• Journal of the Korean Ceramic Society
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• v.32 no.4
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• pp.471-481
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• 1995

Unirradiated UO2 pellets were pulverized by oxidation in air at 40$0^{\circ}C$, and the oxidized powders were reduced in H2 and CO atmospheres at $600^{\circ}C$. During the oxidation of UO2 at 40$0^{\circ}C$, intergranular cracks which caused the spallation were mainly developed by the volume contraction due to the formation of intermediate phase (U4O9 or U3O7). As oxidation proceeded, U3O8 finally formed. As the oxidation/reduction cycles were repeated, the powder surface became coarser, specific surface area was increased and average particle size was decreased. The sintered densities of the powder were increased by the oxidation/reduction cycle due to the characteristic changes of the powder.

• Analytical Science and Technology
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• v.14 no.3
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• pp.203-211
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• 2001

In this paper it was described on the intereference effect of uranium to analyze Cs in $UO_2$ by Electron Probe Micro Analysis(EPMA) and the beam stability of Cs $L_{\alpha}$ X-ray intensity for some Cs compounds. According to the experimental results, the CsI showed the highest $L_{\alpha}$ X-ray intensity among the tested Cs compounds at the experimental condition; 15~30 kV of accelerating voltage and PET, LiF crystal. When 100 nA of beam current was applied to Cs compounds, Cs $L_{\alpha}$ X-ray intensity was continuously decreased with increasing time. The decreasing rate of Cs $L_{\alpha}$ X-ray intensity was directly proportional to the applied beam current and accelerating voltage but inversely proportional to the applied beam size. It was found that uranium interference can be prevented by using Cs $L_{\alpha}$ X-ray wavelength of Lif crytal for Cs analysis in $UO_2$ by EPMA.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2007.05a
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• pp.153-154
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• 2007

• Proceedings of the Materials Research Society of Korea Conference
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• 2000.11a
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• pp.76-76
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• 2000

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05b
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• pp.727-732
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• 1995

사용후핵연료 중간저장 시설의 누수사고시 예상되는 핵연료봉의 온도상승을 SFUEL 컴퓨터 코드 분석결과에 따른 실제 $UO_2$의 산화거동을 실험하였다. 외기 온도 38$^{\circ}C$에서 환기회수가 시간당 0, 1, 2회인 조건에서 저장용기 밑바닥 구멍 크기가 2.54, 5.08, 7.62 cm인 경우의 실험결과 환기회수 0회 바닥구멍 크기 2,54 cm 일 때 약 15시간 후 건전성 상실(0.6% 무게증가)이 일어났으며 환기회수 2회 바닥구멍 크기 7.62 cm 일 때는 약 21시간 이후에 건전성 상실이 일어나 가장 느렸다. 바닥구멍 크기가 증가할수록 공기 순환비의 영향을 크게 받으며, 또 외기 온도가 낮을 수록 공기 순환비의 영향을 크게 받았다.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.470-475
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• 1996

사용후핵연료 장기 건식저장시 여러가지 저장조건에서 사용후핵연료 피복관 및 사용후핵연료 ($UO_2$)에 대한 장기 건전성을 종합적으로 평가할 수 있는 SIECO 코드를 개발하였다. 건식저장 시스템은 사용후핵연료를 헬륨 및 공기분위기하에서 TN-24P 건식 저장용기에 장기 저장할 경우로 하였으며 피복관의 최대 표면온도는 COBRA-SFS코드를 사용하여 계산하였고, 열유동 해석결과를 바탕으로 SIECO코드를 이용하여 핵연료 연소도 및 냉각기간, 냉각매체에 따른 최대 건식저장 허용온도를 피복관의 열화 및 $UO_2$ 산화의 관점에서 계산하였다.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.3
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• pp.229-233
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• 2015

Developing novel anode materials to replace the Pt anode currently used in electrolytic reduction is an important issue on pyroprocessing. In this study, the electrochemical behavior of TiN was investigated as the conductive ceramic anode which evolves O₂ gas during the reaction. The feasibility and stability of the TiN anode was examined during the electrolytic reduction of UO₂. The TiN anode could electrochemically convert UO₂ to metallic U in a LiCl–Li₂O molten salt electrolyte. No oxidation of TiN was observed during the reaction; however, the formation of voids in the bulk section appeared to limit the lifetime of the TiN anode.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.2
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• pp.77-84
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• 2005

A voloxidizer for a hot cell demonstration, that handles spent fuels of a high radiation level in a limited space should be small and spent fuel powders should not be dispersed out of the equipment involved. In this study a density rate equation as well as the Stokes'equation has been proposed in order to obtain the theoretical terminal velocity of powders. The terminal velocity of U$_{3}$O$_{8}$ has been predicted by using the terminal velocity of SiO$_{2}$, and then determination has been the optimum air flow rate which is able to prevent powders from scattering. An equation which has shown a relationship between theoretical terminal velocities of U$_{3}$O$_{8}$ and SiO$_{2}$ has been derived with the help of the Stokes'equation, and then an experimental verification made for the theoretical Stokes' equation of SiO$_{2}$ by means of an experimental device made of acryl. The theoretical terminal velocity based on the proposed density rate equation has been verified by detecting U$_{3}$O$_{8}$ powders in a filter installed in the mock-up voloxidizer. As the results, the optimum air flow rates seem to be 20 LPM by the Stokes'equation while they are 14.5 L/min by the density rate equation. At the experiments with the mock-up voloxidizer, a trace amount of U$_{3}$O$_{8}$ seems to be detectable at the air flow rate of 14.5 L/min by the density rate equation, but U$_{3}$O$_{8}$ powders of 7$\mu$m diameter seem detectable at the air flow rate of 20 L/min by the Stokes'equation. It is revealed that 14.5 L/min is the optimum air flowe rate which is capable of preventing U$_{3}$O$_{8}$ powders from scattering in the UO$_{2}$ voloxidizer and the proposed density rate equation is proper to calculate the terminal velocity of U$_{3}$O$_{8}$ powders.

• Resources Recycling
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• v.21 no.1
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• pp.66-74
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• 2012

In order to evaluate the feasibility of selective sulfidization of uranium and rare-earth(RE) oxides, an analysis on thermodynamic data, such as $M-O_2-S_2$ phase stability diagram and changes of Gibbs free energy for sulfidization of uranium and rare-earth oxides were carried out. Comparing $RE-O_2-S_2$ with $U-O_2-S_2$ phase stability diagram at wide range of sulfur potential, $UO_2$ remains unreacted, while RE oxides are sulfidized. The Gibbs free energy change(${\Delta}G^{\circ}$) of sulfidization of RE oxides is lower than that of uranium oxides. Thus, the selective formation of RE sulfides is possible during sulfidization of RE and uranium oxides at lower temperature. $CS_2$ was selected as a sulfidizing agent, because it is a stronger sulfidizing agent than other agents and reacts at lower temperature.

• Proceedings of the Korean Nuclear Society Conference
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• 2002.05a
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• pp.240.2-240
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• 2002