• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.601-601
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• 2013

Superhydrophobic W18O49 nanowire (NW) arrays were synthesizedusing a thermal evaporation and surface chemistry modification methods by self-assembled monolayer (SAM). As-prepared non-wetting W18O49 NWs surface shows water contact angle of $163.2^{\circ}$ and has reliable stability in underwater conditions. Hence the superhydrophobic W18O49 NWs surface exhibits silvery surface by total reflection of water layer and air interlayer. The stability analysus of underwater superhydrophobicity of W18O49 NWs arrays was conducted by changing hydrostatic pressure and surface energy of W18O49 NWs arrays. The stability of superhydrophobicity in underwater conditions decreased exponentially as hydrostatic pressure applied to the substrates increased3. In addition, as surface energy decreased, the underwater stability of superhydrophobic surface increased sharply. Specifically, sueprhydrophobic stability increased exponentially as surface energy of W18O49 NWs arrays was decreased. Based on these results, the models for explaining tendencies of superhydrophobic stability underwater resulting from hydrostatic pressure and surface energy were designed. The combination of fugacity and Laplace pressure explained this exponential decay of stability according to hydrostatic pressure and surface energy. This study on fabrication and modeling of underwater stability of superhydrophobic W18O49 NW arrays will help in designing highly stable superhydrophobic surfaces and broadening fields of superhydrophobic applications even submerged underwater.

• 한국분말재료학회지
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• 제11권3호
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• pp.253-258
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• 2004

We report a carbothermal reduction process for massive synthesis of monolithic W$_{18}$O$_{49}$ phase from tungsten oxide in the presence of carbon source. Carbon black powder was used as a carbon source and added to WO$_3$ by 40 weight percent. Bundles of W$_{18}$O$_{49}$ rods were formed over the temperature range of 80$0^{\circ}C$$^{\circ}C$ to 90$0^{\circ}C$. Pure W$_{18}$O$_{49}$ bundles could be separated from the mixture of W$_{18}$O$_{49}$ and residual carbon black powder. Field emission character of W$_{18}$O$_{49}$ phase was determined using the extracted W$_{18}$O$_{49}$ rods. Flat lamp fabricated from the W$_{18}$O$_{49}$ rods showed the turn-on field of 9.3 V/${\mu}m$.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2004년도 춘계총회 및 연구발표회 초록집
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• pp.42.1-42.1
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• 2004

• Bulletin of the Korean Chemical Society
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• 제30권1호
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• pp.227-229
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• 2009

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.33.1-33.1
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• 2009

To date, nanostructured tungsten oxides with a variety of stoichiometries, such as WO3, WO2.9, W18O49, and WO2, have been prepared, because they are promising candidates for applications such as gas sensors, photocatalysts, electrochromic devices, and field emission devices. Among them, W18O49 and WO2 have been widely studied due to their outstanding chemical sensing, catalytic, and electron emissive properties. Here we report, for the first time, a one-pot solution-phase route to synthesizing a novel composite hierarchical hollow structure without adding catalysts, surfactants, or templates. The products, consisting of a WO2 hollow core sphere surrounded by a W18O49 nanorod shell (yielding a sea urchin-like structure), were generated as discrete structures via Ostwald ripening. To our knowledge, this type of composite hierarchical core/shell structure has not been reported previously. The morphological evolution and the detailed growth mechanism were carefully studied. We also demonstrate that the size of the hollow urchins is readily tunable by controlling the reactant concentrations.Interestingly, although bulk tungsten oxides are weakly paramagnetic or diamagnetic, the as-prepared products show unusual ferromagnetic behavior atroom temperature. The urchin structures also show a very high Brunauer-Emmet-Teller (BET) surface area, suggesting that they may potentially be applied to chemical sensor or effective catalyst technologies.

• 대한금속재료학회지
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• 제49권3호
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• pp.270-274
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• 2011

Plasma electrolytic oxidation (PEO) treatment was performed on squeeze cast AZ31 alloy and $Al_{18}B_4O_{33}w/AZ31$ composite. Scanning electron microscope (SEM) was employed to characterize the surface morphology and cross-section microstructure of the coating. The phase structures of the PEO coating were analyzed by X-ray diffraction (XRD). The corrosion resistance of the PEO coating was evaluated by electrochemical method. The results showed that the $Al_{18}B_4O_{33}$ whisker on the surface of the composite was decomposed and $MgAl_2O_4$ was formed in the PEO coating layer of $Al_{18}B_4O_{33}w/AZ31$ composite during PEO treatment. As a result, the electrochemical corrosion potential of the PEO coated $Al_{18}B_4O_{33}w/AZ31$ composite was increased compared with that of AZ31 alloy.

• 한국재료학회지
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• 제32권2호
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• pp.57-65
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• 2022

Herein a rich, Se-nanoparticle modified Mo-W₁₈O₄₉ nanocomposite as efficient hydrogen evolution reaction catalyst is reported via hydrothermal synthesized process. In this work, Na₂SeSO₃ solution and selenium powder are used as Se precursor material. The structure and composition of the nanocomposites are characterized by X-ray diffraction (XRD), high-resolution field emission scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), EDX spectrum analysis and the corresponding element mapping. The improved electrochemical properties are studied by current density, and EIS analysis. The as-prepared Se modified Mo-W₁₈O₄₉ synthesized via Na₂SeSO₃ is investigated by FE-SEM analysis and found to exhibit spherical particles combined with nanosheets. This special morphology effectively improves the charge separation and transfer efficiency, resulting in enhanced photoelectric behavior compared with that of pure Mo-W₁₈O₄₉. The nanomaterial obtained via Na₂SeSO₃ solution demonstrates a high HER activity and low overpotential of -0.34 V, allowing it to deliver a current density of 10 mA cm^-2.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2008년도 제34회 동계학술대회 초록집
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• pp.89-89
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• 2008

• 한국전자현미경학회:학술대회논문집
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• 한국현미경학회 2004년도 제35차 추계학술대회 및 제2회 HVEM 이용자 워크샵
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• pp.72-76
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• 2004

• 한국작물학회지
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• 제33권3호
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• pp.287-291
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• 1988

1981년 전남지방에서 생산된 쌀보리 '영산보리'를 공시하여 일반보리쌀은 농업기술연구소에 설치되어 있는 표준도정시설로, 할맥은 맥류연구소에서 확립된 할맥가공방법으로 가공하여 도정수율, 입형, 소요전력, 화학성분 그리고 취반특성을 구명한 결과는 다음과 같다. 1. 도정율은 일반보리쌀이 70.10%인데 비하여 할맥이 68.27% 였다. 2. 입장/입폭비율은 할맥이 2.88인데 일반보리 쌀이 1.36이었으며 천립중은 할맥이 9.5g인데 일반보리쌀이 18.5 g 이었다. 3. 가공중 소요전력은 일반보리쌀이 91.1 kW/1.000kg인데 비하여 할맥이 105.1 kw/1,000 kg 으로 할맥가공에서 140.0kW/1,000 kg 더 많이 소요되었다. 4. 단백질, MgO 함량은 할맥이 일반보리쌀에서 보다 높았으나, P$_2$O$_{5}$, $K_2$O 및 Mn은 거의 차가 없었다. 5. 취반후 백도의 차이는 일반보리쌀이 45.5%, 할맥이 49.5%, 수분흡수율은 일반보리쌀이 225.7%, 할맥이 312.7 %, 팽윤성은 일반보리쌀이 283%, 할맥이 318%로 할맥이 일반보리쌀보다 각각 4.0, 87.0 및 35% 높았다.및 35% 높았다.