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Photopolymerization of Methyl methacrylate with Phenylsilane

  • 홍란영;우희권;함희숙
    • Bulletin of the Korean Chemical Society
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    • v.16 no.4
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    • pp.360-363
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    • 1995

  • The photopolymerization of methyl methacrylate(MMA) with phenylsilane wasperformed. The molecular weights of the poly(MMA) containing SiH moieties were increased with augment of molar ratio of PhSiH3 over MMA by cross-linking via hydrosilation at the expense of isolated yield. Phenylsilane apparently influenced on the photopolymerization as a chain transfer agent and solvent.

  • https://doi.org/10.5012/bkcs.1995.16.4.360 인용 PDF

A Study on the Determinants of Research Productivity among Professors of Science and Engineering (이공계 대학교수의 연구생산성 영향요인에 관한 연구)

  • 류희숙;배종태
    • Proceedings of the Technology Innovation Conference
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    • 1996.12a
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    • pp.77-98
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    • 1996

  • This study is a critical assessment of research productivity through publication among scientists and engineers. This study scrutinizes previous findings on the correlates and determinant3 of publication productivity: Provides overview and organization of that knowledge ; indicates gape and shortcomings n the research; and identifies the questions and issues which are both answered and unanswered. through the analysis of the 223 mail questionnaires collected from professors of mechanical engineering, electrical engineering, chemistry and physics, this study obtains the particular determinants of publication productivity at the science and engineering schools in Korea. Especially, early research productivity and the number of doctoral students are very important to publish good research articles. Also the qualities of professors' Ph. D. institution and employing university are critical influencing factors to publication productivity. The data are analyzed using correlation, ANOVA, and multiple regression analysis and all the regression models are statistically significant. All the variables in this study are focused on the socialization of individual research scientists and any psychological or personal background variables are excluded, because the perspective of this article is not that of scientific sociologist but of science and technology Policy interest. This study proves that there exists an scriptive advantage according to the individual background such as his Ph. D. institution and employing university in Korea. This study also shows that all research resources and research performances are unequally distributed. This result proposes that supporting basic research at university must begins with relative assessment of researchers, departments, and institutions in consideration with their research environment and to evaluate researchers in compared with excellent research university like SNU, KAIST, POSTECH is unequal and inadequate.

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Human CYP1A2 Promoter Fused-Luciferase Gene Constructs Hardly Respond to Polycyclic Hydrocarbons in Transient Transfection Study in HepG2 Cells

  • Chung, Injae
    • Toxicological Research
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    • v.16 no.2
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    • pp.95-100
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    • 2000

  • In previous study, both constitutive expression and 3-methylcholanthrene (3MC)-mediated elevation of CYP1A2 mRNA were demonstrated in human hepatoma HepG2 cells by reverse transcription-polymerase chain reaction (RT-PCR), suggesting that HepG2 cells would be appropriate for the study of human CYP1A2 regulation(Chung and Bresnick, 1994). Further studies were conducted to determine the basis of this induction phenomenon that is observed in HepG2 cells. Since CYP1A1 gene, another polycyclic hydrocarbon(PH)-inducible gene, is regulated by PHs through their interactions via receptors with cis-elements, the 5'-flanking region of human CYP 1A2 gene was analyzed to search such responsive elements. The promoter activity of various lengths of CYP1A2 gene sequence (-3203/+58bp) was measured in transiently-transfected HepG2 cells by fusion constructs containing the CAT, hGH or luciferase genes as a reporter. This region of the CYP1A2 gene, although containing a XRE, was only weakly responsive (less than 2 fold induction) to 10 nM of TCDD or 1 $\mu$M 3 MC treatment. This small enhancement of promoter activity is inconsistent with the previous observation, i.e., 12 to 14 fold-enhanced CYP1A2 mRNA from 1 $\mu$M 3 MC treated HepG2 cells, suggesting that additional mechanisms would exist for PH-mediated induction of CYP1A2 in these cells.

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