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Hybrid 구조의 Fe계 연자성 박막의 특성 (Properties of Fe-based Soft magnetic Thin Film with Hybrid Structures)

  • 송재성;이원재;허정섭;김현식;오영우
    • 한국전기전자재료학회논문지
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    • 제13권11호
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    • pp.963-968
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    • 2000
  • Magnetic properties and microstructures of Fe$\_$93-x/Zr$_3$B$_4$Ag$\_$x/ thin films were investigated as a function of addition of element Ag, (X$\_$Ag/=0 to 6 at.%) and annealing temperature, T$\_$a/=300$\^{C}$ to 600$\^{C}$. In the case of adding Ag, magnetic properties of Fe$\_$93-x/Zr$_3$B$_4$Ag$\_$x/ thin films were improved than those of Ag-free Fe$\_$93/Zr$_3$B$_4$thin films. The prominent soft magnetic properties with coercivity of 1.1 Oe, saturation magnetization of 2.2 T and permeability of 5400 at 50㎒ were obtained from Fe$\_$88/Zr$_3$B$_4$Ag$\_$5/ thin film annealed was lower than that of Fe-base or Co-base thin films reported previously. Such enhanced magnetic properties are presumably attributed to the format in ultra fine grains. Also, the reduced eddy current loss in the annealed sample is due to refined micro magnetic domains with increasing the amount of Ag in Fe$\_$93-x/Zr$_3$B$_4$Ag$\_$x/ thin films.

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(${Pb_{1-x}}{Ca_x}$)(${Ca_{1/3}}{Nb_{2/3}}$)$O_3$세라믹스의 마이크로파 유전특성에 미치는 결합원자가의 영향 (Effect of Bond Valence on Microwave Dielectric Properties of (${Pb_{1-x}}{Ca_x}$)(${Ca_{1/3}}{Nb_{2/3}}$)$O_3$Ceramics)

  • 김응수;이형규
    • 한국세라믹학회지
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    • 제38권7호
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    • pp.678-682
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    • 2001
  • 복합 페롭스카이트(P $b_{1-x}$C $a_{x}$)(C $a_{1}$3/N $b_{2}$3/) $O_3$(0.6$\leq$x$\leq$0.8) 세라믹스의 마이크로파 유전특성과 결합원자가사이의 관계에 대하여 고찰하였다. 유전상수(K)는 Ca 치환량이 증가함에 따라 A-자리의 이온반경 세제곱에 비례하여 감소하며, Qf 값은 증가하였다. Ca 치환량이 증가함에 따라 관찰된 이온분극률($\alpha$$_{obs}$)과 이론적인 이온분극률($\alpha$$_{theo}$) 사이의 편차는 3.47%에서 6.37%로 증가하였다. 이는 A-자리 결합원자가의 감소에 따른 결합강도의 감소로 해석하였다. 소결시편의 공진주파수의 온도계수(TCF)는 AB $O_3$페롭스카이트 화합물의 A-자리 결합원자가에 의존하였다.

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Investigation of LiO2 Adsorption on LaB1-xB'xO3(001) for Li-Air Battery Applications: A Density Functional Theory Study

  • Kwon, Hyunguk;Han, Jeong Woo
    • 한국세라믹학회지
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    • 제53권3호
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    • pp.306-311
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    • 2016
  • Li-air batteries have received much attention due to their superior theoretical energy density. However, their sluggish kinetics on the cathode side is considered the main barrier to high performance. The rational design of electrode catalysts with high activity is therefore an important challenge. To solve this issue, we performed density functional theory (DFT) calculations to analyze the adsorption behavior of the $LiO_2$ molecule, which is considered to be a key intermediate in both the Li-oxygen reduction reaction (ORR) and the evolution reaction (OER). Specifically, to use the activity descriptor approach, the $LiO_2$ adsorption energy, which has previously been demonstrated to be a reliable descriptor of the cathode reaction in Li-air batteries, was calculated on $LaB_{1-x}B^{\prime}_xO_3$(001) (B, B' = Mn, Fe, Co, and Ni, x = 0.0, 0.5). Our fast screening results showed that $LaMnO_3$, $LaMn_{0.5}Fe_{0.5}O_3$, or $LaFeO_3$ would be good candidate catalysts. We believe that our results will provide a way to more efficiently develop new cathode materials for Li-air batteries.

A NOTE ON PARTIAL SIGN-SOLVABILITY

  • Hwang, Suk-Geun;Park, Jin-Woo
    • 대한수학회보
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    • 제43권3호
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    • pp.471-478
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    • 2006
  • In this paper we prove that if AX=b is a partial sign-solvable linear system with A being sign non-singular matrix and if ${\alpha}=\{j:\;x_j\;is\;sign-determined\;by\; Ax=b\}, then $A_{\alpha}X_{\alpha}=b_{\alpha}$ is a sign-solvable linear system, where $A_{\alpha}$ denotes the submatrix of A occupying rows and columns in o and xo and be are subvectors of x and b whose components lie in ${\alpha}$. For a sign non-singular matrix A, let $A_l,\;...,A_{\kappa}$ be the fully indecomposable components of A and let ${\alpha}_i$ denote the set of row numbers of $A_r,\;r=1,\;...,\;k$. We also show that if $A_x=b$ is a partial sign-solvable linear system, then, for $r=1,\;...,\;k$, if one of the components of xor is a fixed zero solution of Ax=b, then so are all the components of x_{{\alpha}r}$.

$NdFe_{10.7}TiB_{0.3}N_x$$NdFe_{10.7}TiMo_{0.3}N_x$의 자기특성 (Magnetic Properties of $NdFe_{10.7}TiB_{0.3}N_x$ and $NdFe_{10.7}TiMo_{0.3}N_x$)

  • 김윤배;김희태;김창석;김택기
    • 한국자기학회지
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    • 제2권3호
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    • pp.239-243
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    • 1992
  • $ThMN_{12}$ 구조를 갖는 $NdFe_{11}TiN_x$ 형 화합물에서 B 이 자화 및 큐리온도의 상승에 매우 효과적임이 밝혀졌다. $NdFe_{10.7}TiB_{0.3}N_x$ 의 자화 및 큐리온도는 $NdFe_{10.7}Ti_{1.3}N_x$ 의 경우에 비하여 각각 20 $Am^2$/kg (20 emu/g) 및 $90^{\circ}C$가 높은 148 $Am^2$/kg (148 emu/g) 및 $560^{\circ}C$를 나타내었다. 한편, Mo은 이방성자장의 증가에 효과적이며, 또한, 질화처리시 ${\alpha}-Fe$의 생성 억제에 효과적인 것으로 추측된다. $NdFe_{10.7}TiMo_{0.3}N_x$ 의 이방성자장은 약 7960 kA/m (100 kOe) 로 $NdFe_{10.7}Ti_{1.3}N_x$ 의 경우에 비하여 약 1590 kA/m (20 kOe) 가 증가한 결과를 보였다.

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ON A NEW CLASS OF DOUBLE INTEGRALS INVOLVING GENERALIZED HYPERGEOMETRIC FUNCTION 3F2

  • Kim, Insuk
    • 호남수학학술지
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    • 제40권4호
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    • pp.809-816
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    • 2018
  • The aim of this research paper is to evaluate fifty double integrals invoving generalized hypergeometric function (25 each) in the form of $${{\int}^1_0}{{\int}^1_0}\;x^{{\gamma}-1}y^{{\gamma}+c-1}(1-x)^{c-1}(1-y)^{c+{\ell}}(1-xy)^{{\delta}-2c-{\ell}-1}{\times}_3F_2\[{^{a,\;b,\;2c+{\ell}+1}_{\frac{1}{2}(a+b+i+1),\;2c+j}}\;;{\frac{(1-x)y}{1-xy}}\]dxdy$$ and $${{\int}^1_0}{{\int}^1_0}\;x^{{\gamma}-1}y^{{\gamma}+c+{\ell}}(1-x)^{c+{\ell}}(1-y)^{c-1}(1-xy)^{{\delta}-2c-{\ell}-1}{\times}_3F_2\[{^{a,\;b,\;2c+{\ell}+1}_{\frac{1}{2}(a+b+i+1),\;2c+j}}\;;{\frac{1-y}{1-xy}}\]dxdy$$ in the most general form for any ${\ell}{\in}{\mathbb{Z}}$ and i, j = 0, ${\pm}1$, ${\pm}2$. The results are derived with the help of generalization of Edwards's well known double integral due to Kim, et al. and generalized classical Watson's summation theorem obtained earlier by Lavoie, et al. More than one hundred ineteresting special cases have also been obtained.

Nucleation and growth of vacancy agglomeration in CZ silicon crystals

  • Ogawa, Tomoya;Ma, Minya
    • 한국결정성장학회지
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    • 제9권3호
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    • pp.286-288
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    • 1999
  • When concentration of vacancies in a CZ silicon crystal is defined by molar fraction $X_{B}$, the degree for supersaturation $\sigma$ is given by $[X_{B}-X_{BS}]/X_{BS}=X_{B}/X_{BS}-1=ln(X_{B}/X_{BS})$ because $X_{B}/X_{BS}$ is nearly equal to unity. Here, $X_{BS}$ is the saturated concentration of vacancies in a silicon crystal and $X_{B}$ is a little larger than $X_{BS}$. According to Bragg-Williams approximation, the chemical potential of the vacancies in the crystal is given by ${\mu}_{B}={\mu}^{0}+RT$ ln $X_{B}+RT$ ln ${\gamma}$, where R is the gas constant, T is temperature, ${\mu}^{0}$ is an ideal chemical potential of the vacancies and ${\gamma}$ is and adjustable parameter similar to the activity of solute in a solute in a solution. Thus, ${\sigma}(T)$ is equal to $({\mu}_{B}-{\mu}_{BS})/RT$. Driving force of nucleation for the vacancy agglomeration will be proportional to the chemical potentialdifference $({\mu}_{B}-{\mu}_{BS})/RT$ or ${\sigma}(T)$, while growth of the vacancy agglomeration is proportaional to diffusion of the vacancies and grad ${\mu}_{B}$.

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X-LIFTING MODULES OVER RIGHT PERFECT RINGS

  • Chang, Chae-Hoon
    • 대한수학회보
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    • 제45권1호
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    • pp.59-66
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    • 2008
  • Keskin and Harmanci defined the family B(M,X) = ${A{\leq}M|{\exists}Y{\leq}X,{\exists}f{\in}Hom_R(M,X/Y),\;Ker\;f/A{\ll}M/A}$. And Orhan and Keskin generalized projective modules via the class B(M, X). In this note we introduce X-local summands and X-hollow modules via the class B(M, X). Let R be a right perfect ring and let M be an X-lifting module. We prove that if every co-closed submodule of any projective module P contains Rad(P), then M has an indecomposable decomposition. This result is a generalization of Kuratomi and Chang's result [9, Theorem 3.4]. Let X be an R-module. We also prove that for an X-hollow module H such that every non-zero direct summand K of H with $K{\in}B$(H, X), if $H{\oplus}H$ has the internal exchange property, then H has a local endomorphism ring.