• Title/Summary/Keyword: [O]/[$N_2$] ratio

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Characteristics of A Multilayer Piezoelectric Transformer Using PAN-PZT Ceramics (PAN-PZT계 세라믹스를 이용한 적층형압전변압기의 특성)

  • 박타리;이동균;최지원;신용덕;김현재;고태국;윤석진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.143-146
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    • 2002
  • The characteristics of a multilayer piezoelectric transformer were investigated using 0.05Pb(A $l_{0.5}$N $b_{0.5}$) $O_3$-0.95Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_3$+0.9wt%N $b_2$ $O_{5}$+0.5wt%Mn $O_2$+0.04wt% $V_2$ $O_{5}$ ceramics. The multilayer piezoelectric trans formers were developed for voltage step-up. The multilayer ceramic technology was applied in piezoelectric transformer. The electrical characteristics of the piezoelectric transformer (33x8.5x1mm) has the efficiency of above 85%, step-up ratio of 70 under the 130 kΩ load, and driving frequency of 93.5kHz, respectively.ctively.y.y.

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The Study on the CEC Increase and Granulation of Natural Zeolite -The Effect of NaOH Concentration and Na2O/Al2O3 Ratio (천연(天然) Zeolite의 CEC 증가(增加)와 입단화(粒團化)에 관(關)한 연구(硏究) -1. NaOH농도(濃度)와 조반비(曺礬比)(Na2O/Al2O3)의 영향(影響))

  • Choi, Jyung;Hur, Nam-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.2
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    • pp.67-71
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    • 1993
  • This study was carried out to develop the soil conditioner and/or the absorbent of high CEC with the natural zeolite poeder whose price was very low. The $SiO_2/Al_2O_3$ ratio & CEC of the natural zeolite were 6.78 and 67.5me/100g respectively. The CEC of the post-reaction product which was treated with 3N-NaOH and $Na_2O/Al_2O_3$ ratio. 9.5 for 8hours was about 200me/100g, which was the highest value than any other treatments. The dominant clay minerals were clinoptilolite, mordenite and smectite in natural zeolite, while phillipsite in the post-reaction product.

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Adhesion and Diffusion Barrier Properties of $TaN_x$ Films between Cu and $SiO_2$ (Cu 박막과 $SiO_2$ 절연막사이의 $TaN_x$ 박막의 접착 및 확산방지 특성)

  • Kim, Yong-Chul;Lee, Do-Seon;Lee, Won-Jong
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.3
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    • pp.19-24
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    • 2009
  • Formation of an adhesion/barrier layer and a seed layer by sputtering techniques followed by electroplating has been one of the most widely used methods for the filling of through-Si via (TSV) with high aspect ratio for 3-D packaging. In this research, the adhesion and diffusion-barrier properties of the $TaN_x$ film deposited by reactive sputtering were investigated. The adhesion strength between Cu film and $SiO_2$/Si substrate was quantitatively measured by $180^{\circ}$ peel test and topple test as a function of the composition of the adhesive $TaN_x$ film. As the nitrogen content increased in the adhesive $TaN_x$ film, the adhesion strength between Cu and $SiO_2$/Si substrate increased, which was attributed to the increased formation of interfacial compound layer with the nitrogen flow rate. We also examined the diffusion-barrier properties of the $TaN_x$ films against Cu diffusion and found that it was improved with increasing nitrogen content in the $TaN_x$ film up to N/Ta ratio of 1.4.

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The $SO_2$ effect on NOx removal by Corona Shower System (코로나 샤워 시스템을 이용한 NOx제거에서 $SO_2$의 영향)

  • Park, Jae-Yoon;Kim, Ick-Kewn;Lee, Jae-Dong;Kim, Jong-Dal;Lee, Duck-Chool;Chang, J.S.
    • Proceedings of the KIEE Conference
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    • 1998.07e
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    • pp.1794-1796
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    • 1998
  • In this study, the $SO_2$ addition effect on NOx removal has been conducted from a combustion flue gases by the do corona discharge-activated radical shower systems. The simulated flue gases were consisted of NO-O_2-$N_2$, NO-$CO_2-N_2-O_2$ and $NO-SO_2-CO_2-Na-O_2$([NO]o:200ppm and $[SO_2]o$:800ppm). The injection gases used as radical source gases were $NH_3$-Ar-air. $SO_2$ and NOx removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as $SO_2$. NOx and $NO_2$ gas detectors. By-product aerosol particles were also observed by Condensation Nucleation Particle Counter(CNPC) and SEM images after sampling. The results showed that asignificant aerosol Particle formation was observed during a removal operation in corona radical shower systems. The NOx removal efficiency significantly increased with increasing applied voltage and $NH_3$ molecule ratio. The $SO_2$ removal efficiency was not significantly effected by applied voltage and slightly increased with increasing $NH_3$ molecule ratio. The NOx removal efficiency for NO-$SO_2-CO_2-N_2-O_2$ was better than that for NO-$CO_2-N_2-O_2$.

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A Review on Emission and Mitigation of N2O in Biological Wastewater Treatment (생물학적 하폐수처리과정에서 N2O 배출 및 저감에 관한 고찰)

  • Cho, Kyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.46 no.3
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    • pp.181-193
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    • 2018
  • Nitrous oxide ($N_2O$) is a potent greenhouse gas as well as an ozone-depleting substance. $N_2O$ is emitted during the biological nitrogen removal process in wastewater treatment systems (WTSs), and has significant environmental impacts. In this study, $N_2O$ emission in WTSs was comprehensively reviewed to better understand the effects of key parameters on $N_2O$ emission and obtain useful guidelines for $N_2O$ mitigation strategies in WTSs. Three biological pathways leading to $N_2O$ emission are hydroxylamine oxidation, nitrifier denitrification, and heterotrohic denitrification. Measurements at lab-, pilot- and full-scale WTSs have shown large variations in $N_2O$ emission (0-95% of N-loaded) during wastewater treatment. In the full-scale WTSs (0-14.6% $N_2O$ of N-loaded), the average and median values were 1.95% and 0.2% of N-loaded, respectively. Dissolved oxygen, nitrite concentrations, and chemical oxygen demand (COD)/N ratio are the most important parameters leading to $N_2O$ emission. A variety of operational strategies have been suggested to minimize $N_2O$ emission from WTSs. A new $N_2O$ mitigation strategy involving the introduction of microorganisms with high $N_2O$ reductase activity or oxygenic denitrification ability has been proposed as an alternative canonical denitrification.

Transparency of AlON Fabricated by Pressureless Reaction Sintering Using Various Sintering Aids (소결조제를 달리해 상압 반응소결로 제조된 AlON의 투명도)

  • Koo, Bon-Kyung;Koo, Kyeo-Hun;Kim, Ji-Hye;Jung, In-Chul;Lee, Jae-Hyung
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.392-396
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    • 2009
  • AlON was fabricated by the pressureless reaction sintering of $Al_2O_3$-AlN powder mixtures. The ratio of AlN to $Al_2O_3$ as well as various sintering aids were the main variables for this study. The optimum ratio of AlN in the $Al_2O_3$-AlN mixture was approximately 35.0 mol%. For the sintering aids, only when a small amount of MgO was added together with $Y_2O_3$ and BN, AlON specimens could be sintered to a full density with negligible pores and high transparency. Other combinations of $Y_2O_3$, BN, CaO and MgO resulted in enough pores in the sintered specimens to have in-line transmittance only between 0% and 30%. The in-line transmittance reached over 80% after sintering at $1975^{\circ}C$ for 10 h for the specimen containing 0.15 wt% MgO, 0.08 wt% $Y_2O_3$ and 0.02 wt% BN.

Thermal Phenomena of an N2O Catalyst Bed for Hybrid Rockets Using a Porous Medium Approach (다공성 매질 접근법을 적용한 하이브리드 로켓 N2O 촉매 점화기의 열적 현상)

  • 유우준;김수종;김진곤;장석필
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.9
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    • pp.89-96
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    • 2006
  • In this study, fluid flow and thermal characteristics in a catalyst bed for nitrous oxide catalytic decomposition which is introduced as a hybrid rocket ignition system for small satellites were theoretically considered. To analyze the thermal phenomena of the catalyst bed, a so-called porous medium approach has been opted for modeling the honeycomb geometry of the catalyst bed. Using a Brinkman-extended Darcy model for fluid flow and the one-equation model for heat transfer, the analytical solutions for both velocity and temperature distributions in the catalyst bed are obtained and compared with experimental data to validate the porous medium approach. Based on the analytical solutions, parameters of engineering importance are identified to be the porosity of the catalyst bed, effective volumetric ratio, the ratio of the radius of the catalyst bed to the radius of a pore, heat flux generated by a heater, and pumping power. Their effects on thermal phenomena of the catalyst bed are studied.

A Study on the Influence of Substituting Cu Eine Particle for CuO on NiCuZn Ferrite (CuO 대신 Cu 미분말 치환이 NiCuZn Ferrite에 미치는 영향에 관한 연구)

  • Kim, Jae-Sik;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.13 no.1
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    • pp.15-20
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    • 2003
  • Diffusion speed of Cu metal fine particle is fast better than CuO, so it will promote grain growth in sintering. In this paper, the influence on substituting Cu fine particle for CuO of NiCuZn ferrite with basic composition (N $i_{0.204}$C $u_{0.204}$Z $n_{0.612}$ $O_{1.02}$)F $e_{1.98}$ $O_{2.98}$ has been investigated with varying Cu/CuO ratio. The perfect spinel structure of sintered specimen at 90$0^{\circ}C$ was confirmed by the analysis of XRD patterns. The best condition was obtained when the ratio of Cu/CuO was 60%, and the permeability was 1100 and Ms was 87 emu/g in this condition. Cu has influenced on grain growth in sintering, substituting Cu fine particle for CuO could lower sintering temperature over the 3$0^{\circ}C$. After sintering, substituting Cu performed as good as CuO.s CuO.s CuO.

Synthesis and Characterization of Palladium (IV) Complexes with Guanine, Adenine, and Uracil Base (Guanine, Adenine 및 Uracil 염기를 갖는 팔라듐 (IV) 착물의 합성과 그 성질)

  • Oh Sang Oh;Chung Duck Young;Kim Hee Seon
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.679-684
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    • 1992
  • New Pd(IV) complexes have been prepared through the reactions of $trans-[Pd(en)_2Cl_2](ClO_4)_2 $(en = ethylenediamine) with Guanine, Adenine, or Uracil anion as purine and pyrimidine base. We identified the ratio of central metal versus ligands by $C{\cdot}H{\cdot}N$ elemental analysis and proposed the coordinating site of the base by infrared spectrum, $^1H-NMR,\; and\; ^{13}C$-NMR spectrum. Guanine or Adenine ligand coordinated at N7 site and an en ligand exchanged for $ClO_4^-$ counter ions of the starting material . As these results, the complexes showed the formula $[Pd(en)L_2(ClO_4)_2](ClO_4)_2{\cdot}(en)$, (L = Guanine, Adenine). But in the Uracil complex no exchange of the en ligand and $ClO_4^-$ occured and Uracil anion preferred the N1 to N3 as coordinating site, the complex $[Pd(en)_2(Urac)_2](ClO_4)_2(Urac = Uracil anion).$

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The Effects of Process parameters on TiN Films deposited by Ion Plating Technique (이온 플레이팅의 TiN코팅층에 미치는 작업인자의 영향)

  • 백응승;권식철;이상로;이건환
    • Journal of the Korean institute of surface engineering
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    • v.23 no.2
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    • pp.24-29
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    • 1990
  • The TiN filmms were deposited on the stainless steel substrates by BARE techinique in order to investigate the effects of process parameters such as source-to-substate distance (15-35cm), N2 pressure(4$\times$10-10 -1$\times$10-3mb)and bias voltage(O-2000V), on the deposition rate, the concentration ratio [N/Ti] and the surface color of the films. The deposition rate was deduced from the weight measurement, the [N/ti] ratio by ESCA. The deposition rate decreased with a relationship of=40.2/D2 where D was source-to-substrate distance. The effect of the bias voltage and the N2pressure on the deposition rate, however, appeared negligble. The [N/Ti] ratio was in the narrow range of 0.7 tp 0.8 It increased slightly with the N2 partial pressure and deceased with the source-to-substrate distance. It was confired by ESCA that a significant amount of oxygen and carbon was contaminated after deposition in the top surface of TiN films. The surface color of TiN film was changed from light gold yellow to reddish gold yellow with increasing [N/Ti] ratio.

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