• Title/Summary/Keyword: $Y_2O_3$ additive

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A study on the dielectric characteristics of 0.05PAN-0.85PZT ceramics with additive (첨가제에 의한 0.05PAN-0.95PZT계 세라믹의 유전 특성에 관한 연구)

  • Kim, Hyun-Chul;Shin, Hyea-Koung;Kim, Jean-Shop;Yoon, Hyun-Sang;Bae, Seon-Gi
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1661-1663
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    • 2000
  • This study was to measure the dielectric characteristics of 0.05Pb($Al_{0.5}Nb_{0.5}$)-0.95Pb($Zr_{0.52}Ti_{0.48})O_3$[PAN-PZT] system ceramics according to the variation of $Cr_{2}O_3$, $Fe_{2}O_3$ addition amount. 0.0$\sim$1.2[wt%] and according to sintering temperature after creating the specimens with a general sintering way. The results of this study were summarized as follows : the dielectric constant at 20[$^{\circ}C$] reduced dy increasing additive on the whole. The dielectric loss was minimum value of 12.77[%], sintered at 1200[$^{\circ}C$], dopped with $Cr_{2}O_3$ 0.3[wt%] and minimum value of 10.89[%], sintered at 1200[$^{\circ}C$], dopped with $Fe_{2}O_3$ 0.6[wt%]. The variation rate of dielectric constant according to the change of frequency was decreased slowly by increasing frequency. The temperature coefficient of capacitance turned out increasing the stability of the temperature, decreased $Cr_{2}O_3$ 0.3wt% showed its minimum value 0.59[%/$^{\circ}C$], the maximum value 0.9[%/$^{\circ}C$] with $Cr_{2}O_3$ 3wt%.

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Effect of $Dy_2O_3$ on Dielectric Properties of Barium Titanate ($BaTiO_3$의 유전성에 미치는 $Dy_2O_3$의 영향)

  • 윤기현;송효일
    • Journal of the Korean Ceramic Society
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    • v.19 no.4
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    • pp.316-320
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    • 1982
  • The effect of the additive on dielectric properties of $BaTiO_3$ containing 0.030 mol% $Dy_2O_3$ was investigated function of frequency from 5$\times$104 to 0.3$\times$107cps and temperature from 25 to 1$25^{\circ}C$. The dielectric constant increased with increasing $Dy_2O_3$ concentration from 0 to 0.05mol% due to space charge polarization. However, the dielectric constant decreased for further increase of $Dy_2O_3$ concentration due to density increase. The dielectric constant exhibits rapid change at the Curie temperature and the Curie temperature drops from 122 to 116$^{\circ}C$ with increasing amount of $Dy_2O_3$ concentration.

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An Experimental Study on Falling Film Heat and Mass Transfer for Binary Nanofluids ($H_2O$/LiBr+Nanoparticles) (이성분 나노유체($H_2O$/LiBr+나노입자)를 적용한 유하박막 흡수기의 열 및 물질전달 촉진 실험)

  • Kim, Hyun-Dae;Kim, Sung-Su;Nam, Sang-Chul;Jeong, Jin-Hee;Kang, Yong-Tae
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.130-135
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    • 2008
  • The objectives of this study are to investigate the combined heat and mass transfer enhancement using binary nanofluids as the working fluids in a $H_2O$/LiBr absorber. The result of heat and mass transfer experiment with the additives(Arabicgum, 2E1H) showed that the heat and mass transfer performance of binary nanofluid with 2E1H enhanced significantly in comparison with that without additive. In the case of 0.01wt% $Al_2O_3$ binary nanofluids with 2E1H, the vapor absorption rate increased up to 77% in comparison with that without additive. The heat transfer rate of 0.01wt% $Al_2O_3$ binary nanofluids with 2E1H increased up to 19%. Based on the experimental results, it is recommended that the $Al_2O_3$ binary nanofluid be good with 2E1H to improve the heat and mass transfer performance.

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The Effect of $MgO-Y_2O_3$ on $Al_2O_3-TiC$ Composites

  • Kasuriya, S.;Atong, D.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.543-544
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    • 2006
  • The effect of the additives, $Y_2O_3$ and MgO, on the sintering and properties of $Al_2O_3-TiC$ composites was investigated. It is known that MgO is used as additive for improving densification and $Y_2O_3$ is applied as sintering aid. In this study, the amounts of TiC were varied in the range of 30-47 wt%. The 0.5 wt% MgO and also varied amounts of $Y_2O_3$ from 0.3 to 1 wt% were added into the composites. The sintering of $Al_2O_3-TiC$ composites was performed in a graphite-heating element furnace at different sintering temperature, 1700 and $1900\;^{\circ}C$, for 2 hr under an argon atmosphere. The results demonstrated that the properties of the composites sintered at $1700\;^{\circ}C$ were much better than those sintered at $1900\;^{\circ}C$. The comparisons on physical properties, mechanical properties and microstructure of composites with and without additives were reported. Comparing with other samples, $Al_2O_3-30wt%TiC$ composites with 0.5wt% MgO and $1\;wt%Y_2O_3$ exhibited the highest density of approximately 98% of theoretical and flexural strength of 302 MPa.

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A Study on the Effects of $TiO_2$ and $Al(OH)_3$ for ZnO Ceramic Varistor (ZnO Ceramic Varistor에 미치는 $TiO_2$$Al(OH)_3$의 영향)

  • 안영필;김복희
    • Journal of the Korean Ceramic Society
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    • v.19 no.4
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    • pp.287-292
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    • 1982
  • Nonohmic properties of ZnO ceramics with various small amounts of additives were studied in relation to experimental methods, additive contant and sintaring temperature. The kinds of additives used to following chemicals were basic additives ($0.5Bi_2O_3$, $0.3BaCO_3$, $0.5MnCO_3$, $0.5Cr_2O_3$, $0.1KNO_3$), $TiO_2$ and $Al(OH)_3$. Expecially, this study has focused on the effectsof $TiO_2$ and $Al(OH)_3$ in ZnO ceramics with the basic additives. SEM studies indicated that the addition of TiO2 promoted grain growth but retarded grain growth with the addition of $Al(OH)_3$. Also, in the case of calcination of ZnO with $TiO_2$ and ZnO with $Al(OH)_3$ previously, grain size of ZnO with $TiO_2$ was larger and that of ZnO with Al(OH)3 was smaller in comparison to the case with out calcination. From the viewpoint of nonohmic exponent and nonohimic resistance, electrical characteristics of ZnO, $TiO_2$ and the basic additives was more effective than that of ZnO, $Al(OH)_3$ and the basic additives. Nonohmic exponent and nonohmic resistance of ZnO, $TiO_2$ and the basic additives was 11-13 and 40-65 respectively.

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Fabrication of La2O3-TiO2-SiO2 System Glass Derived from a Sol-Gel Process

  • Iwasaki, Mitsunobu;Masaki, Hitoshi;Ito, Seishiro;Park, Won-Kyu
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.137-141
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    • 2007
  • $La_{2}O_{3}-TiO_{2}-SiO_{2}$ glass, a type that could not obtained so far by the conventional melting method, was prepared successfully using a sol gel process. Glass derived with the sol-gel process has compositions of $5La_{2}O_{3}-5TiO_{2}-90SiO_{2},\;5La_{2}O_{3}-10TiO_{2}-85SiO_{2}$, and $5La_{2}O_{3}-20TiO_{2}75SiO_{2}$. The UV-visible absorption edge of all glass compositions was below 400 nm. The measured density is in the range of 2.55-2.89, and was nearly identical to the calculated density and the refractive index of the glasses derived from the sol-gel ranges from 1.545 to 1.645. The molar additive coefficient of $TiO_{2}$ measured in this ternary system is lower than the calculated value, while the value of $La_{2}O_{3}$ is higher.

The Study of the Properties of $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ Ceramics Modified with $La_2O_3$, $Nb_2O_5$ and $Al_2O_3$ (첨가제에 따른 $Pb(Mg_{1/2} W_{1/2}) O_3-PbTiO_3-ObZrO_3$ 고용체의 특성에 대한 연구)

  • 안영필;황학인;홍진녕
    • Journal of the Korean Ceramic Society
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    • v.22 no.2
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    • pp.17-24
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    • 1985
  • In the composition of $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ the effect of particle size on PbO vaporization were measured, . The initial step of discontinuous vaporization of unreated PbO during the calcining process was depended on the particle size. All additives $La_2O_3Nb_2O_5$ and $Al_2O_3$ inhibited the grain growth of the composition $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ +2wt% excess PbO. The dielectric and piezoelectric properties of the composition $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ were improved by the addition of 2wt% excess PbO and proper additive. The electromechanical planar coupling factor of 0.65 and mechnical quality factor of 390 could be obtained by adding 5wt% $Nb_2O_5$ to the composition 2wt% excess PbO+$Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$.

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Microwave Dielectric Properties of Low-temperature Sintered $Mg_4Nb_2O_9$ Ceramics (저온소결 $Mg_4Nb_2O_9$ 세라믹스의 마이크로파 유전특성)

  • Lee, Ji-Hun;Bang, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.439-442
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    • 2004
  • The effects of sintering additives on the low-temperature sintering and microwave dielectric properties of $Mg_4Nb_2O_9$ dielectric ceramics were studied. When $3{\sim}20wt%$ of $0.242Bi_2O_3-0.758V_2O_5$ was added, the sintering temperature decreased from $1100{\sim}1300^{\circ}C$ to $950^{\circ}C$ and high density was obtained. When $Mg_4Nb_2O_9$ was sintered at $950^{\circ}C$ with 10wt% of sintering additive, the microwave dielectric properties of $Q{\times}f_0\;=\;80.035GHz,\;\epsilon_r\;=\;13.3\;and\;\tau_f\;=\;-12.9\;ppm/^{\circ}C$ were obtained.

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Photocurrent Characteristics of Plasma Sprayed TiO2 Composite Coatings according to Additive Transition Metal (전이금속을 첨가한 플라즈마 TiO2 복합 용사피막의 광전류 특성)

  • Ko, Byung-Chun;Ko, Young-Bong;Park, Kyeung-Chaea
    • Journal of the Korean institute of surface engineering
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    • v.44 no.3
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    • pp.89-94
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    • 2011
  • In this study, the photocurrent characteristics of plasma sprayed $TiO_2$ coatings have been investigated according to additive transition metal (Fe, Mn, Nb powder) and heat treatment conditions. The plasma sprayed $TiO_2$ coatings by heat treatment at $400^{\circ}C$ and 90 min had the higher photocurrent at ultraviolet light, no photocurrent at visible light. The photocurrent of plasma sprayed $TiO_2$ coatings added by Fe, Mn, Nb (named by plasma sprayed $TiO_2$ composite coatings) was lower than that of plasma sprayed $TiO_2$ coatings at ultraviolet light, as was low in intensity ratio of XRD(101)/(110). and the atomic percentage of oxygen by plasma sprayed $TiO_2$ composite coatings was higher than that by plasma sprayed $TiO_2$ coatings. The photocurrent of plasma sprayed $TiO_2$ composite coatings in heat treatment at $400^{\circ}C$ and 90 min was higher than that of plasma sprayed $TiO_2$ coatings in same heat treatment conditions at ultraviolet and visible light, as was high in oxygen affinity by heat treatment.

Influence of Chemical Composition of Pyrophosphate Copper Baths on Properties of Electrodeposited Cu Films (전기도금 된 Cu 필름 특성에 미치는 피로인산구리용액의 화학성분의 영향)

  • Shin, Dong-Yul;Koo, Bon-Keup;Park, Deok-Yong
    • Journal of the Korean Electrochemical Society
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    • v.18 no.1
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    • pp.7-16
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    • 2015
  • Effects of chemical composition ($Cu^{2+}$, $K_4P_2O_7$ and additive concentrations) of baths on properties of Cu thin films electrodeposited from pyrophosphate copper bath were investigated. Current efficiency was increased to be near 100% with increasing $Cu^{2+}$ concentrations from 0.02 to 0.3M. Decrease of current efficiency was observed in the range of 1.5~1.8M $K_4P_2O_7$ concentration, but current efficiency of about 100% was measured in the ranges of both 0.9~1.3M and 2.1~2.4M. The change of additive concentration did not influenced current efficiency. Residual stress of electrodeposited Cu thin films was measured to be about 20 MPa below 0.15 M $Cu^{2+}$ concentration and increased with the increase of it to 0.25 M. Maximum residual stress of 120MPa was observed at 0.25M $Cu^{2+}$ concentration. On the other hand, residual stress decreased from 80 to near 0 MPa as $K_4P_2O_7$ concentration varied from 0.9 to 2.4M and but The change of additive concentration did not affected on residual stress. $Cu^{2+}$ and $K_4P_2O_7$ concentrations significantly affect on surface morphology of electrodeposited Cu thin films, but additive concentration slightly affected. From XRD analysis, the microstructures of electrodeposited Cu thin film was affected from the changes of $Cu^{2+}$ and $K_4P_2O_7$ concentrations, but not from that of additive concentration. Strong preferred orientation of (111) peak was observed with increasing $Cu^{2+}$ and $K_4P_2O_7$ concentrations.