• Title/Summary/Keyword: 가소

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Reevaluation of hydrogen gas dissolved cleaning solutions in single wafer megasonic cleaning

  • Kim, Hyeok-Min;Gang, Bong-Gyun;Lee, Seung-Ho;Kim, Jeong-In;Lee, Hui-Myeong;Park, Jin-Gu
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.34.1-34.1
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    • 2009
  • 1970년대 WernerKern에 의해서 개발된 RCA 습식 세정 공정은 이후 메가소닉 기술 개발과 더불어 현재까지반도체 세정 공정에서 필수 공정으로 알려져 있다. 하지만, 반도체패턴의 고집적화 미세화에 따라 메가소닉을 기반으로 하는 세정기술은 패턴 붕괴 및 나노 입자 제거의 한계를 드러내면서 난관에 봉착하고 있으며, 특히, 기존의 Batch식에서 매엽식으로 세정 방식이 전환은 새로운 개념의 메가소닉 기술 개발을 요구하게 되었다. 메가소닉을 사용한습식 세정공정은 메가소닉에 의한 캐비테이션 효과 (Cavitation Effect)에 따른 충격파 및음압 (Acoustic Streaming)에 의한 입자제거를 주요 메커니즘으로 한다. 메가소닉 주파수와 Boundary Layer 두께는, $\delta=\surd(2v/\omega)$($\delta$=두께, v=유체속도), $\omega=2{\pi}f$ (f=주파수), 으로 표현할 수 있다. 위의 식에 따르면, 메가소닉을 이용한 세정공정에서 주파수가 높아질수록 Boundary Layer의 두께가 감소하며, 이는제거 가능한 입자의 크기가 작아짐을 의미하며, 다시말해, 1 MHz 보다 2 MHz 메가소닉 세정장비에서 미세 입자 세정에 유리함을 예상할 수 있다. 본연구에서는 매엽식 세정장비를 사용하여, 1MHz 및 2MHz 콘-타입 (Cone-Type) 메가소닉 장치를 100nm이하 세정 입자에 대한 입자 제거효율을 평가하였다. 입자 제거 효율을 평가하기 위하여, 표준 형광입자(63nm/104nm 형광입자, Duke Scientifics, USA)를각각 IPA에 분산시킨 후, 실리콘 쿠폰 웨이퍼 ($20mm{\times}20mm$)를 일정시간 동안 Dipping 한 후, 고순도 질소로 건조시켜 오염하였다. 매엽식 세정장비(Aaron, Korea)에 1MHz와 2MHz의 콘-타입메가소닉 발진기 (Durasonic, Korea)를 각각 장착하였다.입자 오염 및 세정 후 입자 개수 측정 및 오염입자의 Mapping은 형광현미경 (LV100D, Nikon, Japan)과 소프트웨어(Image-proPlus, MediaCybernetics, USA)를 사용하여 평가하였으며, Hydrophone을 사용하여 메가소닉에서 발생되는 음압의 균일도를 각 조건에서 측정하였다. 각각의 세정공정은 1MHz와 2MHz 메가소닉 발진기 각각에서 1W, 3W, 5W 파워로 1분간 처리하였으며, 매질을 초순수를 사용하였다. 104nm 형광 입자는 1MHz 와 2 MHz 메가소닉 세정기와 모든 세정 공정조건에서 약 99%의 세정효율인 반면, 63nm 형광입자의 경우는 전체적인세정 결과가 80% 대로 감소하였다. 본 연구를 통하여, 입자크기의 미세화에 따른 입자제거효율이 크게 감소 하는 것을 확인할 수 있으며, 기존 Batch식 메가소닉 대비 단시간 및 낮은 전압에서 동일 혹은높은 세정 효율을 얻었다. 다만, 1MHz와 2MHz 메가소닉에서의 세정력은 큰 차이를 관찰 할 수 없었는데, 주파수변화에 따른 세정효율 측정을 위하여 미세 입자를 사용한 추가 실험이 필요 할 것이다.

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Quantitative Evaluation of Plasticity and Extension for Extruding Body (압출성형용 소지의 가소성과 연신율의 정량화)

  • Bae, Won-Tae;Shin, Dong-Woo
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1048-1054
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    • 2002
  • When forming the ceramic body with plastic mass, it is needed that a quantitative testing method for plasticity, not only to evaluate the plasticity of a body, but also to control it within limits. Although many testing instruments were introduced, but no handy testing instrument for the plasticity quantitatively has been developed. In this study, modified vicat needle was designed to handily evaluate the plasicity of extruding bodies for honeycomb. The plasticity of three plastic masses was tested with this equipment. Columned needle with 2 mm diameter was adopted to measure the resistance for deformation and spherical needle with 9.5 mm diameter was adopted to measure the amount of deformation before cracking. The plasticity of three tested bodies were clearly distinguished quantitatively each other and the testing results were helpful to evaluated the workability of theses bodies. Probably, it is possible to evaluate the plasticity of various ceramic bodies with this apparatus, if suitable diameters of columns and spheres are selected.

A Trend and Market in Eco-friendly Plasticizers: Review and Prospective (친환경 가소제의 시장과 동향)

  • Oh, Eunyoung;Kim, Baek-hwan;Suhr, Jonghwan
    • Composites Research
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    • v.35 no.4
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    • pp.232-241
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    • 2022
  • Plasticizers are chemical additives added to polymers to have a desirable effect on mechanical properties such as processability and ductility. In this paper, we explore the use and market of eco-friendly plasticizers that can replace phthalate-based plasticizers that have been traditionally used in the plastics market. Bio plasticizers are derived primarily from biomass sources, including agricultural products, by-products and wastes. Regardless of the source of biomass, an ideal eco-friendly plasticizer should be non-toxic, have high resistance to volatilization, extraction, and migration, have good compatibility and compatibility, and be economical. The global bio plasticizer market is expected to reach USD 2.1 billion by 2030 from USD 1.3 billion in 2020, growing at a CAGR of 5.31% from 2021 to 2030.

Plasticity of clay bodies containing bottom ashes from power plant (석탄 바닥재를 함유한 점토 소지의 가소성에 관한 연구)

  • Jeon, Hye-Jin;Kim, Yoo-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.5
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    • pp.223-230
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    • 2007
  • Plasticity of clay bodies containing bottom ashes(BA) and small portion of other wastes was investigated. Plasticity indices of clay bodies using Atterberg limits were measured. It was confirmed that the plasticity indices could be applicable in actual forming process by extrusion. The forming possible compositions were found by changing the contents of water, bottom ash, stone dust, and sewage sludge. The relationship between the plasticity and physical properties of the aggregate green body was also investigated. The compositions for extrusion forming can be expected by measured the plasticity indices and these results were confirmed by real extrusion process. There is also strong relationship between the plasticity indices and the property of aggregate green body.

Polyvinylchloride Plasticized with Acetylated Monoglycerides Derived from Plant Oil (아세틸화 모노글리세라이드계 가소제 합성 및 PVC 가소성능에 관한 연구)

  • Lee, Sangjun;Yuk, Jeong-Suk;Kim, A-Ryeon;Choung, Ji Sun;Shin, Jihoon;Kim, Young-Wun
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.42-49
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    • 2017
  • To replace phthalate plasticizer for PVC, acetylated monoglyceride (AMG) plasticizers were prepared from plant oil and their plasticization effects were also investigated. Transesterification of coconut oil by glycerol followed by acetylation with acetic anhydride gave AMG-CoCo (Coco : Coconut Oil). In addition, AMG-GMO (GMO : Glycerol monooleate) and AMG-GMO-Epoxy were synthesized by acetylation and epoxidation with glycerol monooleate. It was found that the thermal stability of AMG plasticizers increased in the following order: AMG-GMO-Epoxy > AMG-GMO > AMG-CoCo and all three plasticizers were thermally more stable than those of common petroleum-based plasticizer DOP (Dioctyl phthalate). The tensile strain values of the PVC containing AMG compounds were ca. 770~810%, while tensile strength values were ca. 19~22 MPa, which were higher than those of PVC containing DOP. DMA (Dynamic Mechanical Analysis) results showed that the miscibility of AMG-GMO-Epoxy in PVC was excellent and the $T_g$ of PVC containing AMG-GMO-Epoxy at 50 phr decreased down to $24^{\circ}C$. Finally, the leaching experiment result showed that the weight loss values of PVC containing AMG-GMO and AMG-GMO-Epoxy at 50 phr were as low as 2 and 1%, respectively, indicating that they have high water migration resistance. The above findings suggested that AMG-GMO-Epoxy could be one of plant oil-based PVC plasticizers to replace DOP.

Study on Degradation Characteristics and Chemical Cleaning Methods of Plasticized PVC for Conservation of Plastic Artifact (연질 PVC 작품 보존을 위한 가소제 종류별 열화 특성 및 화학적 세척법 연구)

  • Lee, Na Ra;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.35 no.2
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    • pp.159-168
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    • 2019
  • Plasticizers, which are added to plastics, can cause exudation, which means that the plasticizer comes out from surface of the plastics. This causes the surface of plastic artworks to become sticky, and this allows dust and pollutants to become attached to the surface. Therefore, in this study, the degradation characteristics and chemical cleaning methods of each type of plasticizer are evaluated using PVC specimens. To evaluate the degradation characteristics and chemical cleaning methods, microscopic observation, chromaticity and weight measurement, and FT-IR spectroscopy were performed. The results showed that PVCs containing different plasticizers have different degradation patterns. Especially, the PVC containing TOTM showed discoloration and exudation. In the evaluation of the chemical cleaning methods, ethyl alcohol and KOH solution showed good effects, but their stability was not good. Surfactant was found to have a good cleaning effect and stability as a cleaner for exudated plasticizers.

Effect of Plasticizer on Physical Properties of Poly(vinyl acetate-co-ethylene) Emulsion (Poly(vinyl acetate-co-ethylene) 에멀젼 물성에 대한 가소제 효과)

  • Choi, Yong-Hae;Lee, Won-Ki
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.459-463
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    • 2009
  • In this study, physical properties of poly(vinyl acetate-co-ethylene) (VAE) emulsion were investigated by adding different amounts of di-butyl phthalate (DBP) which is a common plasticizer of VAE. The glass transition temperature $(T_g)$ of the dried plasticized VAE emulsion film, which measured by Differential Scanning Calorimeter, was decreased with increasing the DBP contents while the viscosity of the plasticized VAE emulsion was increased with the DBP contents. These results suggest that the plasticizer in the dried VAE film can prevent the strong interaction between chains, resulted by the decrease of $T_g$. In the emulsion, however, the particle sizes were swelled by the penetration of plasticizers and then its viscosity increased with the DBP content. When the DBP was added, the mechanical properties of the plasticized VAE films, such as tensile strength, elongation and creep resistance, were decreased while the water resistance was increased.

Extraction Property of Plasticizer in LPG High Pressure Rubber Hose (LPG용 고압고무호스에서 가소제 추출특성)

  • Kim, Young-Gu
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.156-160
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    • 2004
  • The extraction rates of plasticizer of LPG high pressure rubber are studied. Submerging solvents are composed of propane, n-butane, n-pentane, n-hexane, n-heptane, propylene, 1,3-butadiene, 1-pentene, 1-hexene, ethanethiol, t-butanethiol, dimethyl sulfide, methyl ethyl sulfide. The relationship between the extraction rate of plasticizer and the descriptors of submerging solvent by using multiple linear regression is as follows; PE(wt%) = 7.5193 - 0.58500Carbon${\sharp}$ + 2.3294DB + 2364SH, (N = 13, F = 24.135, R$^2$ = 0.8894, R$_{adj}^2$ = 0.8526, Variance = 7.588) Plasticizer is well extracted by LPG composed of the high vapour pressure and polarity compounds. The mass of extracted plasticizer becomes increasing in proportion to the contents of thiol sulfur compound and unsaturated hydrocarbon such as propylene and 1,3-butadiene in LPG. While the heavier hydrocarbons are, the less the quantities of plasticizer extracted from rubber are.

Determination of Plasticizers in the Gasket of Glass Bottle for Bulgogi Sauces (불고기 소스용 유리병 가스켓에서의 가소제 정량)

  • Lee, Jung-Pyo;Lee, Keun-Taik
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.15 no.2
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    • pp.61-65
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    • 2009
  • This study was conducted to investigate the safety status of gasket of glass bottle being used for the Bulgogi sauce. The content of plasticizers in the gasket and their migrated amounts into Bulgogi sauce were determined. Among the plasticizers analyzed, only di-isodecyl phthalate (DIDP) was detected in the range between 30.6 and 35.9% from 6 samples. None of the plasticizers was detected in the sauce. Therefore, it can be concluded that the safety status of the gasket tested met the requirement of limit values as prescribed for the migration test of food packaging utensils, containers and packages of the Korea Food Code.

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