• 제목/요약/키워드: $Y_2O_3$ additive

검색결과 528건 처리시간 0.026초

Effect of Additive Size on the Densification and Thermal Conductivity of AlN Ceramics with MgO-CaO-Al2O3-SiO2 Additives

  • Lee, Hwa-Jun;Cho, Woo-Seok;Kim, Hyeong Jun;Kim, Hyung-Tae;Ryu, Sung-Soo
    • 한국세라믹학회지
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    • 제54권1호
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    • pp.43-48
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    • 2017
  • In this study, we investigate the effect of additive size on the densification and thermal conductivity of AlN ceramics with $MgO-CaO-Al_2O_3-SiO_2$ (MCAS) additives. Micro-sized MCAS powder prepared via melting and nano-sized MCAS powder synthesized via the polymeric complex method are used as sintering additives. We analyze the densification behavior of AlN added with 5 wt.% of MCAS by dilatometry as well as by isothermal sintering in the temperature range of $1300{\sim}1700^{\circ}C$. AlN exhibits higher sinterability with nano-MCAS than with micro-MCAS, and both specimens approach their maximum densities when sintered at $1600^{\circ}C$ for 4 h. The thermal conductivities of AlN with 5 wt% of nano- and micro-MCAS additives sintered at $1600^{\circ}C$ are 82.6 and 32.0 W/mK, respectively. We find that nano-MCAS is more effective in sintering of AlN ceramics at lower temperatures, and thus for enhancing their thermal conductivities.

전력선 통신(PLC)을 위한 HV 커플러용 자심재료 (Ceramic magnetic core material for coupling unit under the condition of high voltage as a part of the PLC)

  • 이해연;김현식;오영우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.365-368
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    • 2000
  • We have studies on the Microstructures and densities as a function of forming pressures and the magnetic properties of the specimens with additive Bi$_2$O$_3$ that sintered at 95$0^{\circ}C$ for 4.5 hours for synthesizing optimal Ni-Cu-Zn ferrite. Green density rose generally as Forming pressure increased from 1.7 ton/cm$^2$to 2.5 ton/cm$^2$and Cold Isostatic Pressure(CIP) method was more effective than Die Pressure(DP) method to high green density. Forming pressure had no influence on apparent density but on the other hand Bi$_2$O$_3$contents were strongly dominant to appaernt density than forming pressure. Bi$_2$O$_3$liquid phases created during sintering process promoted sintering and grain growth so that apparent density, grain size and permeability increased compared to that of the specimens which were sintered with non-additive Bi$_2$O$_3$.

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Enhancement of nuclear radiation shielding and mechanical properties of YBiBO3 glasses using La2O3

  • Issa, Shams A.M.;Ali, Atif Mossad;Tekin, H.O.;Saddeek, Y.B.;Al-Hajry, Ali;Algarni, Hamed;Susoy, G.
    • Nuclear Engineering and Technology
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    • 제52권6호
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    • pp.1297-1303
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    • 2020
  • In this study, nuclear radiation shielding and rigidity parameters of Y (0.1-x)B0.6Bi1.8O3La2x glassy system were investigated in order to determine it's suitability for use as nuclear radiation shielding materials. Therefore, a group of bismuth borate glass samples with La2O3 additive were synthesized using the technique of melt quenching. According to the results, the increase of the La2O3 additive increases the density of the glass samples and the mass attenuation coefficient (μm) values, whereas the half-value layer (HVL) and mean free path (MFP) values decrease. The effective atomic number (Zeff) is also enhanced with an increment of both mass removal cross section for neutron (ΣR) and absorption neutron scattering cross section (σabs). In addition to the other parameters, rigidity parameter values were theoretically examined. The increase of La2O3 causes some other important magnitudes to increase. These are the average crosslink density, the number of bonds per unit volume, as well as the stretching force constant values of these glass samples. These results are in concordance with the increase of elastic moduli in terms of the Makishima-Mackenzie model. This model showed an increase in the rigidity of the glass samples as a function of La2O3.

$Pb_5Ge_3O_11$에 의한 반도성 $BaTiO_3$ 세라믹스의 저온소결성 (Low-Temperature Sinterbility of Semiconducting $BaTiO_3$ Ceramics with $Pb_5Ge_3O_11$ Additives)

  • 윤상옥;정형진;윤기현
    • 한국세라믹학회지
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    • 제28권5호
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    • pp.359-364
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    • 1991
  • The effects of Pb5Ge3O11 on the sinterbility and lattice variation of the semiconducting 0.15 mol% Y2O3 doped BaTiO3 have been investigated as functions of additive contents (from 0.25 mol% to 2.5 mol%) and sintering temperatures (from 110$0^{\circ}C$ to 130$0^{\circ}C$). As the amount of Pb5Ge3O11 increases, the sinterbility of BaTiO3 increases abruptly at around 115$0^{\circ}C$. During the sintering, the most of Pb+2 ions in additives penetrate into BaTiO3 lattices and Ge+4 ions present at grain boundaries. Therefore the c lattice of the BaTiO3 increases largely and then the tetragonality increases due to the diffusion of the Pb+2 ions.

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Novel high performanced and fouling resistant PSf/ZnO membranes for water treatment

  • Sarihan, Adem;Eren, Erdal
    • Membrane and Water Treatment
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    • 제8권6호
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    • pp.563-574
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    • 2017
  • Antibacterial effective, high performanced, novel ZnO embedded composite membranes were obtained by blendig ZnO nanoparticles with polysulfone. IR, TG/DTG, XRD and SEM analysis were performed to characterize structure and morphology of ZnO nanoparticles and composite membranes. Contact angle, EWC, porosity and pore structure properties of composite membranes were investigated. Cross-flow filtration studies were performed to investigation of performances of prepared membranes. It was found from the cross section SEM images that ZnO nanoparticles dispersed homogenously up to additive amount of 2% and the membrane skin layer thicknesses increased in the presence of ZnO. Contact angle of pure PSf membranes were reduced from $70^{\circ}$ to $55^{\circ}$ after addition of 4% ZnO. Porosity of composite membrane contains 1% ZnO was higher about 22% than pure PSf membrane. BSA rejection ratio and PWF of 0.5% ZnO embedded composite membrane became 2.2 and 2.3 times higher than pure PSf membrane. It was determined from flux recovery ratios that ZnO additive increased the fouling resistance of composite membranes. Also, the bacterial killing ability of ZnO is well known and there are many researches related to this in the literature. Therefore, it is expected that prepared composite membranes will show antibacterial effect.

NiO 및 $Cr_2O_3$를 첨가한 0.02PYW-0.98PZT계 세라믹의 압전특성에 관한 연구 (A study on the piezoelectric characteristic of 0.02PYW-0.98PZT system piezoelectric ceramics dopped with NiO, $Cr_2O_3$)

  • 김진섭;김현철;윤현상;배선기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1789-1791
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    • 1999
  • In consideration of piezoelectric characteristic and Temperature stability, 3-element system dopped with NiO, $Cr_2O_3$ well-known as Hardner and Stabilizer whose primary element is PZT was eximanated its structure, piezoelectric characteristics, dopping with Nio, $Cr_2O_3$. We think that piezoelectric Characteristic is developed, remenent polarization and $E_c$ can developed in specimens by dopping with NiO, $Cr_2O_3$ additive. also, electromechanical quality factor largely showed tendency of decrement. According to dopping NiO, $Cr_2O_3$ more.

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Sheath Heater 모듈 실링용 B2O3-ZnO-Bi2O3계 유리소재 및 첨가제에 따른 물성 변화 (Effect of an Additive on the Physical and Electrical Properties of the B2O3-ZnO-Bi2O3 Glass System for a Sheath Heater Module)

  • 최진삼;신동우;배원태
    • 한국세라믹학회지
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    • 제50권1호
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    • pp.57-62
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    • 2013
  • We investigated the thermal and electrical properties of the $B_2O_3-ZnO-Bi_2O_3$ glass system as a sealing material in sheath heater modules. A composition with over 90 wt% $Bi_2O_3$ in the $B_2O_3-ZnO-Bi_2O_3$ system was glassified by controlling the cooling rate. The glass transition temperature and thermal expansion coefficient in bismate glass could be controlled by the minor ingredients of ZnO, $SiO_2$, $BaO_2$, and $K_2O$. The $B_2O_3-ZnO-Bi_2O_3$ glass system bonded well to metal, and bismate glass insulating properties were comparable to those of bismate glass $B_2O_3-ZnO-PbO$ glass system in a sheath heater module.

Effect of Additive Amount on Microstructure and Fracture Toughness of SiC-TiC Composites

  • Min-Jin Kim;Young-Wook Kim;Wonjoong Kim;Hun-Jin Lim;Duk-Ho Cho
    • The Korean Journal of Ceramics
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    • 제6권2호
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    • pp.91-95
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    • 2000
  • Powder mixtures of $\beta$-SiC-TiC in a weight ratio of 2:1 containing 5-20 wt% additives ($Al_2O_3$-$Y_2O_3$) were liquid-phase sintered at $1830^{\circ}C$ for 1h by hot-pressing and subsequently annealed at $1950^{\circ}C$ for 6h to enhance grain growth. The annealed specimens revealed a microstructure of \"in situ-toughened composite\" as a result of the $\beta$longrightarrow$\alpha$ phase transformation of SiC during annealing. The increase of the content of additives accelerated the growth of elongated $\alpha$-SiC grains with higher aspect ratio and improved fracture toughness. The fracture toughness of SiC-TiC composite containing 20 wt% additive was 6.2 MPa.$m^{1/2}$.2}$.

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$SnO_2$계 가스 센서의 안정성 향상을 위한 산화물의 첨가 효과 (The effect of additive on $SnO_2$ gas sensor for improving stability)

  • 박광묵;민봉기;최순돈;남효덕
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.865-868
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    • 2002
  • $SnO_2$ powders were prepare by precipitating $Sn(OH)_4$ from an aqueous solution of $SnCl_4{\cdot}5H_2O$, pH 9.5. The effects of stability and sensitivity of $SnO_2$ thick film sensors added with various amounts, $SiO_2$, $Al_2O_3$, $ZrO_2$, $TiO_2$ have been investigated. It is shown that the 3wt% $Al_2O_3$ or $SiO_2$ can improve the stability of $SnO_2$ gas sensor at an operating temperature of $350^{\circ}C$.

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