• 제목/요약/키워드: /Cr/

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TiC, TiN, CrN, TiCrN, TiAlN 코팅의 산화특성 (Oxidation Characteristics of TiC, TiN, CrN, TiCrN and TiAlN Coatings)

  • ;황연상;원성빈;이동복
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2013년도 춘계학술대회 논문집
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    • pp.119-120
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    • 2013
  • 공구, 다이몰드 등에 널리 쓰이는 TiC, TiN, CrN, TiCrN, TiAlN 코팅의 산화특성을 비교하기 위하여 $600^{\circ}C-900^{\circ}C$에서 대기중 산화시험을 실시하였다. 내산화성은 (TiC, TiN), TiAlN, TiCrN, CrN 코팅의 순서로 증가하였다. 코팅원소중 Ti는 $TiO_2$로, Cr은 $Cr_2O_3$로, Al은 $Al_2O_3$로 산화되었다.

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방사광 x-선 기법에 의한 다층형 Fe/Cr 자성박막의 계면확산 연구 (Interfacial Diffusion in Fe/Cr Magnetic Multilayers Studied by Synchrotron X-ray Techniques)

  • 조태식
    • 한국전기전자재료학회논문지
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    • 제17권2호
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    • pp.223-227
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    • 2004
  • We have studied the interfacial diffusion of Fe/Cr multilayers using synchrotron x-ray techniques, such as x-ray reflectivity, extended x-ray absorption fine structures (EXAFS), and high-resolution x-ray scattering. The results of x-ray reflectivity indicated that the interfacial roughness of Fe/Cr multilayers increased with the Cr-layer thickness. The Fourier transform (FT) of EXAFS data clearly showed that the Fe atoms dominantly diffused into the stable Cr layers at the Fe/Cr interface. The results of high-resolution x-ray scattering supported the interfacial diffusion of Fe atoms. Out study revealed that the dominantly interfacial diffusion of Fe atoms into the Cr layers effects the interfacial roughness of the Fe/Cr multilayers.

SIS로써 AMADEUS CRS 사례연구

  • 정기억
    • 한국정보시스템학회:학술대회논문집
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    • 한국정보시스템학회 1998년도 추계학술대회논문집21세기를 위한정보기술의 발전방향
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    • pp.178-187
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    • 1998
  • 전략정보시스템의 성공사례로서 항상 제시하고 있는 것이 항공사의 CRS이다. 처음 CRS가 출현했을 때 항공사들은 CRS를 통해서 그렇지 않은 항공사에 비해 상당한 전략적 우위를 지킬 수 있었다. 그러나 현재의 경우 이러한 CRS의 전략적 활용의 예는 그다지 중 요한 의미를 갖지 못할 수 도 있다. 왜냐하면 이제 어느 항공사(서비스제공자)나 어느 여행 사(사용자)의 경우도 이러한 CRS를 활용하지 않는 경우는 없기 때문이다. 그렇다고 해서 CRS가 전략적 가치가 전혀 없다고 단정 지울 수 없다. 만일 특정의 CRS가 다른 CRS와의 차별화 된 기능을 갖고 있다면 그것은 충분한 전략적 가치가 있다고 볼 수 있다. 즉, 보다 다양한 기능, 광범위한 데이터 량, 풍부하게 제공되는 정보 그리고 사용상 편리성 등의 특 성을 가진 CRS는 전략적 의미가 있는 것이다. 본 연구는 이러한 입장에서 CRS의 차별화 된 전략적 특성을 파악하기 위하여 AMADEUS에 대한 사례연구를 수행하였다. 사례를 분석 한 결과 일부 차별적인 기능에 대해서는 전략적 특성을 갖고 있다고 볼 수 있었다.

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크롬계 이중도금층 제조 및 특성평가 (Fabrication of Chromium-based Double Layered Deposit)

  • 박상언;김동수;김만;장도연;권식철
    • 연구논문집
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    • 통권31호
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    • pp.127-133
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    • 2001
  • In chromium electrodeposition, crack is inevitably accompanied by chromium layer. Behavior of crack formation and crack density were different from the plating conditions such as current density, temperature, waveform of applied current and so on. And cracks have an influence on the corrosion resistance of chromium deposit, because corrosion occurs through the network of cracks between deposit and substrate. Therefore, many researches have been achieved in order to remove the cracks in chromium deposit. Formation of double layers, Cr/Cr and Ni/Cr were investigated to increase corrosion resistance of chromium deposit in this study. As pretreatment prior to outer chromium coating, acid pickling and current control method were examined. Cracks in cross-section of each sample were observed with SEM and CASS(Copper modified acetic acid salt spray) test was performed to evaluate corrosion resistance. It was found that corrosion resistance of Cr/Cr and Ni/Cr double layers were superior to Cr or Ni single layer from the results of CASS test.

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팩 세멘테이션에 의한 Al 및 Cr의 동시 코팅 (Codeposition of Al and Cr by pack cementation)

  • 손희식;이윤제;김문일
    • 열처리공학회지
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    • 제8권2호
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    • pp.127-136
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    • 1995
  • The simultaneous addition of Al and Cr to the surface of Ni-and Fe-base alloy provides enhanced resistance to oxidation and corrosion in high temperatures. However, because of the large differences in thermodynamic stabilities of the volatile halides of Al and Cr, the codeposition of Al and Cr by halideactivated pack cementation is only possible for very specific, limited combinations of conditions. In this study, the experiments on the combinations of various metallic source powders and activators were conducted in order to obtain codeposition layers of Al and Cr on Ni with adequate composition by pack cementation. When Cr-Al masteralloy was used as a source powder, it was not easy to control Al and Cr content sensitively in the coating layers. On the other hand, when pure Cr and Al powder was used, ${\beta}$-NiAl layer containing about 20wt % Cr was obtained.

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폴리이미드에 스퍼터 증착된 Cu-Cr 합금박막의 열처리 거동 (Thermal behavior of Cu-Cr Alloy Films sputter-deposited onto polyimide)

  • 임준홍;이태곤;김영호;한승희
    • 한국표면공학회지
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    • 제27권5호
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    • pp.273-284
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    • 1994
  • Thermal behavior of Cu-Cr thin alloy films has been investigated by SEM, AES, and TEM. Cu-Cr alloy films containing 3wt% Cr, 8wt% Cr have been sputter-deposited onto polyimide substrates and heat treated at $400^{\circ}C$ for 2hrs in the various atmosphere. Before heat treatment, Cu and Cr content in the film are uniform through the thickness and oxygen content in the film is negligible. Redistribution of Cr, Cu, and O in the film due to heat treatment depends on the Cr content and heat treatment atmoshpere. There kinds of thermal behavior are ascribed to the formation of surface and interface oxides as well as internal oxidation. Hillocks are observed on the surface of Cu-Cr alloy films which have been heat treated in N2. The hillocks are composed of large grainss of Cu.

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EFFECT OF Al UNDERLAYER ON THE MICROSTRUCTURES OF CoCrTa/Cr FILMS

  • Chang, H.S.;Shin, K.H.;Lee, T.D.;Park, J.K.
    • 한국자기학회지
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    • 제5권5호
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    • pp.614-617
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    • 1995
  • Thin CoCrTa/Cr films were deposited on glass substrates at $280^{\circ}C$ with or without Al underlayer. The coercivity of CoCrTa increased considerably by introducing an Al underlayer. The grain size of Cr thin film deposited on Al underlayer became smaller than that of Cr thin film deposited on glass substrate. The grain size of CoCrTa thin film was determined by Cr grain size. The cause of the coercivity increase seems to be associated with the refinement and uniform distribution of CoCrTa grains.

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VMn underlayer for CoCrPt Longitudinal Media

  • S. C. Oh;Lee, T. D.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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    • pp.352-362
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    • 2000
  • In this study, effects of novel VMn underlayer on magnetic properties of CoCrPt/VMn longitudinal medium was studied and compared with those of CoCrPt/Cr medium. It was found that the VMn film had (200) preferred orientation and the lattice constant was about 0.2967 nm, which is slightly larger than that of the Cr, 0.2888 nm. The grain size of VMn film was 9.3 nm at 30 nm thickness, and this is about 38 % smaller than that of a similarly deposited Cr film. The CoCrPt/VMn films showed higher coercivity in comparison with the CoCrPt/Cr films. The coercivity increase seems to be attributed to the increased Co (11.0) texture, improved lattice matching between Co (11.0) and VMn (200), and lower stacking fault density. Mn must have diffused into the CoCrPt magnetic layer more uniformly rather than preferentially along grain boundaries this reduced Ms at higher substrate temperature

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A study on magnetic layer thickness effects on magnetic properties of CoCrPt/Ti perpendicular media.

  • M. S. Hwang;Lee, T. D.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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    • pp.369-376
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    • 2000
  • Change of magnetic properties in CoCrPt/Ti perpendicular media with varying CoCrPt films thickness has been studied. As CoCrPt films thickness increase, the Ms(magnetization saturation) drastically increases at thinner thickness and gradually increases with further increase in thickness from 25nm. This Ms behaviour is associated with primarily the formation of "amorphous-like" reacted layer by intermixing of CoCrPt and Ti at CoCrPt/Ti interface and secondarily change of Cr segregation mode with varying the CoCrPt films thickness. Magnetic domain structure distinctively changes with increasing CoCrPt magnetic layer(ML) thickness. Also the strength of exchange coupling measured from the slope in demagnetizing region in M-H loop changes with ML thickness. Details of the above magnetic properties will be discussed. The expansion of lattice parameters a and c at thinner thickness suggests that Cr segregation mode may be connected with the residual stress of the films. Finally, negative nucleation field(Hn) behaviour with the exchange slope will be reported.

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Effect of $Cr^{6+}$ Stress on Photosynthetic Pigments and Certain Physiological Processes in the Cyanobacterium Anacystis nidulans and Its Chromium Resistant Strain

  • KHATTAR, J. I. S.,;SARMA, T. A.;ANURADHA SHARMA,
    • Journal of Microbiology and Biotechnology
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    • 제14권6호
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    • pp.1211-1216
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    • 2004
  • A MNNG (N-methyl-N'-nitro-N-nitrosoguanidine) induced chromium resistant strain ($Cr^{r}18$) of unicellular cyanobacterium Anacystis nidulans has been isolated and characterized. The resistant strain could grow (although restricted to $50\%$ of control) in chromium concentration (180${\mu}M$) lethal to the wild-type. Sublethal ($160{\mu}M$) concentration of $Cr^{6+}$ significantly reduced (13-$37.5$) all the photosynthetic pigments of A. nidulans with maximum reduction in phycoerythrin followed by ChI $\alpha$. Pigments of A. nidulans were drastically decreased in lethal concentration of Cr^{6+} with maximum reduction in phycoerythrin ($75\%$) and allophycocyanin ($67.5\%$). Resistant strain $Cr^{r}18$ resisted toxic effects of sublethal and lethal concentrations of $Cr^{6+}$ on photosynthetic pigments as revealed by less decrease in pigments as compared to A. nidulans. Effect of $Cr^{6+}$ stress was also studied on nitrogen assimilation and phosphate uptake. Sublethal concentration of $Cr^{6+}$ drastically reduced ($71.5\%$) nitrate uptake by A. nidulans while a decrease of $29\%$ was observed in strain $Cr^{r}18$. Short (2 day) exposure of A. nidulans and its resistant strain $Cr^{r}18\;to\;Cr^{6+}$ did not affect nitrate reductase and glutamine synthetase (transferase), whereas longer (10 day) exposure to $Cr^{6+}$ lowered activities of both enzymes in A. nidulans but not significantly in the strain $Cr^{r}18$. Ammonium uptake by both strains was not affected by $Cr^{6+}$. Thus, $Cr^{6+}$ affected photosynthetic pigments, nitrogen assimilation, and phosphate uptake of A. nidulans, while strain $Cr^{r}18$ was able to resist toxic effects of the metal. Advantages of using strain $Cr^{r}18$ for bioremediation purposes have been evaluated by studying $Cr^{6+}$ removal from the solution. Resistant strain $Cr^{r}18$ was able to remove $33\%$ more $Cr^{6+}$ than A. nidulans and thus it can prove to be a good candidate for bioremediation of $Cr^{6+}$ from polluted waters.