• 한국세라믹학회지
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• 제39권8호
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• pp.795-800
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• 2002

융액인상법으로 질소분위기 하에서 $Yb^{3+}$ 이온이 20at% 고용된 $Yb:YCa_4O(BO_3)_3$ (Yb:YCOB) 단결정을 이리듐 도가니를 사용하여 성장시켰다. 양질의 단결정을 성장시키기 위한 인상속도와 회전속도는 각각 1.5∼2 mm/h와 10∼20 rpm이었다. 분광물성 측정 결과, 흡수단이 236 nm에 있었으며, 전형적인 $Yb^{3+}$ 이온의 흡수 스펙트럼이 관찰되었다. Yb:YCOB의 열팽창계수는 320∼650 K의 측정범위에서 결정학적 축 a, b 그리고 c에 대해 12.1×$10^{-6}$ /K, 5.9${\times}10^{-6}$/K, 12.9${\times}10^{-6}$이었다. 비열은 330 K에서 0.162 $cal/g{\cdot}K$이었다.

• 한국광학회:학술대회논문집
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• 한국광학회 2001년도 하계학술발표회
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• pp.246-247
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• 2001

Undoped YCa$_4$O(BO$_3$)$_3$ (sp. gr. Cm) single crystals as well as singly or co-doped with Yb, Er and Ce were grown using Czochralski technique. With the aid of x-ray analysis, crystallographic data of Ce, Er, Yb:YCA$_4$O(BO$_3$) crystals were found.

• 한국광학회지
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• 제10권4호
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• pp.301-305
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• 1999

Czocharlski pulling method에 의해 성장된 새로운 광학결정 YCOB($YCa_4O(BO_3)_3$)의 파장에 따른 위상 정합 조건을 제시하였으며, Nd:YAG 레이저의 1064nm의 출력을 기본파로 하였을 때 제2조화파 발생 효율을 조사하였다. 또한 $Yb^{3+}$이온과 $Nd^{3+}$ 이온이 도핑된 YCOB의 제2조화파 발생효율을 조사하여 희토류 이온 도핑에 따른 비선형성의 변화를 조사하였다.

• 한국광학회:학술대회논문집
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• 한국광학회 1999년도 제16회 광학 및 양자전자 학술발표회Proceedings of 16th Optics and Quantum Electronics Conference, 1999
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• pp.220-221
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• 1999

Single crystals of Yttrium Calcium Oxyborate (YCOB) doped with different concentrations of Er3+ and Yb3+ ions were growth by Czochralski method. High qualities of crystals in morphology and transparency were obtained . Analysis on crystal structure and lattice parameters were performed by X-ray diffraction method. It was found that congruent melting composition is YCA4.2O1.2(BO3)3. Absorption and fluorescence properties of grown crystals were also reported.

• 한국결정학회지
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• 제11권1호
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• pp.16-21
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• 2000

(Yb/sub x/Y/sub 1-x/)Ca₄O(BO₃)₃ single crystals where x=0.3,8,15,20% were grown by Czochralski Method. The crystals grown under the optimum conditions were transparent and colorless with good crystal form. Using polarizing microscope, crystal defects such as parasite crystals and bubbles were detected depending on the composition of melts and pulling rates. The optimum growth parameters for high quality of single crystals were 15∼20 rpm of rotation rate and 2mm/h of pulling rate at the flow rate of 2 l/min of Nitrogen gas. The relationship between crystal axes and optical axes was investigated by optical crystallographic method, polarization technique and single crystal X-ray method. From the spectroscopic measurements, it was confirmed that there were strong absorption bands at 900 and 976.4 nm and strong emission band at 976.4 nm in Yb/sup 3+/ ion doped YCa₄O(BO₃)₃ crystal. For the application of second harmonic generation of 1.064 ㎛ laser, non-linear optical devices with θ=32.32° and Ψ=0°, λ/10 of flatness and the size of 6x8x5.73 mm were fabricated from the grown YCa₄O(BO₃)₃ crystal.