• Title/Summary/Keyword: $YBa_2Cu_3O_7

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CHARACTERIZATION OF $YBa_2Cu_3O_{7-x}$ MADE BY A SOL-GEL PROCESS USING NITRATE SALTS AND SODIUM HYDROXIDE (질산염(窒酸鹽)과 수산화(水酸化)나트륨을 써서 졸-겔 법(法)으로 만든 $YBa_2Cu_3O_{7-x}$의 특성분석(特性分析))

  • Kim, Bong-Heup;Kang, Hyung-Boo;Kim, Hyun-Teak
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.143-149
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    • 1990
  • A sol-gel processing of $YBa_2Cu_3O_{7-x}$ superconductor using metal nitrate salts and sodium hydroxide as the starting materials has been investigated because of the need to produce pure, hompgeneous superconducting materials. Since the precipitation of barium hydroxides can be obtained only at high basicities, the process has to be carried out Ca. pH 13 to get the simultaneous coprecipitation with the other metal hydroxides. The involved reaction mechanisms were investigated and intermediate and final products were characterized by means of thermogravimetric analysis(TGA), infra-red(IR) spectroscopy, X-ray diffraction(XRD) analysis, scanning electron microscopy(SEM), thermal mechanical analysis(TMA) and electrical measurement.

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Properties of a Hybrid Type Superconducting Fault Current Limiter using YBa2Cu3O7 Films (YBa2Cu3O7 박막을 이용한 하이브리드형 초전도 사고전류제한기의 특성)

  • Choi, Hyo-Sang;Cho, Yong-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.4
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    • pp.391-397
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    • 2006
  • We present investigations of a hybrid type superconducting fault current limiter (SFCL), which consists of transformers and resistive superconducting elements. The secondary windings of the transformer were separated into several electrically isolated circuits and linked inductively with each other by mutual flux, each of which has a superconducting current limiting element of $YBa_2Cu_3O_7$ (YBCO) stripes as a current limiting element. Simple connection in series of the SFCL elements tends to produce ill-timed quenching because of power dissipation unbalance between SFCL elements. Both electrical isolation and mutual flux linkage of the elements provides a solution to power dissipation unbalance, inducing simultaneous quench and current redistribution of the YBCO films. This design enables to increase the voltage rating of SFCL with given YBCO stripes.

Microstructures fo Top Seed Milt-Processed $YBa_{2}$$Cu_{3}$$O_{7-\delta}$ Superconductor (종자결정법으로 성장시킨 $YBa_{2}$$Cu_{3}$$O_{7-\delta}$ 고온초전도체의 미세구조)

  • 한영희;성태현;한상철;이준성;정상진
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 1999.02a
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    • pp.43-46
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    • 1999
  • The microstructure of Top Seed Milt-Processed $YBa_{2}$$Cu_{3}$$O_{7-\delta}$ single crystal was studied. It was presumed that the segregation of Y211 is due to the difference of growth rates between a, b axis and c axis in crystal direction. Corn kernel lide structure which was grown by the diffusion of Y211 was observed. At the near corner of the seed crystal, the diagonal line on Y123 cry crystal is formed by the corn kernel like structure.

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Deformation Mechanism Map for Creep and Superplastic Deformation in $YBa_2Cu_3O_{7-x}$ Ceramic Superconductors ($YBa_2Cu_3O_{7-x}$ 세라믹 초전도체의 크리프와 초소성변형에 대한 변형기관도)

  • 윤존도;초우예
    • Journal of the Korean Ceramic Society
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    • v.33 no.6
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    • pp.718-724
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    • 1996
  • Deformation mechanism map of Langdon-Mohammed type for YBa2Cu3O7-x superconducting ceramic was constructed by considering mechanisms of Nabarro-Herring Coble and powder-law creep and grain boundary sliding (GBS) with an accommodation by grain boundary diffusion. The map was found consistent with experi-mental results not only of the creep the also of the superplastic deformation. It showed the transition from interface reaction-controlled to the grain boundary diffusion-controlled GBS mechanism at about 1 ${\mu}{\textrm}{m}$ grain size and 100 MPa flow stress in agreement with the experimental results.

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Characteristics of rapid-thermal-annealed $YBa_2Cu_3O_{7-x}$ high $T_c$, superconducting thin-films (급속 열처리에 의한 $YBa_2Cu_3O_{7-x}$ 고온 초전도체 박막의 특성)

  • Shin, Hyun-Yong;Park, Chang-Yub;Kim, Kyu-Soo
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1137-1139
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    • 1993
  • The superconducting thin films of $YBa_2Cu_3O_{7-x}$ were deposited on (100) sapphire substrates at low temperature by rf magnetron sputtering and annealed at $895^{\circ}C$ for 60 sec. using rapid-thermal-annealing(RTA) technique. The films were characterized by SEM, four-point probe resistivity measurement, XRD, and AES. The RTA processed HTS films had a preferential structure with c-axis normal to the substrate surface.

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Dependence of ambient gas of oxide films fabricated by laser ablation method (레이저 어브레이션법에 의해 제조된 산화물 박막의 분위기가스 의존성)

  • 최충석;이덕출
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.357-363
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    • 1996
  • The superconducting properties of YBa$_{2}$Cu$_{3}$$O_{7-x}$(YBaCuO) thin films prepared by laser ablation have been investigated. The x-ray diffraction patterns of the films were substantially different from one another. The Y and Ba oxides are formed by the collisions with oxygen molecules. On the other hand, the Cu oxide is mainly formed at initial stage of the laser irradiation. The YBaCuO films manufactured on MgO(100) substrate were indicated T$_{c}$(zero)=90 K, T$_{c}$(onset)=92 K, and J$_{c}$=3.5*10$^{5}$ A/cm$^{2}$(at 77.3K). The optimum conditions were found to be a substrate temperature of 710.deg. C, an energy density of 2 J/cm$^{2}$, and a target-substrate distance of 60mm in an oxygen partial pressure of 200 mTorr.0 mTorr.

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Growth Conditions of $SrTiO_3 $ Film on Textured Metal Substrate for $YBa_2CU_3O_{7-\delta}$ Coated Conductor ($YBa_2CU_3O_{7-\delta}$ coated Conductor 완충층으로의 응용을 위한 $SrTiO_3 $ 박막의 성장 조건)

  • Chung, J.K.;Ko, R.K.;Song, K.J.;Park, C.;Kim, C.J.
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.51-55
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    • 2003
  • SrTiO₃ (STO) thin fims were deposited on the biaxially textured Ni-3 wt%W alloy substrates to be used as a single buffer layer for YBa₂CU₃O/sub 7-8/(YBCO) coated conductor. Thin films of YBCO and STO were deposited using pulsed laser. The deposition condition for epitaxial growth of STO on the textured metal was identified, and YBCO coated conductor with a single STO buffer layer with critical current density of 1.2 MA㎠ at 77 K under zero magnetic field and critical temperature of 86 K, was fabricated.

Microwave Detector Using $YBa_2Cu_3O_{7-x}$ Grain Boundary Junction ($YBa_2Cu_3O_{7-x}$ 결정입계 접합을 이용한 마이크로파 감지소자)

  • Sin, Jung-Sik;Jo, Chang-Hyeon;Hwang, Du-Seop;Kim, Yeong-Geun;Wi, Dang-Mun;Cheon, Seong-Sun;Sin, U-Seok;Bae, Seong-Jun;Hong, Seung-Beom
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.681-686
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    • 1994
  • Microwave Detector Using $YBa_{2}Cu_{3}O_{7-x}$, Grain Boundary Junction $YBa_{2}Cu_{3}O_{7-x}$ superconductor thin films were deposited on $LaAIO_{3}$ (100) single crystal substrates using a metal organic chemical vapor deposition (MOCVD) method. These films showed the critical temperature of about 9OK and critical current density of over $10^5/A \textrm{cm}^2$at 77K. These films showed granular structure with 0.5~1.5$\mu \textrm{m}$ grains. Bridge-type junctions, 6$\mu \textrm{m}$ in width and 6pm in length, were fabricated using the photolithography and the Ar ion milling techniques. Current-voltage (I-V) characteristics of these junctions with the microwave irradiation at 77K were studied. The critical current densities decreased as the irradiated microwave power increased. When microwaves were irradiated on the bridge at 77K. the I-V charateristics showed constant voltage stcp(Shapiro steps) at $\Delta$=nho/2e.

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Synthesis of High Tc Superconductor YBa2Cu3O7-$\delta$ by Oxalate Coprecipitation Method II. The Effect of Cu2+-Oxalate-Complex Formation for the Solubilities of Y3+ and Ba2+ (Oxalate공침법에 의한 고온 초전도체 YBa2Cu3O7-$\delta$의 합성 II. Cu2+-Oxalate-Complex가 Y3+ 및 Ba2+의 용해도에 미치는 영향)

  • 최진호;김배환;최규원
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.395-401
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    • 1989
  • The concentrations of Cu(II), Y(III) and Ba(II) ionic species in aqueous solution due to the formation of Cu2+-oxalate-complex have been theoretically calculated with respect to pH and their solubility diagrams could be obtained. It was verified from the calculation that the excess of Cu2+ and Ba2+ should be added in order to obtain oxalate coprecipitates with the molar ratio of Y : Ba : Cu=1 : 2 : 3. The exact amount of excess species has been calculated with respect to the initial concentrations of metal ions and pH.

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