studied. But it has limitation because it is impossible to collect the deterioration data at initial production phase. The estimated storage life presented by this study shows the similar value to previous studies and the method can describe the condition distribution and storage life distribution. So, the estimation method studied in this paper can be used for a life cycle management about deterioration of propellant for propulsion unit or components of missile, too.

Study on a screening method of retired Lithium Ion battery cells for recycling (폐 리튬이온 배터리 셀의 재활용을 위한 스크리닝 방식 고찰)

  • Lee, Chun-Gu;Park, Joung-Hu;Lee, Seong-Jun;Kim, Jong-Hoon
    • Proceedings of the KIPE Conference
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    • 2018.07a
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    • pp.225-227
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    • 2018
  • 일반적으로 리튬이온은 배터리들은 각 배터리마다 고유의 전기화학적 특성을 갖고 있으며 이러한 특성들로 인해서 직렬 또는 병렬로 패키징 되어서 팩으로 사용 될 때 각 셀 간의 전압 불균형이 발생하게 된다. 셀 벨런싱 회로 같은 셀 간 불균형을 회복시켜주는 기능이 없다면 배터리 팩 내의 셀 간 전압 불균형은 시간이 지남에 따라 더 커지게 되고 이는 배터리 팩의 노화를 가속 시키거나 배터리 팩의 성능을 저하시키는 원인이 된다. 이는 폐 리튬이온 배터리 팩을 재활용하는데 있어서도 반드시 고려해야하는 사항으로서 재활용 팩의 사용시간에 영향을 끼칠 수 있다. 위의 문제를 극복하기 위해서는 배터리 팩을 만들기 전에 스크리닝을 통해서 전기화학적 성분이 유사한 배터리들을 팩으로 만드는 것이 필요하다. 일반적으로 프레시 배터리의 용량은 거의 비슷하기 때문에 프레시 배터리 용량은 프레시 배터리를 스크리닝 하기 위한 많은 기준들 중에서 가중치가 크지 않지만 폐 리튬이온 배터리들은 각 배터리마다 고유의 전기화학적 특성을 갖을 뿐만 아니라 각 배터리마다 상이한 배터리 용량을 갖고 있기 때문에 각 배터리의 용량에 프레시 배터리를 스크리닝 할 때보다 큰 가중치를 두어 스크리닝 할 필요가 있다. 본 논문에서는 같은 전류 프로파일로 노화된 배터리 팩 내의 셀들의 전기화학적 특성을 분석하여 폐배터리 셀들을 재활용하기 위한 스크리닝 방법에 대해서 고찰한다.

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Improvement of Bonding Process and Bond Strength of HTPB Propellant/Liner using a Polymeric Curative (고분자 경화제를 사용한 라이너와 HTPB 추진제의 접착력 및 접착공정 개선)

  • Jeong Byung-Hun;Seo Tae-Seok;Hong Myung-Pyo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.413-416
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    • 2005
  • The study has been performed on the improvement of bonding process and bond strength of HTPB propellant and liner using a polymeric curative. In case of liner using polymeric curative prepared from reaction of HTPB and TDI, migration of curative was decreased at bond interface. So EPDM insulation sanding and Desmodur RE coating process could be omitted in motor case preparation and bond strengths between the HTPB propellant and liner were increased. Also deterioration phenomena of bond strength could not be observed in accelerated aging test.

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The Effects of Physical Aging of PSF/AS4 Laminate on Fatigue (PSE/AS4 복합재료의 가속노화가 피로강도에 미치는 영향)

  • Kim, Hyung-Won
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.39-44
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    • 2005
  • The effects of aging of PSF/AS4 laminates on fatigue was studied using the new energy release rate analysis. The analysis by the variational mechanics has been useful in providing fracture mechanics interpretation of matrix microcracking in cross-ply laminates. This paper describes the changes of the critical energy release rate (microcracking toughness) according to the aging period under fatigue loading. The master plot by modified Paris-law gives a characterization of a material system's resistance to microcrack formation. PSF $[0/90_{s}]_{s}$ laminates were aged at four different temperature based on the glass transition temperature for 0 to 60 days. At all temperatures, the toughness decreased with aging time. The decrease of the toughness at higher temperature was faster than at lower temperature. To assess the effects of aging on fatigue, the unaged laminates were compared with the laminates which had been aged for 60 days at 170$^{\circ}C$ near 180 $^{\circ}C$ t$_g$. The slope of dD/dN versus ${\Delta}G_m$. of the aged laminates was lower than that of the unaged laminates. There was a significant shift of the aged data to formation of microcracks at the lower values of ${\Delta}G_m$.

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Improvement of Bonding Process and Bond Strength of HTPB Propellant/Liner using a Polymeric Curative (고분자 경화제를 사용한 라이너와 HTPB 추진제의 접착력 및 접착공정 개선)

  • Jeong Byung-Hun;Seo Tae-Seok;Hong Myung-Pyo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.2
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    • pp.110-114
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    • 2006
  • The study has been performed on the improvement of bonding process and bond strength of HTPB propellant and liner using a polymeric curative. In case of liner using polymeric curative prepared from reaction of HTPB and TDI, migration of curative was decreased at bond interface. So EPDM insulation sanding and Desmodur RE coating process could be omitted in motor case preparation and bond strengths between the HTPB propellant and liner were increased. Also deterioration phenomena of bond strength could not be observed in accelerated aging test.

A Study on Chemical Structure of White Smoke Grenade by Aging (가속노화에 따른 백색 연막수류탄(M8)의 화학적 구조 변화에 관한 연구)

  • Park, Jang-Ho;Cho, Min-Su;Kim, Young-Dae;Lee, Byung-Teak;Chang, Il-Ho
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.6
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    • pp.1186-1191
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    • 2011
  • Composition which was used as a white smoke grenade consists of Aluminium(Al), Hexachloroethane(HCE) and Zinc Oxide(ZnO), etc. there is a possibility of misfire due to long term storage and there are very few reports on the mechanism behind misfire. In this study, an experimental method known as accelerated degradation testing is used to investigate the chemical mechanism resulting in misfire. The mechanism of chemical change during long term storage was analyzed with XRD and FT-IR. Analysis results suggest that a part of HCE consisting of the white smoke grenade disappeared and the other part was combined into $ZnCl_2$, $AlCl_3$, as a recycled intermediate product under closed system.

Effect of Cure System on the Life-time of Hydrogenated NBR O-ring using Intermittent Compression Stress Relaxation(CSR) (간헐 압축응력 완화를 이용한 가교 구조가 hydrogenated NBR 오링의 수명에 미치는 영향 연구)

  • Lee, Jin-Hyok;Bae, Jong-Woo;Kim, Jung-Su;Hwang, Tae-Jun;Choi, Yu-Seok;Baek, Kwang-Sae;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.144-151
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    • 2011
  • Intermittent CSR testing was used to investigate the degradation of a hydrogenated NBR(HNBR) O-rings, and also the prediction of its life-time. The cure system of HNBR O-ring was controlled as sulfur cure and peroxide cure system. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. The testing allowed observation of the effects of friction, heat loss, and stress relaxation by the Mullins effect. Degradation of O-rings by thermal aging was observed between 100 and $120^{\circ}C$. In the temperature range of $100-120^{\circ}C$, O-rings showed linear degradation behavior and satisfied the Arrhenius relationship. The activation energy of HNBR-S was about 70.6 kJ/mol. From Arrhenius plots, predicted life-times of HNBR-S O-ring were 31.1 years and 33.7 years for 50% and 40% failure conditions, respectively. In case of HNBR-P, the activation energy was about 72.1kJ/mol, and predicted life-times were 34.0 years and 36.5 years for 50% and 40% failure conditions, respectively. The peroxide cure system showed slower degradation rate and higher activation energy than the sulfur cure system.

Equipment Qualification of Class 1E Safety-Reeled Random Wound NEMA Electric Motor for Nuclear Power Plants (원자력발전소용 안전등급 저압유도전동기의 기기검증)

  • Kim, J.;Lee, I.W.;Hur, I.G.;Choi, B.W.
    • Proceedings of the KIEE Conference
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    • 2001.04a
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    • pp.63-66
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    • 2001
  • 원자력발전소는 지진과 같은 자연재해나 극한 운전조건에서 방사능물질이 외부로 누출되는 것을 방지하도록 설계 되어야한다. 따라서 이와 관련된 안전등급기기는 원전설비의 정상운전조건뿐 아니라 원전설계기준 사고조건(DBE, Design Basis Events)에서도 그 안전성 관련 기능이 검증되어야 한다. 본 연구에서는 국내 원자력 발전소의 다양한 환경조건을 만족하며 엄격한 기기검증요건에 따라 당사가 수행한 안전등급(Class 1E) 저압 유도전동기의 개발사례를 중심으로 방사능노출시험, 가속열노화해석 및 시험, 내진해석 및 시험으로 구성되는 기기검증의 절차와 방법을 제시하였다.

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Useful lifetime prediction of rail-pad by using the accelerated heat aging test (가속 열노화시험을 통한 레일패드 사용수명예측)

  • Woo, Chang-Su;Park, Hyun-Sung;Choi, Byung-Ik;Yang, Sin-Chu;Jang, Sung-Yep;Kim, Eun
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.1010-1015
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    • 2009
  • Rail-pad is an important and readily replaceable component of a railway track, as it is the elastic layer between the rail and the sleeper. Characteristics and useful lifetime prediction of rail-pad was very important in design procedure to assure the safety and reliability. In order to investigate the useful lifetime, the accelerate test were carried out. Accelerated test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the acceleration test, several useful lifetime prediction for rail-pads were proposed.

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Life-Time Prediction of HNBR Diaphragm in Oil Reservoir (유압구동장치 동력원용 고무 다이아프램 저유기의 수명 예측 연구)

  • Kim, Sol A
    • Journal of Drive and Control
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    • v.18 no.2
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    • pp.32-37
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    • 2021
  • The piston reservoir is mainly used in hydraulic blow-down system for aerospace engineering. The reservoir is heavy due to both hydraulic cylinder and piston in pressurization. The positive expulsion tank with rubber diaphragm has been mostly applied propellant and fuel tank at low pressure to satellites. To reduce weight, the reservoir that can be used at high pressure with rubber diaphragm was developed. In this research, the prediction of life-time for the rubber diaphragm was implemented through an accelerated life test, as a part of development of new reservoir. Also, the diaphragm was stored in an temperature chamber at the same condition as and operation with hydraulic oil. As a result, the life-time for a rubber diaphragm was successfully evaluated via Arrhenius law and Time-Temperature Superposition based on failure times over temperatures in the accelerated test.